logo

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2005, 127, 12, 4397-4402
RETURN TO ISSUEPREVArticleNEXT

Molecular Rotor of Cs2([18]crown-6)3 in the Solid State Coupled with the Magnetism of [Ni(dmit)2]

View Author Information
Contribution from the Research Institute for Electronic Science, Hokkaido University, Sapporo 060-0812, Japan, Graduate School of Environmental Earth Science, Hokkaido University, Sapporo 060-0810, Japan, CREST, Japan Science and Technology Corporation (JST), Kawaguchi 332-0012, Japan, Graduate School of Science, Hokkaido University, Sapporo 060-0810, Japan, Institute for Molecular Science, Okazaki 444-8585, Japan, and Research Center for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
Cite this: J. Am. Chem. Soc. 2005, 127, 12, 4397–4402
Publication Date (Web):February 26, 2005
https://doi.org/10.1021/ja043527a
Copyright © 2005 American Chemical Society
RIGHTS & PERMISSIONS
Article Views
1070
Altmetric
-
Citations
87
LEARN ABOUT THESE METRICS

Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.

Read OnlinePDF (491 KB)
Get e-Alerts
Supporting Info (13)»
SUBJECTS:

Abstract

Abstract Image

Nanoscale molecular rotors that can be driven in the solid state have been realized in Cs2([18]crown-6)3[Ni(dmit)2]2 crystals. To provide interactions between the molecular motion of the rotor and the electronic system, [Ni(dmit)2]- ions, which bear one S = 1/2 spin on each molecule, were introduced into the crystal. Rotation of the [18]crown-6 molecules within a Cs2([18]crown-6)3 supramolecule above 220 K was confirmed using X-ray diffraction, NMR, and specific heat measurements. Strong correlations were observed between the magnetic behavior of the [Ni(dmit)2]- ions and molecular rotation. Furthermore, braking of the molecular rotation within the crystal was achieved by the application of hydrostatic pressure.

*

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

†

 Research Institute for Electronic Science, Hokkaido University.

‡

 Graduate School of Environmental Earth Science, Hokkaido University.

 CREST, JST.

⊥

 Graduate School of Science, Hokkaido University.

‖

 Institute for Molecular Science.

§

 Research Center for Molecular Thermodynamics, Graduate School of Science, Osaka University.

Supporting Information Available

ARTICLE SECTIONS
Jump To

Temperature-dependent crystal data of 1, electrical conductivity, and ESR spectrum at 298 K (PDF, CIF). This material is available free of charge via the Internet at http://pubs.acs.org.

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Cited By

This article is cited by 88 publications.

