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One-Electron Reduction of Kinetically Stabilized Dipnictenes:  Synthesis of Dipnictene Anion Radicals

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Contribution from the Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan, Department of Chemistry, School of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan, and Department of Theoretical Molecular Science, Institute for Molecular Science, Myodaiji, Okazaki 444-8585, Japan
Cite this: J. Am. Chem. Soc. 2006, 128, 38, 12582–12588
Publication Date (Web):September 1, 2006
https://doi.org/10.1021/ja064062m
Copyright © 2006 American Chemical Society
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Abstract

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The redox behavior of kinetically stabilized dipnictenes, BbtEEBbt [E = P, Sb, Bi; Bbt = 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl], was systematically disclosed using cyclic voltammetry and theoretical calculations. It was found that they showed reversible one-electron redox couples in the reduction region. The anion radical species of the Bbt-substituted diphosphene and distibene were successfully synthesized by the reduction of the corresponding neutral dipnictenes (BbtPPBbt and BbtSbSbBbt). Their structures were reasonably characterized by ESR, UV−vis, and Raman spectroscopy, and the distibene anion radical was structurally characterized by X-ray crystallographic analysis.

†

 Kyoto University.

‡

 Osaka City University.

§

 Waseda University.

‖

 Institute for Molecular Science.

*

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

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X-ray crystallographic data of [Li+(dme)3][2b•-] in a CIF format. Complete ref 29 and the optimized coordinates of the model compounds in PDF format. This material is available free of charge via the Internet at http://pubs.acs.org.

