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Large-Scale Synthesis of Thiolated Au25 Clusters via Ligand Exchange Reactions of Phosphine-Stabilized Au11 Clusters

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School of Materials Science, Japan Advanced Institute of Science and Technology, 1-1 Asahidai, Nomi, Ishikawa 923-1292, Japan, Research Center for Molecular-Scale Nanoscience, Institute for Molecular Science, Myodaiji, Okazaki 444-8585, Japan, and Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan
Cite this: J. Am. Chem. Soc. 2005, 127, 39, 13464–13465
Publication Date (Web):September 8, 2005
https://doi.org/10.1021/ja053915s
Copyright © 2005 American Chemical Society
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Abstract

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Phosphine-stabilized Au11 clusters in chloroform were reacted with glutathione (GSH) in water under a nitrogen atmosphere. The resulting Au:SG clusters exhibit an optical absorption spectrum similar to that of Au25(SG)18, which was isolated as one of the major products from chemically prepared Au:SG clusters (Negishi, Y. et al. J. Am. Chem. Soc.2005, 127, 5261). Rigorous characterization by optical spectroscopy, electrospray ionization mass spectrometry, and polyacrylamide gel electrophoresis confirms that the Au25(SG)18 clusters were selectively obtained on the sub-100 mg scale by ligand exchange reaction under aerobic conditions. The ligand exchange strategy offers a practical and convenient method of synthesizing thiolated Au25 clusters on a large scale.

†

 Japan Advanced Institute of Science and Technology.

‡

 Institute for Molecular Science.

*

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

§

 University of Tsukuba.

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