  1. Kohei Sambe, Norihisa Hoshino, Takashi Takeda, Takayoshi Nakamura, Tomoyuki Akutagawa. Dynamics and Structural Diversity of Li+(Crown Ether) Supramolecular Cations in Electrically Conducting Salts. The Journal of Physical Chemistry C 2020, 124 (25) , 13560-13571. https://doi.org/10.1021/acs.jpcc.0c02686
  2. Kohei Sambe, Norihisa Hoshino, Takashi Takeda, Takayoshi Nakamura, Tomoyuki Akutagawa. Structural Modulation of Electrically Conducting TCNQ Salts Using Na+(crown ether) Supramolecular Cations. Crystal Growth & Design 2020, 20 (6) , 3625-3634. https://doi.org/10.1021/acs.cgd.0c00169
  3. Tomasz Pawlak, Dorota Czajkowska-Szczykowska, Izabella Jastrzebska, Rosa Santillan, Barbara Seroka, Jadwiga Maj, Jacek W. Morzycki, Pablo Labra-Vázquez, Norberto Farfán, Grzegorz D. Bujacz, Marek J. Potrzebowski. Influence of Hydrogen/Fluorine Substitution on Structure, Thermal Phase Transitions, and Internal Molecular Motion of Aromatic Residues in the Crystal Lattice of Steroidal Rotors. Crystal Growth & Design 2020, 20 (4) , 2202-2216. https://doi.org/10.1021/acs.cgd.9b01179
  4. Guo-Jun Yuan, Dong-Sheng Shao, Bing-Wen Hu, Wen-Long Liu, Xiao-Ming Ren. A Rotorlike Supramolecular Assembly, {[K(18-crown-6)]PbI3}∞, with a Reversible Breaking-Symmetry Phase Transition near Room Temperature. Inorganic Chemistry 2020, 59 (2) , 980-983. https://doi.org/10.1021/acs.inorgchem.9b03517
  5. Katsuya Ichihashi, Daisuke Konno, Takuya Date, Takumi Nishimura, Kseniya Yu. Maryunina, Katsuya Inoue, Toshimi Nakaya, Kazuhiro Toyoda, Yoko Tatewaki, Tomoyuki Akutagawa, Takayoshi Nakamura, Sadafumi Nishihara. Optimizing Lithium Ion Conduction through Crown Ether-Based Cylindrical Channels in [Ni(dmit)2]− Salts. Chemistry of Materials 2018, 30 (20) , 7130-7137. https://doi.org/10.1021/acs.chemmater.8b03027
  6. Daut R. Islamov, Valery G. Shtyrlin, Nikita Yu. Serov, Ivan V. Fedyanin, and Konstantin A. Lyssenko . Symmetry Influence on the Rotation of Molecules in Crystals. Crystal Growth & Design 2017, 17 (9) , 4703-4709. https://doi.org/10.1021/acs.cgd.7b00588
  7. Jhon Zapata-Rivera, Daniel Maynau, and Carmen J. Calzado . Evaluation of the Magnetic Interactions in Salts Containing [Ni(dmit)2]− Radical Anions. Chemistry of Materials 2017, 29 (10) , 4317-4329. https://doi.org/10.1021/acs.chemmater.7b00632
  8. Jun Xiong, Kazuya Kubo, Shin-ichiro Noro, Tomoyuki Akutagawa, and Takayoshi Nakamura . Self-assembled Structure of Inorganic–Organic Hybrid Crystals Based on Keggin Polyoxometallates [SMo12O402–] and Supramolecular Cations. Crystal Growth & Design 2016, 16 (2) , 800-807. https://doi.org/10.1021/acs.cgd.5b01388
  9. Shigehisa Akine, Fumihiko Utsuno, Shunjin Piao, Hideo Orita, Seiji Tsuzuki, and Tatsuya Nabeshima . Synthesis, Ion Recognition Ability, and Metal-Assisted Aggregation Behavior of Dinuclear Metallohosts Having a Bis(Saloph) Macrocyclic Ligand. Inorganic Chemistry 2016, 55 (2) , 810-821. https://doi.org/10.1021/acs.inorgchem.5b02288
  10. Luca Catalano, Salvador Pérez-Estrada, Giancarlo Terraneo, Tullio Pilati, Giuseppe Resnati, Pierangelo Metrangolo, and Miguel A. Garcia-Garibay . Dynamic Characterization of Crystalline Supramolecular Rotors Assembled through Halogen Bonding. Journal of the American Chemical Society 2015, 137 (49) , 15386-15389. https://doi.org/10.1021/jacs.5b10776
  11. Munehiro Inukai, Tomohiro Fukushima, Yuh Hijikata, Naoki Ogiwara, Satoshi Horike, and Susumu Kitagawa . Control of Molecular Rotor Rotational Frequencies in Porous Coordination Polymers Using a Solid-Solution Approach. Journal of the American Chemical Society 2015, 137 (38) , 12183-12186. https://doi.org/10.1021/jacs.5b05413
  12. Sundus Erbas-Cakmak, David A. Leigh, Charlie T. McTernan, and Alina L. Nussbaumer . Artificial Molecular Machines. Chemical Reviews 2015, 115 (18) , 10081-10206. https://doi.org/10.1021/acs.chemrev.5b00146
