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Activation of a SiSi Bond by η1-Coordination to a Transition Metal

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Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany
Cite this: J. Am. Chem. Soc. 2005, 127, 29, 10174–10175
Publication Date (Web):July 1, 2005
https://doi.org/10.1021/ja052593p
Copyright © 2005 American Chemical Society
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Abstract

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Reaction of the disilenide 1 with Cp2ZrCl2 yields 2, the first transition metal complex with an η1-σ-bonded disilene moiety. The compound 2 exhibits a strongly red-shifted UV−vis absorption, resulting in an intensely green color. The SiSi bond in 2 is considerably activated as shown by the rearrangement to a silyl-substituted zirconocene 3. X-ray diffraction studies on 2 reveal that the SiSi bond is significantly longer than that in the precursor 1. Conversely, the Zr−Si distance is considerably smaller than the corresponding distance in 3, suggesting a certain degree of electron donation toward the 16e- zirconium center.

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Details of the synthesis and structure determinations of 2 and 3. The X-ray crystallographic data are supplied in CIF format. This material is available free of charge via the Internet at http://pubs.acs.org.

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