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[5,10,15,20-Tetrakis(4-((pentaammineruthenio)- cyano)phenyl)porphyrinato]cobalt(II) Immobilized on Graphite Electrodes Catalyzes the Electroreduction of O2 to H2O, but the Corresponding 4-Cyano-2,6-dimethylphenyl Derivative Catalyzes the Reduction Only to H2O2

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Arthur Amos Noyes Laboratories, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125
Cite this: Inorg. Chem. 1997, 36, 18, 4138–4140
Publication Date (Web):August 27, 1997
https://doi.org/10.1021/ic970275o
Copyright © 1997 American Chemical Society

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    21. C. Song, L. Zhang, J. Zhang, D. P. Wilkinson, R. Baker. Temperature Dependence of Oxygen Reduction Catalyzed by Cobalt Fluoro‐Phthalocyanine Adsorbed on a Graphite Electrode. Fuel Cells 2007, 7 (1) , 9-15. https://doi.org/10.1002/fuce.200500205
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    27. Herbert Winnischofer, Vésper Yoshiyuki Otake, Sergio Dovidauskas, Marcelo Nakamura, Henrique Eisi Toma, Koiti Araki. Supramolecular tetracluster-cobalt porphyrin: a four-electron transfer catalyst for dioxygen reduction. Electrochimica Acta 2004, 49 (22-23) , 3711-3718. https://doi.org/10.1016/j.electacta.2003.12.052
    28. Toshiyuki Abe, Masao Kaneko. Reduction catalysis by metal complexes confined in a polymer matrix. Progress in Polymer Science 2003, 28 (10) , 1441-1488. https://doi.org/10.1016/S0079-6700(03)00057-1
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    31. Mojtaba Shamsipur, Abdollah Salimi, Hasan Haddadzadeh, Mir Fazlollah Mousavi. Electrocatalytic activity of cobaloxime complexes adsorbed on glassy carbon electrodes toward the reduction of dioxygen. Journal of Electroanalytical Chemistry 2001, 517 (1-2) , 37-44. https://doi.org/10.1016/S0022-0728(01)00644-1
    32. Koiti Araki, Sergio Dovidauskas, Herbert Winnischofer, Anamaria D.P. Alexiou, Henrique Eisi Toma. A new highly efficient tetra-electronic catalyst based on a cobalt porphyrin bound to four μ3-oxo-ruthenium acetate clusters. Journal of Electroanalytical Chemistry 2001, 498 (1-2) , 152-160. https://doi.org/10.1016/S0022-0728(00)00348-X
    33. N Rea, B Loock, D Lexa. Porphyrins bound to Ru(bpy)2 clusters: electrocatalysis of sulfite. Inorganica Chimica Acta 2001, 312 (1-2) , 53-66. https://doi.org/10.1016/S0020-1693(00)00319-4
    34. Beat Steiger, J. Spencer Baskin, Fred C. Anson, Ahmed H. Zewail. Femtosecond Dynamics of Dioxygen – Picket-Fence Cobalt Porphyrins: Ultrafast Release of O2 and the Nature of Dative Bonding. Angewandte Chemie 2000, 112 (1) , 263-266. https://doi.org/10.1002/(SICI)1521-3757(20000103)112:1<263::AID-ANGE263>3.0.CO;2-Z
    35. Henrique E Toma, Koiti Araki. Supramolecular assemblies of ruthenium complexes and porphyrins. Coordination Chemistry Reviews 2000, 196 (1) , 307-329. https://doi.org/10.1016/S0010-8545(99)00041-7
    36. Takakazu Yamamoto, Tohru Kimura, Kouichi Shiraishi. Preparation of π-Conjugated Polymers Composed of Hydroquinone, p -Benzoquinone, and p -Diacetoxyphenylene Units. Optical and Redox Properties of the Polymers. Macromolecules 1999, 32 (26) , 8886-8896. https://doi.org/10.1021/ma9907946
    37. BEAT STEIGER, FRED C. ANSON. Preparation, Isolation and Electrochemical Characterization of Cobalt Porphyrins with Ru ( NH 3 ) 5 2+ Complexes Coordinated to 4-Cyanophenyl Substituents in the 5, 10, 15 and 20 Positions on the Porphyrin Ring. Journal of Porphyrins and Phthalocyanines 1999, 03 (02) , 159-165. https://doi.org/10.1002/(SICI)1099-1409(199902)3:2<159::AID-JPP113>3.0.CO;2-E
    38. Lucian Gurban, André Tézé, Gilbert Hervé. Coordination of the tetrakis-pyridyl-porphyrin to the ferri-11-tungstophosphate. Electrocatalytic activity of the complex immobilized on a glassy carbon electrode. Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry 1998, 1 (5-6) , 397-403. https://doi.org/10.1016/S1387-1609(98)80177-1
    39. Fred C. Anson, Chunnian Shi, Beat Steiger. Novel Multinuclear Catalysts for the Electroreduction of Dioxygen Directly to Water. Accounts of Chemical Research 1997, 30 (11) , 437-444. https://doi.org/10.1021/ar960264j

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