  13. Xing Jiang, Braulio Rodríguez-Molina, Narega Nazarian, and Miguel A. Garcia-Garibay . Rotation of a Bulky Triptycene in the Solid State: Toward Engineered Nanoscale Artificial Molecular Machines. Journal of the American Chemical Society 2014, 136 (25) , 8871-8874. https://doi.org/10.1021/ja503467e
  14. Melissa Hughs, Miguel Jimenez, Saeed Khan, and Miguel A. Garcia-Garibay . Synthesis, Rotational Dynamics, and Photophysical Characterization of a Crystalline Linearly Conjugated Phenyleneethynylene Molecular Dirotor. The Journal of Organic Chemistry 2013, 78 (11) , 5293-5302. https://doi.org/10.1021/jo4004053
  15. Shigeng Li, Junhua Luo, Zhihua Sun, Shuquan Zhang, Lina Li, Xiaojun Shi, and Maochun Hong . Phase Transition Triggered by Ordering of Unique Pendulum-Like Motions in a Supramolecular Complex: Potassium Hydrogen Bis(dichloroacetate)-18-Crown-6. Crystal Growth & Design 2013, 13 (6) , 2675-2679. https://doi.org/10.1021/cg4004565
  16. Laura Cañadillas-Delgado, Oscar Fabelo, J. Alberto Rodríguez-Velamazán, Marie-Hélène Lemée-Cailleau, Sax A. Mason, Emilio Pardo, Francesc Lloret, Jiong-Peng Zhao, Xian-He Bu, Virginie Simonet, Claire V. Colin, and Juan Rodríguez-Carvajal . The Role of Order–Disorder Transitions in the Quest for Molecular Multiferroics: Structural and Magnetic Neutron Studies of a Mixed Valence Iron(II)–Iron(III) Formate Framework. Journal of the American Chemical Society 2012, 134 (48) , 19772-19781. https://doi.org/10.1021/ja3082457
  17. Norihisa Hoshino, Yuuya Yoshii, Masaki Aonuma, Kazuya Kubo, Takayoshi Nakamura, and Tomoyuki Akutagawa . Supramolecular Rotators of (Aniliniums)([18]crown-6) in Electrically Conducting [Ni(dmit)2] Crystals. Inorganic Chemistry 2012, 51 (23) , 12968-12975. https://doi.org/10.1021/ic302093b
  18. Cyprien Lemouchi, Cécile Mézière, Leokadiya Zorina, Sergey Simonov, Antonio Rodríguez-Fortea, Enric Canadell, Pawel Wzietek, Pascale Auban-Senzier, Claude Pasquier, Thierry Giamarchi, Miguel A. Garcia-Garibay, and Patrick Batail . Design and Evaluation of a Crystalline Hybrid of Molecular Conductors and Molecular Rotors. Journal of the American Chemical Society 2012, 134 (18) , 7880-7891. https://doi.org/10.1021/ja301484b
  19. J. Alberto Rodríguez-Velamazán, Miguel A. González, José A. Real, Miguel Castro, M. Carmen Muñoz, Ana B. Gaspar, Ryo Ohtani, Masaaki Ohba, Ko Yoneda, Yuh Hijikata, Nobuhiro Yanai, Motohiro Mizuno, Hideo Ando, and Susumu Kitagawa . A Switchable Molecular Rotator: Neutron Spectroscopy Study on a Polymeric Spin-Crossover Compound. Journal of the American Chemical Society 2012, 134 (11) , 5083-5089. https://doi.org/10.1021/ja206228n
  20. Cortnie S. Vogelsberg, Silvia Bracco, Mario Beretta, Angiolina Comotti, Piero Sozzani, and Miguel A. Garcia-Garibay . Dynamics of Molecular Rotors Confined in Two Dimensions: Transition from a 2D Rotational Glass to a 2D Rotational Fluid in a Periodic Mesoporous Organosilica. The Journal of Physical Chemistry B 2012, 116 (5) , 1623-1632. https://doi.org/10.1021/jp2119263
  21. Patrick Commins, Jose E. Nuñez, and Miguel A. Garcia-Garibay . Synthesis of Bridged Molecular Gyroscopes with Closed Topologies: Triple One-Pot Macrocyclization. The Journal of Organic Chemistry 2011, 76 (20) , 8355-8363. https://doi.org/10.1021/jo201513y
  22. Palanisamy Rajakannu, Bhaskaran Shankar, Anju Yadav, Ramasamy Shanmugam, Deepak Gupta, Firasat Hussain, Che-Hao Chang, Malaichamy Sathiyendiran, and Kuang-Lieh Lu . Adaptation toward Restricted Conformational Dynamics: From the Series of Neutral Molecular Rotors. Organometallics 2011, 30 (11) , 3168-3176. https://doi.org/10.1021/om200269z
