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Fluoride Complexation of Element 104, Rutherfordium

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Contribution from the Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195, Japan, Cyclotron Center, RIKEN, Wako, Saitama 351-0198, Japan, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan, Faculty of Science, Niigata University, Niigata, Niigata 950-2181, Japan, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan, Department of Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan, Faculty of Science, Kanazawa University, Kanazawa, Ishikawa 920-1192, Japan, School of Health Sciences, University of Tokushima, Tokushima, Tokushima 770-8509, Japan, Gesellschaft für Schwerionenforschung, D-64291 Darmstadt, Germany, and Institut für Kernchemie, Universität Mainz, D-55099 Mainz, Germany
Cite this: J. Am. Chem. Soc. 2004, 126, 16, 5219–5224
Publication Date (Web):April 2, 2004
https://doi.org/10.1021/ja031824u
Copyright © 2004 American Chemical Society
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    Abstract

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    Fluoride complexation of element 104, rutherfordium (Rf), produced in the 248Cm(18O,5n)261Rf reaction has been studied by anion-exchange chromatography on an atom-at-a-time scale. The anion-exchange chromatographic behavior of Rf was investigated in 1.9−13.9 M hydrofluoric acid together with those of the group-4 elements Zr and Hf produced in the 18O-induced reactions on Ge and Gd targets, respectively. It was found that the adsorption behavior of Rf on anion-exchange resin is quite different from those of Zr and Hf, suggesting the influence of relativistic effects on the fluoride complexation of Rf.

    *

    In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

    †

     Japan Atomic Energy Research Institute.

    ‡

     RIKEN.

    §

     Osaka University.

    ‖

     Niigata University.

    ⊥

     Tokyo Metropolitan University.

    ✗

     University of Tsukuba.

    ○

     Kanazawa University.

    #

     University of Tokushima.

    ∇

     Gesellschaft für Schwerionenforschung.

    ◆

     Universität Mainz.

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