ACS Publications. Most Trusted. Most Cited. Most Read
Nitrogen Abstraction from Nitriles by Osmium(IV) Complexes

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2001, 123, 18, 4336-4337
    Communication

    Nitrogen Abstraction from Nitriles by Osmium(IV) Complexes
    Click to copy article linkArticle link copied!

    View Author Information
    Department of Chemistry, Box 351700 University of Washington, Seattle, Washington 98195-1700
    Other Access OptionsSupporting Information (2)

    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2001, 123, 18, 4336–4337
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ja005645d
    Published April 13, 2001
    Copyright © 2001 American Chemical Society
    Request reuse permissions
    Copyright © 2001 American Chemical Society

    Subjects

    what are subjects

    Note: In lieu of an abstract, this is the article's first page.

    Free first page

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    §

     University of Washington staff crystallographer.

    *

    In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

    Supporting Information Available

    Click to copy section linkSection link copied!

    Experimental, spectroscopic, analytical, and crystallographic data (PDF). This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!
    Citation Statements
    Explore this article's citation statements on scite.ai
    powered by  Scite

    This article is cited by 29 publications.

    1. M. Angeles Alvarez, M. Esther García, Daniel García-Vivó, Ana M. Guerra, Miguel A. Ruiz. C≡N and N≡O Bond Cleavages of Acetonitrile and Nitrosyl Ligands at a Dimolybdenum Center to Render Ethylidyne and Acetamidinate Ligands. Inorganic Chemistry 2024, 63 (7) , 3207-3211. https://doi.org/10.1021/acs.inorgchem.3c03697
    2. Yusuke Takahashi, Atsushi Tahara, Toshiro Takao. Intramolecular Nitrene Transfer via the C≡N Bond Cleavage of Acetonitrile to a μ3-Alkylidyne Ligand on a Cationic Triruthenium Plane. Organometallics 2020, 39 (15) , 2888-2899. https://doi.org/10.1021/acs.organomet.0c00393
    3. Ruth Castro-Rodrigo, Miguel A. Esteruelas, Ana M. López and Enrique Oñate. Reactions of a Dihydrogen Complex with Terminal Alkynes: Formation of Osmium−Carbyne and −Carbene Derivatives with the Hydridotris(pyrazolyl)borate Ligand. Organometallics 2008, 27 (14) , 3547-3555. https://doi.org/10.1021/om800248e
    4. Ruth Castro-Rodrigo,, Miguel A. Esteruelas,, Ana M. López,, Montserrat Oliván, and, Enrique Oñate. Preparation, Spectroscopic Characterization, X-ray Structure, and Theoretical Investigation of Hydride−, Dihydrogen−, and Acetone−OsTp Complexes:  A Hydridotris(pyrazolyl)borate−Cyclopentadienyl Comparison. Organometallics 2007, 26 (18) , 4498-4509. https://doi.org/10.1021/om700480t
    5. Nadezhda A. Bokach,, Tatyana B. Pakhomova,, Vadim Yu. Kukushkin,, Matti Haukka, and, Armando J. L. Pombeiro. Hydrolytic Metal-Mediated Coupling of Dialkylcyanamides at a Pt(IV) Center Giving a New Family of Diimino Ligands. Inorganic Chemistry 2003, 42 (23) , 7560-7568. https://doi.org/10.1021/ic034800x
    6. Maximilian N. Kopylovich,, Armando J. L. Pombeiro,, Andreas Fischer,, Lars Kloo, and, Vadim Yu. Kukushkin. Facile Ni(II)/Ketoxime-Mediated Conversion of Organonitriles into Imidoylamidine Ligands. Synthesis of Imidoylamidines and Acetyl Amides. Inorganic Chemistry 2003, 42 (22) , 7239-7248. https://doi.org/10.1021/ic0349813
    7. Vadim Yu. Kukushkin and, Armando J. L. Pombeiro. Additions to Metal-Activated Organonitriles. Chemical Reviews 2002, 102 (5) , 1771-1802. https://doi.org/10.1021/cr0103266
    8. M. Angeles Alvarez, M. Esther García, Daniel García-Vivó, Ana M. Guerra, Miguel A. Ruiz. Nitrosyl derivatives of the halide-bridged complexes [M2Cp2(μ-X)(μ-P Bu2)(CO)2] (M = Mo, W; X = Cl, I).. Journal of Organometallic Chemistry 2024, 1012 , 123147. https://doi.org/10.1016/j.jorganchem.2024.123147
    9. Patrick Q. Kelly, Alexander S. Filatov, Mark D. Levin. A Synthetic Cycle for Heteroarene Synthesis by Nitride Insertion**. Angewandte Chemie 2022, 134 (46) https://doi.org/10.1002/ange.202213041
    10. Patrick Q. Kelly, Alexander S. Filatov, Mark D. Levin. A Synthetic Cycle for Heteroarene Synthesis by Nitride Insertion**. Angewandte Chemie International Edition 2022, 61 (46) https://doi.org/10.1002/anie.202213041
    11. Lixin Liu, Jianyu Dong, Yaxing Zhang, Yongbo Zhou, Shuang-Feng Yin. Cu-mediated nitrogen atom transfer via CN bond cleavage. Organic & Biomolecular Chemistry 2015, 13 (39) , 9948-9952. https://doi.org/10.1039/C5OB01738F
    12. Jing Zhao, Shaoguang Zhang, Wen-Xiong Zhang, Zhenfeng Xi. Coordination-induced skeletal rearrangements of zirconacyclobutene–silacyclobutene fused complexes. Coordination Chemistry Reviews 2014, 270-271 , 2-13. https://doi.org/10.1016/j.ccr.2013.08.032