  23. Cyprien Lemouchi, Cortnie S. Vogelsberg, Leokadiya Zorina, Sergey Simonov, Patrick Batail, Stuart Brown, and Miguel A. Garcia-Garibay . Ultra-fast Rotors for Molecular Machines and Functional Materials via Halogen Bonding: Crystals of 1,4-Bis(iodoethynyl)bicyclo[2.2.2]octane with Distinct Gigahertz Rotation at Two Sites. Journal of the American Chemical Society 2011, 133 (16) , 6371-6379. https://doi.org/10.1021/ja200503j
  24. Qiong Ye, Tomoyuki Akutagawa, Toru Endo, Shin-ichiro Noro, Takayoshi Nakamura, and Ren-Gen Xiong . Asymmetrical [Ni(dmit)2]− Arrangements Induced by (1R,2R)-Cyclohexanediammonium - Crown Ether Supramolecules. Inorganic Chemistry 2010, 49 (18) , 8591-8600. https://doi.org/10.1021/ic101253g
  25. Zachary J. O’Brien, Steven D. Karlen, Saeed Khan and Miguel A. Garcia-Garibay. Solid-State Molecular Rotors with Perdeuterated Stators: Mechanistic Insights from Biphenylene Rotational Dynamics in Ordered and Disordered Crystal Forms. The Journal of Organic Chemistry 2010, 75 (8) , 2482-2491. https://doi.org/10.1021/jo9025176
  26. Shuangquan Zang, Xiaoming Ren, Yang Su, You Song, Wenjun Tong, Zhaoping Ni, Hanhua Zhao, Song Gao and Qingjin Meng . Observation of Magnetic Bistability in Polymorphs of the [Ni(dmit)2]− Complexes. Inorganic Chemistry 2009, 48 (20) , 9623-9630. https://doi.org/10.1021/ic900090e
  27. Tomoyuki Akutagawa, Kozo Shitagami, Masaki Aonuma, Shin-ichiro Noro and Takayoshi Nakamura . Ferromagnetic and Antiferromagnetic Coupling of [Ni(dmit)2]− Anion Layers Induced by Cs+2(benzo[18]crown-6)3 Supramolecule. Inorganic Chemistry 2009, 48 (10) , 4454-4461. https://doi.org/10.1021/ic9001847
  28. Tomoyuki Akutagawa, Daisuke Sato, Hiroyuki Koshinaka, Masaaki Aonuma, Shin-ichiro Noro, Sadamu Takeda and Takayoshi Nakamura . Solid-State Molecular Rotators of Anilinium and Adamantylammonium in [Ni(dmit)2]− Salts with Diverse Magnetic Properties. Inorganic Chemistry 2008, 47 (13) , 5951-5962. https://doi.org/10.1021/ic800271m
  29. Tomoyuki Akutagawa, Daigoro Endo, Fumito Kudo, Shin-ichiro Noro, Sadamu Takeda, Leroy Cronin and Takayoshi Nakamura . A Solid-State Supramolecular Rotator Assembled from a Cs-crown Ether Polyoxometalate Hybrid: (Cs+)3([18]crown-6)3(H+)2[PMo12O40]. Crystal Growth & Design 2008, 8 (3) , 812-816. https://doi.org/10.1021/cg060951+
  30. Daisuke Sato,, Tomoyuki Akutagawa,, Sadamu Takeda,, Shin-ichiro Noro, and, Takayoshi Nakamura. Supramolecular Rotor:  Adamantylammonium([18]crown-6) in [Ni(dmit)2]- Salt. Inorganic Chemistry 2007, 46 (2) , 363-365. https://doi.org/10.1021/ic061831u
  31. Tomoyuki Akutagawa,, Daigoro Endo,, Hiroyuki Imai,, Shin-ichiro Noro,, Leroy Cronin, and, Takayoshi Nakamura. Formation of p-Phenylenediamine−Crown Ether−[PMo12O40]4- Salts. Inorganic Chemistry 2006, 45 (21) , 8628-8637. https://doi.org/10.1021/ic060857i
  32. Tomoyuki Akutagawa,, Takeshi Motokizawa,, Kazumasa Matsuura,, Sadafumi Nishihara,, Shin-ichiro Noro, and, Takayoshi Nakamura. Structural Phase Transition of Magnetic [Ni(dmit)2]- Salts Induced by Supramolecular Cation Structures of (M+)([12]crown-4)2. The Journal of Physical Chemistry B 2006, 110 (12) , 5897-5904. https://doi.org/10.1021/jp055574a
  33. Zhaoping Ni,, Xiaoming Ren,, Jing Ma,, Jingli Xie,, Chunlin Ni,, Zhida Chen, and, Qingjin Meng. Theoretical Studies on the Magnetic Switching Controlled by Stacking Patterns of Bis(maleonitriledithiolato) Nickelate(III) Dimers. Journal of the American Chemical Society 2005, 127 (41) , 14330-14338. https://doi.org/10.1021/ja050631z
  34. Tomoyuki Akutagawa,, Kazumasa Matsuura,, Asako Hashimoto, and, Takayoshi Nakamura. Magnetism of [Ni(dmit)2] Salts with [Meso- and (1S, 2S)-Diphenyl-1,2-Ethanediammonium]([18]crown-6)2 Supramolecular Cations. Inorganic Chemistry 2005, 44 (13) , 4454-4456. https://doi.org/10.1021/ic050241d
  35. Yuto Shimoyama, Sayaka Uchida. Structure-function Relationships of Porous Ionic Crystals (PICs) Based on Polyoxometalate Anions and Oxo-centered Trinuclear Metal Carboxylates as Counter Cations. Chemistry Letters 2021, 50 (1) , 21-30. https://doi.org/10.1246/cl.200603
  36. Kazuya Saito. Importance of Molecular Crystals. 2020,,, 199-220. https://doi.org/10.1007/978-981-15-9023-8_10
  37. Kazuya Saito. Chemical Physics of Molecular Condensed Matter. 2020,,https://doi.org/10.1007/978-981-15-9023-8
  38. Elżbieta Szostak, Dawid Pinkowicz, Patryk Fryń, Monika Marzec. Investigation of correlation between phase transformations and changes in structural, dynamic, magnetic and dielectric properties of hexakis-DMSO cobalt (II) complex. Journal of Molecular Structure 2019, 1194 , 227-235. https://doi.org/10.1016/j.molstruc.2019.05.069
  39. Naoki Ogiwara, Daniil I. Kolokolov, Masaki Donoshita, Hirokazu Kobayashi, Satoshi Horike, Alexander G. Stepanov, Hiroshi Kitagawa. The effect of amorphization on the molecular motion of the 2-methylimidazolate linkers in ZIF-8. Chemical Communications 2019, 55 (42) , 5906-5909. https://doi.org/10.1039/C9CC02673H
  40. Yuki Shirakawa, Kiyonori Takahashi, Hiroyasu Sato, Norihisa Hoshino, Hayato Anetai, Shin‐ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura. Hydrogen‐Bonded Polyrotaxane Cation Structure in Nickel Dithiolate Anion Radical Salts: Ferromagnetic and Semiconducting Behavior Associated with Structural Phase Transition. Chemistry – A European Journal 2019, 25 (28) , 6920-6927. https://doi.org/10.1002/chem.201806230
  41. Katsuya Ichihashi, Daisuke Konno, Kseniya Yu. Maryunina, Katsuya Inoue, Kazuhiro Toyoda, Shogo Kawaguchi, Yoshiki Kubota, Yoko Tatewaki, Tomoyuki Akutagawa, Takayoshi Nakamura, Sadafumi Nishihara. Selective Ion Exchange in Supramolecular Channels in the Crystalline State. Angewandte Chemie 2019, 131 (13) , 4213-4216. https://doi.org/10.1002/ange.201813709
  42. Katsuya Ichihashi, Daisuke Konno, Kseniya Yu. Maryunina, Katsuya Inoue, Kazuhiro Toyoda, Shogo Kawaguchi, Yoshiki Kubota, Yoko Tatewaki, Tomoyuki Akutagawa, Takayoshi Nakamura, Sadafumi Nishihara. Selective Ion Exchange in Supramolecular Channels in the Crystalline State. Angewandte Chemie International Edition 2019, 58 (13) , 4169-4172. https://doi.org/10.1002/anie.201813709
  43. Jun Xiong, Kazuya Kubo, Shao-Fang Lü, Ming Li, Takayoshi Nakamura. Supramolecular self-assembly for designing non-centrosymmetric crystals based on Keggin polyoxometallates and crown ether. Dalton Transactions 2018, 47 (39) , 14001-14007. https://doi.org/10.1039/C8DT02910E
  44. Munehiro Inukai, Masanori Tamura, Satoshi Horike, Masakazu Higuchi, Susumu Kitagawa, Koichi Nakamura. Storage of CO 2 into Porous Coordination Polymer Controlled by Molecular Rotor Dynamics. Angewandte Chemie 2018, 130 (28) , 8823-8826. https://doi.org/10.1002/ange.201805111
  45. Munehiro Inukai, Masanori Tamura, Satoshi Horike, Masakazu Higuchi, Susumu Kitagawa, Koichi Nakamura. Storage of CO 2 into Porous Coordination Polymer Controlled by Molecular Rotor Dynamics. Angewandte Chemie International Edition 2018, 57 (28) , 8687-8690. https://doi.org/10.1002/anie.201805111
  46. Guo-Jun Yuan, Shao-Xian Liu, Zheng-Fang Tian, Xiao-Ming Ren. A high temperature reversible phase transition in a supramolecular complex of 15-crown-5 with tetraphenylboron sodium. New Journal of Chemistry 2018, 42 (18) , 14943-14948. https://doi.org/10.1039/C8NJ02754D
  47. Yuan Chen, Yang Liu, Binzu Gao, Chuli Zhu, Zunqi Liu. Inorganic Anions Regulate the Phase Transition in Two Organic Cation Salts Containing [(4-Nitroanilinium)(18-crown-6)]+ Supramolecules. Crystals 2017, 7 (7) , 224. https://doi.org/10.3390/cryst7070224
  48. Fu-Juan Geng, De-Hong Wu, Lin Zhou, Ping-Ping Shi, Peng-Fei Li, Ji-Xing Gao, Xuan Zheng, Da-Wei Fu, Qiong Ye. Photoluminescent-dielectric duple switch in a perovskite-type high-temperature phase transition compound: [(CH 3 ) 3 PCH 2 OCH 3 ][PbBr 3 ]. Dalton Transactions 2017, 46 (29) , 9528-9534. https://doi.org/10.1039/C7DT01780D