    13. Jeremy M. Smith. Reactive Transition Metal Nitride Complexes. 2014, 417-470. https://doi.org/10.1002/9781118792797.ch06
    14. Udai P. Singh, Vaibhave Aggarwal, Sujata Kashyap. High-spin iron(III) complexes: structural, spectroscopic, and photochemical studies. Journal of Coordination Chemistry 2009, 62 (19) , 3157-3167. https://doi.org/10.1080/00958970903012793
    15. Wen‐Xiong Zhang, Shaoguang Zhang, Xiaohua Sun, Masayoshi Nishiura, Zhaomin Hou, Zhenfeng Xi. Zirconium‐ and Silicon‐Containing Intermediates with Three Fused Rings in a Zirconocene‐Mediated Intermolecular Coupling Reaction. Angewandte Chemie 2009, 121 (39) , 7363-7367. https://doi.org/10.1002/ange.200903329
    16. Wen‐Xiong Zhang, Shaoguang Zhang, Xiaohua Sun, Masayoshi Nishiura, Zhaomin Hou, Zhenfeng Xi. Zirconium‐ and Silicon‐Containing Intermediates with Three Fused Rings in a Zirconocene‐Mediated Intermolecular Coupling Reaction. Angewandte Chemie International Edition 2009, 48 (39) , 7227-7231. https://doi.org/10.1002/anie.200903329
    17. Eva Becker, Sonja Pavlik, Karl Kirchner. The Organometallic Chemistry of Group 8 Tris(pyrazolyl)borate Complexes. 2008, 155-197. https://doi.org/10.1016/S0065-3055(07)56003-X
    18. Priyabrata Banerjee, Golam Mostafa, Alfonso Castiñeiras, Sreebrata Goswami. Two Novel Reactions of a Ruthenium‐Coordinated Phenazine – Oxidative Aromatic Ring Hydroxylation and Dimerization via a New C–N Bond Formation. European Journal of Inorganic Chemistry 2007, 2007 (3) , 412-421. https://doi.org/10.1002/ejic.200600864
    19. Priyabrata Banerjee, Srijit Das, Phillip E. Fanwick, Sreebrata Goswami. Unprecedented examples of double-addition of aromatic amines across a ruthenium(II)-coordinated nitrile function: Isolation and X-ray structures of ruthenium complexes of amidinate and cyclometalated amidine. Journal of Organometallic Chemistry 2006, 691 (13) , 2915-2923. https://doi.org/10.1016/j.jorganchem.2006.02.033
    20. Chaker Lidrissi, Antonio Romerosa, Mustapha Saoud, Manuel Serrano‐Ruiz, Luca Gonsalvi, Maurizio Peruzzini. Stable, Water‐Soluble Pta‐Based Ru–Ag Organometallic Polymers. Angewandte Chemie 2005, 117 (17) , 2624-2628. https://doi.org/10.1002/ange.200462790
    21. Chaker Lidrissi, Antonio Romerosa, Mustapha Saoud, Manuel Serrano‐Ruiz, Luca Gonsalvi, Maurizio Peruzzini. Stable, Water‐Soluble Pta‐Based Ru–Ag Organometallic Polymers. Angewandte Chemie International Edition 2005, 44 (17) , 2568-2572. https://doi.org/10.1002/anie.200462790
    22. Vadim Yu. Kukushkin, Armando J.L. Pombeiro. Metal-mediated and metal-catalyzed hydrolysis of nitriles. Inorganica Chimica Acta 2005, 358 (1) , 1-21. https://doi.org/10.1016/j.ica.2004.04.029
    23. Jake D. Soper, Ian J. Rhile, Antonio G. DiPasquale, James M. Mayer. Oxidation of TpOsIII(NH2Ph)Cl2 to TpOsIV(NHPh)Cl2 by O2. Polyhedron 2004, 23 (2-3) , 323-329. https://doi.org/10.1016/j.poly.2003.11.021
    24. A.J.L. Pombeiro, V.Yu. Kukushkin. Reactivity of Coordinated Nitriles. 2003, 639-660. https://doi.org/10.1016/B0-08-043748-6/01248-2
    25. Chi-Ming Che, Tai-Chu Lau. Ruthenium and Osmium: High Oxidation States. 2003, 733-847. https://doi.org/10.1016/B0-08-043748-6/04215-8
    26. Ka-Lai Yip, Wing-Yiu Yu, Pui-Ming Chan, Nian-Yong Zhu, Chi-Ming Che. Nitrido-ruthenium( vi ) and -osmium( vi ) complexes of multianionic chelating (N, O) ligands. Reactions with nucleophiles, electrophiles and oxidizing agents. Dalton Trans. 2003, 30 (18) , 3556-3566. https://doi.org/10.1039/B304920P
    27. My Hang V. Huynh, Thomas J. Meyer. Proton-Coupled Electron Transfer from Phosphorus: A P−H/P−D Kinetic Isotope Effect of 178. Angewandte Chemie International Edition 2002, 41 (8) , 1395-1398. https://doi.org/10.1002/1521-3773(20020415)41:8<1395::AID-ANIE1395>3.0.CO;2-Z
    28. Andrew D. Burrows. 6  Nitrogen, phosphorus, arsenic, antimony and bismuth. Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem. 2002, 98 , 77-91. https://doi.org/10.1039/B109579J
    29. Michael B. Davies. 27  Mechanisms of reactions in solution. Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem. 2002, 98 , 531-569. https://doi.org/10.1039/B109728H
    Download PDF
    Go to Journal of the American Chemical Society
    Get e-Alerts
    Get e-Alerts

    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2001, 123, 18, 4336–4337
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ja005645d
    Published April 13, 2001
    Copyright © 2001 American Chemical Society
    Request reuse permissions

    Article Views

    546

    Altmetric

    -

    Citations

    29
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.