  49. Yang Lu, Xiu-Ni Hua, Wei-Qiang Liao, Ji-Xing Gao, Zi Yin. A room temperature reversible phase transition containing dielectric switching of a host–guest supramolecular metal–halide compound. Dalton Transactions 2017, 46 (38) , 12760-12765. https://doi.org/10.1039/C7DT02607B
  50. Yukihiro Yoshida, Kazuhide Isomura, Yoshihide Kumagai, Mitsuhiko Maesato, Hideo Kishida, Motohiro Mizuno, Gunzi Saito. Coronene-based charge-transfer complexes. Journal of Physics: Condensed Matter 2016, 28 (30) , 304001. https://doi.org/10.1088/0953-8984/28/30/304001
  51. Qiong Ye, Lin Zhou, Hui-Ting Wang, Li-Hui Kong, Xuan Zheng, Da-Wei Fu. Sequential Phase Transitions Near Room Temperature in a Metal-Crown Ether Compound SbBr 3 (15-Crown-5). ChemistrySelect 2016, 1 (12) , 3144-3149. https://doi.org/10.1002/slct.201600841
  52. Qiong Ye, Hui-Ting Wang, Lin Zhou, Li-Hui Kong, Heng-Yun Ye, Da-Wei Fu, Yi Zhang. Phase transition metal–crown ether coordination compounds tuned by metal ions. Dalton Transactions 2016, 45 (3) , 1000-1006. https://doi.org/10.1039/C5DT02631H
  53. Chengmin Ji, Shenhui Li, Feng Deng, Sijie Liu, Muhammad Adnan Asghar, Zhihua Sun, Maochun Hong, Junhua Luo. Bistable N–H⋯N hydrogen bonds for reversibly modulating the dynamic motion in an organic co-crystal. Physical Chemistry Chemical Physics 2016, 18 (16) , 10868-10872. https://doi.org/10.1039/C6CP01073C
  54. Xiaoguang Liu, Ling Li, Hyeon Mi Noh, Sung Heum Park, Jung Hyun Jeong, Hyun Kyoung Yang, Kiwan Jang, Dong Soo Shin. Synthesis and photoluminescence of novel 3D flower-like CaMoO4 architectures hierarchically self-assembled with tetragonal bipyramid nanocrystals. Optical Materials 2015, 43 , 10-17. https://doi.org/10.1016/j.optmat.2015.02.014
  55. J. Xiong, K. Kubo, S. Noro, T. Akutagawa, T. Nakamura. Supramolecular cations of (m-halogenated-anilinium)(dibenzo[18]crown-6) in Keggin [SMo 12 O 40 2− ] polyoxometallates. CrystEngComm 2015, 17 (4) , 856-861. https://doi.org/10.1039/C4CE01988A
  56. Hao Yang, De-Yue An, Jian-Lan Liu, Xiao-Ming Ren, Lan-Cheng Zhou, Hua-Bing Wang. Observation of a magnetic phase transition but absence of an electrical response in a new two-dimensional mixed-valence nickel-bis-dithiolene molecular crystal. RSC Advances 2015, 5 (18) , 13857-13866. https://doi.org/10.1039/C4RA13354D
  57. Wei-Hua Ning, Lu Zhai, Jian-Lan Liu, Xiao-Ming Ren, Katsuya Ichihashi, Sadafumi Nishihara, Katsuya Inoue. Multiple structural transformations coupled with switchable magnetic and dielectric responses in an amphidynamic crystal of 4′-tert-butylbenzylpyridinium bis(maleonitriledithiolate)nickelate. Journal of Materials Chemistry C 2015, 3 (30) , 7906-7915. https://doi.org/10.1039/C5TC00676G
  58. Yan-Hong Peng, Zong-Xiang Xu, Cheng-Hui Li, Liang Hu, V.A.L. Roy, Shao-Fa Sun, Jian Wang. Synthesis and characterization of a new series of nickel dithiolate compounds containing both acridinium cations and halogen anions. Inorganica Chimica Acta 2014, 410 , 88-93. https://doi.org/10.1016/j.ica.2013.10.020
  59. Ping-Ping Shi, Su-Wen Sun, Ming-Liang Liu, Li-Hui Kong, Qiong Ye. Temperature-dependent crystal structures and unusual dielectric property in [Me2NH2]2[Ni(mnt)2]. Inorganic Chemistry Communications 2013, 37 , 84-88. https://doi.org/10.1016/j.inoche.2013.09.003
  60. Pounraj Thanasekaran, Chia-Yuan Huang, Kuang-Lieh Lu. Synthesis, Structure, and Dynamic Behavior of Discrete Metallacyclic Rotors. Chemistry Letters 2013, 42 (8) , 776-784. https://doi.org/10.1246/cl.130455
  61. Kazuya Kubo, Yin-Nan Yan, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura. Crystal structure of a supramolecular cation salt (adamantylammonium+)2(benzo[18]crown-6)2[Pd(dmit)2]2−(acetone)2. Inorganica Chimica Acta 2013, 404 , 206-209. https://doi.org/10.1016/j.ica.2013.02.018
  62. Qiong Ye, Ping-Ping Shi, Xue-Qun Fu, Tomoyuki Akutagawa, Takayoshi Nakamura. Dielectric and structural phase transition of [Ni(dmit)2]− salt with (4-ethoxyanilinium)([18]crown-6) supramolecular cation. CrystEngComm 2013, 15 (26) , 5307. https://doi.org/10.1039/c3ce40220g
  63. Mei Xue, Kang L. Wang. Molecular Rotors as Switches. Sensors 2012, 12 (9) , 11612-11637. https://doi.org/10.3390/s120911612
  64. W. Setaka, K. Yamaguchi. Thermal modulation of birefringence observed in a crystalline molecular gyrotop. Proceedings of the National Academy of Sciences 2012, 109 (24) , 9271-9275. https://doi.org/10.1073/pnas.1114733109
  65. Qiong Ye, Ping-Ping Shi, Zi-Qi Chen, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura. [Ni(dmit)2]− salt with flexible supramolecular cation rotator. Inorganic Chemistry Communications 2012, 20 , 219-224. https://doi.org/10.1016/j.inoche.2012.03.012
  66. Daigoro Endo, Tomoyuki Akutagawa, Kazuya Kubo, Shin-ichiro Noro, Leroy Cronin, Takayoshi Nakamura. Molecular Motions and Hydrogen-Bonding Networks in ( o -Aminoanilinium)–(Crown Ethers)–[PMo 12 O 40 ] 4− Crystals. Bulletin of the Chemical Society of Japan 2012, 85 (3) , 305-315. https://doi.org/10.1246/bcsj.20110371
  67. Cortnie S. Vogelsberg, Miguel A. Garcia-Garibay. Crystalline molecular machines: function, phase order, dimensionality, and composition. Chem. Soc. Rev. 2012, 41 (5) , 1892-1910. https://doi.org/10.1039/C1CS15197E
  68. Norihisa Hoshino, Kazuya Kubo, Takayoshi Nakamura, Tomoyuki Akutagawa. Crystal structures and magnetic properties of (4,4′-phenylazophenyl)diammonium(crown ethers)[Ni(dmit)2]2 crystals. Dalton Transactions 2012, 41 (31) , 9297. https://doi.org/10.1039/c2dt30807j
  69. Qiong Ye, Kiyonori Takahashi, Norihisa Hoshino, Takemitsu Kikuchi, Tomoyuki Akutagawa, Shin-ichiro Noro, Sadamu Takeda, Takayoshi Nakamura. Huge Dielectric Response and Molecular Motions in Paddle-Wheel [CuII2(Adamantylcarboxylate)4(DMF)2]⋅(DMF)2. Chemistry - A European Journal 2011, 17 (51) , 14442-14449. https://doi.org/10.1002/chem.201101743
  70. Tomoyuki Akutagawa, Hiroyuki Koshinaka, Qiong Ye, Shin-ichiro Noro, Jun Kawamata, Hiroshi Yamaki, Takayoshi Nakamura. Conformational Polymorph of o -Aminoanilinium(dibenzo[18]crown-6) Supramolecules in [Ni(dmit) 2 ] − Salts. Chemistry - An Asian Journal 2010, 5 (3) , 520-529. https://doi.org/10.1002/asia.200900407
  71. Tomoyuki Akutagawa, Daisuke Sato, Qiong Ye, Shin-ichiro Noro, Takayoshi Nakamura. Ferromagnetic coupling of [Ni(dmit)2]− anions in (m-fluoroanilinium)(dicyclohexano[18]crown-6)[Ni(dmit)2]. Dalton Transactions 2010, 39 (9) , 2191. https://doi.org/10.1039/b920600k
  72. Subbalakshmi Jayanty, Tomoyuki Akutagawa, Takayoshi Nakamura. Highly polar 7,7-bis(N,N-dimethylpiperazinium)-8,8-dicyanoquinodimethane in [Ni(dmit)2]− salt: crystal structure and magnetic properties. CrystEngComm 2010, 12 (12) , 4087. https://doi.org/10.1039/c0ce00322k
  73. Tomoyuki Akutagawa, Daisuke Sato, Qiong Ye, Toru Endo, Shin-ichiro Noro, Sadamu Takeda, Takayoshi Nakamura. [18]Crown-6 rotator in spin-ladder compound of m-aminoanilinium([18]crown-6)[Ni(dmit)2]−. Dalton Transactions 2010, 39 (35) , 8219. https://doi.org/10.1039/c0dt00308e
  74. Hai-Bao Duan, Fang Xuan, Xiao-Ming Ren, Zheng-Fang Tian, Lin-Jiang Shen. Two spin systems based on [Ni(dmit) 2 ] − building blocks exhibiting 1-D chain and 2-D sheet structures: crystal structures and magnetic properties. Journal of Coordination Chemistry 2009, 62 (23) , 3772-3781. https://doi.org/10.1080/00958970903159149
  75. Jean-Benoît Giguère, Dominic Thibeault, Francis Cronier, Jean-Sébastien Marois, Michèle Auger, Jean-François Morin. Synthesis of [2]- and [3]rotaxanes through Sonogashira coupling. Tetrahedron Letters 2009, 50 (39) , 5497-5500. https://doi.org/10.1016/j.tetlet.2009.07.101
  76. Henri-Pierre Jacquot de Rouville, Guillaume Vives, Eva Tur, Jeanne Crassous, Gwénaël Rapenne. Synthesis and analytical resolution of chiral pyrazoles derived from (5R)-dihydrocarvone. New J. Chem. 2009, 33 (2) , 293-299. https://doi.org/10.1039/B812123K
  77. Malaichamy Sathiyendiran, Jing-Yun Wu, Murugesan Velayudham, Gene-Hsiang Lee, Shie-Ming Peng, Kuang-Lieh Lu. Neutral metallacyclic rotors. Chemical Communications 2009, 288 (25) , 3795. https://doi.org/10.1039/b901535c
  78. Tomoyuki Akutagawa, Takayoshi Nakamura. Supramolecular approach for solid state Brownian rotators. Dalton Transactions 2008, 422 (45) , 6335. https://doi.org/10.1039/b808748b
  79. Jacob S. Alexander, Damian G. Allis, Weijie Teng, Karin Ruhlandt-Senge. Alkali Metal Diphenylmethanides: Synthetic, Computational and Structural Studies. Chemistry - A European Journal 2007, 13 (35) , 9899-9911. https://doi.org/10.1002/chem.200700763
  80. Sadafumi Nishihara, Tomoyuki Akutagawa, Daisuke Sato, Sadamu Takeda, Shin-ichiro Noro, Takayoshi Nakamura. Multirotations of (Anilinium)([18]Crown-6) Supramolecular Cation Structure in Magnetic Salt of [Ni(dmit)2]−. Chemistry – An Asian Journal 2007, 2 (9) , 1083-1090. https://doi.org/10.1002/asia.200700010
  81. Christine Walbaum, Ingo Pantenburg, Gerd Meyer. Komplexe einwertiger Dibenzo-18-Krone-6-Kationen mit Triiodid als Anionen. Zeitschrift für anorganische und allgemeine Chemie 2007, 633 (10) , 1609-1617. https://doi.org/10.1002/zaac.200700080
  82. Euan R. Kay, David A. Leigh, Francesco Zerbetto. Synthetische molekulare Motoren und mechanische Maschinen. Angewandte Chemie 2007, 119 (1-2) , 72-196. https://doi.org/10.1002/ange.200504313
  83. Euan R. Kay, David A. Leigh, Francesco Zerbetto. Synthetic Molecular Motors and Mechanical Machines. Angewandte Chemie International Edition 2007, 46 (1-2) , 72-191. https://doi.org/10.1002/anie.200504313
  84. Satoshi Horike, Ryotaro Matsuda, Daisuke Tanaka, Seijiro Matsubara, Motohiro Mizuno, Kazunaka Endo, Susumu Kitagawa. Dynamic Motion of Building Blocks in Porous Coordination Polymers. Angewandte Chemie 2006, 118 (43) , 7384-7388. https://doi.org/10.1002/ange.200603196
  85. Satoshi Horike, Ryotaro Matsuda, Daisuke Tanaka, Seijiro Matsubara, Motohiro Mizuno, Kazunaka Endo, Susumu Kitagawa. Dynamic Motion of Building Blocks in Porous Coordination Polymers. Angewandte Chemie International Edition 2006, 45 (43) , 7226-7230. https://doi.org/10.1002/anie.200603196
  86. Guillaume Vives, Alexandre Carella, St?phanie Sistach, Jean-Pierre Launay, Gw?na?l Rapenne. Synthesis of triester-functionalized molecular motors incorporating bis-acetylide trans-platinum insulating fragments. New Journal of Chemistry 2006, 30 (10) , 1429. https://doi.org/10.1039/b605509e
  87. Tomoyuki Akutagawa, Kazumasa Matsuura, Sadafumi Nishihara, Shin-ichiro Noro, Takayoshi Nakamura. Supramolecular Cations of (S)-, (R)-, and (RS)-Indan-1-aminium(dibenzo[18]crown-6) in Magnetic [Ni(dmit)2]- Salts. European Journal of Inorganic Chemistry 2005, 2005 (16) , 3271-3276. https://doi.org/10.1002/ejic.200500131
  88. Satoaki Ikeuchi, Yuji Miyazaki, Sadamu Takeda, Tomoyuki Akutagawa, Sadafumi Nishihara, Takayoshi Nakamura, Kazuya Saito. Cooperativity of dynamics of 18-crown-6 molecule forming one-dimensional chain in Cs2(18-crown-6)3[Ni(dmit)2]2. The Journal of Chemical Physics 2005, 123 (4) , 044514. https://doi.org/10.1063/1.1979481

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

OOPS

You have to login with your ACS ID befor you can login with your Mendeley account.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect

This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy.

CONTINUE