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  2. Christoph Helling, Christoph Wölper, Yannick Schulte, George E. Cutsail III, Stephan Schulz. Synthesis of a Ga-Stabilized As-Centered Radical and a Gallastibene by Tailoring Group 15 Element–Carbon Bond Strengths. Inorganic Chemistry 2019, 58 (15) , 10323-10332. https://doi.org/10.1021/acs.inorgchem.9b01519
  3. Gengwen Tan, Shuyu Li, Sheng Chen, Yunxia Sui, Yue Zhao, and Xinping Wang . Isolable Diphosphorus-Centered Radical Anion and Diradical Dianion. Journal of the American Chemical Society 2016, 138 (21) , 6735-6738. https://doi.org/10.1021/jacs.6b04081
  4. Yuzhong Wang and Gregory H. Robinson . N-Heterocyclic Carbene—Main-Group Chemistry: A Rapidly Evolving Field. Inorganic Chemistry 2014, 53 (22) , 11815-11832. https://doi.org/10.1021/ic502231m
  5. Xiaobo Pan, Xingyong Wang, Yue Zhao, Yunxia Sui, and Xinping Wang . A Crystalline Phosphaalkene Radical Anion. Journal of the American Chemical Society 2014, 136 (28) , 9834-9837. https://doi.org/10.1021/ja504001x
  6. Yuanting Su, Xin Zheng, Xingyong Wang, Xuan Zhang, Yunxia Sui, and Xinping Wang . Two Stable Phosphorus-Containing Four-Membered Ring Radical Cations with Inverse Spin Density Distributions. Journal of the American Chemical Society 2014, 136 (17) , 6251-6254. https://doi.org/10.1021/ja502675d
  7. Xiaobo Pan, Xiaoyu Chen, Tao Li, Yizhi Li, and Xinping Wang . Isolation and X-ray Crystal Structures of Triarylphosphine Radical Cations. Journal of the American Chemical Society 2013, 135 (9) , 3414-3417. https://doi.org/10.1021/ja4012113
  8. Mariham Y. Abraham, Yuzhong Wang, Yaoming Xie, Robert J. Gilliard, Jr., Pingrong Wei, Brian J. Vaccaro, Michael K. Johnson, Henry F. Schaefer, III, Paul v. R. Schleyer, and Gregory H. Robinson . Oxidation of Carbene-Stabilized Diarsenic: Diarsene Dications and Diarsenic Radical Cations. Journal of the American Chemical Society 2013, 135 (7) , 2486-2488. https://doi.org/10.1021/ja400219d
  9. Tanja Sanden, Michael T. Gamer, Anatoly A. Fagin, Valentina A. Chudakova, Sergey N. Konchenko, Igor L. Fedushkin, and Peter W. Roesky . Synthesis of Unsupported Ln–Ga Bonds by Salt Metathesis and Ga–Ga Bond Reduction. Organometallics 2012, 31 (11) , 4331-4339. https://doi.org/10.1021/om300309b
  10. Tomohiro Agou, Yusuke Sugiyama, Takahiro Sasamori, Heisuke Sakai, Yukio Furukawa, Nozomi Takagi, Jing-Dong Guo, Shigeru Nagase, Daisuke Hashizume, and Norihiro Tokitoh . Synthesis of Kinetically Stabilized 1,2-Dihydrodisilenes. Journal of the American Chemical Society 2012, 134 (9) , 4120-4123. https://doi.org/10.1021/ja300694p
  11. Shintaro Ishida, Fumiya Hirakawa, and Takeaki Iwamoto . A Stable Dialkylphosphinyl Radical. Journal of the American Chemical Society 2011, 133 (33) , 12968-12971. https://doi.org/10.1021/ja205001m
  12. Marlena P. Washington, John L. Payton, M. Cather Simpson, and John D. Protasiewicz . Redox Behavior of 2-Substituted 1,3-Benzoxaphospholes and 2,6-Substituted Benzo[1,2-d:4,5-d′]bisoxaphospholes. Organometallics 2011, 30 (7) , 1975-1983. https://doi.org/10.1021/om200014f
  13. Olivier Back, Mehmet Ali Celik, Gernot Frenking, Mohand Melaimi, Bruno Donnadieu and Guy Bertrand . A Crystalline Phosphinyl Radical Cation. Journal of the American Chemical Society 2010, 132 (30) , 10262-10263. https://doi.org/10.1021/ja1046846
  14. Noriyoshi Nagahora, Takahiro Sasamori and Norihiro Tokitoh. A Ferrocenyldiphosphene−Platinum Complex: Structural Features and Theoretical Calculations. Organometallics 2008, 27 (16) , 4265-4268. https://doi.org/10.1021/om800315q
  15. Takeshi Matsumoto, Takahiro Sasamori, Kazunobu Sato, Takeji Takui and Norihiro Tokitoh. Reduction of a Kinetically Stabilized Silabenzene Leading to the Formation of the Corresponding Anion Radical Species. Organometallics 2008, 27 (3) , 305-308. https://doi.org/10.1021/om701060a
  16. Hans J. Breunig,, Tobias Borrmann,, Enno Lork,, Ciprian I. Raţ, and, Uwe Rosenthal. Syntheses and Structures of Distibene Complexes of Tungsten and Titanium:  [W(CO)5{(2,6-Mes2C6H3)2Sb2}] (Mes = 2,4,6-Me3C6H2) and [Cp2Ti{(2,6-Mes2C6H3)2Sb2)}]. Organometallics 2007, 26 (22) , 5364-5368. https://doi.org/10.1021/om700681w
  17. Shaun P. Green,, Cameron Jones,, Guoxia Jin, and, Andreas Stasch. Base-Stabilized Amidodiarsenes:  Synthesis, Structure, and Theoretical Studies. Inorganic Chemistry 2007, 46 (1) , 8-10. https://doi.org/10.1021/ic062163f
  18. Crispin Lichtenberg. Radical Compounds of Antimony and Bismuth. 2020,,, 1-12. https://doi.org/10.1002/9781119951438.eibc2751
  19. . Encyclopedia of Inorganic and Bioinorganic Chemistry. 2011,,https://doi.org/10.1002/9781119951438
  20. Christoph Helling, Christoph Wölper, George E. Cutsail, Gebhard Haberhauer, Stephan Schulz. A Mechanistic Study on Reactions of Group 13 Diyls LM with Cp*SbX 2 : From Stibanyl Radicals to Antimony Hydrides. Chemistry – A European Journal 2020, 26 (59) , 13390-13399. https://doi.org/10.1002/chem.202001739
  21. George E. Cutsail. Applications of electron paramagnetic resonance spectroscopy to heavy main-group radicals. Dalton Transactions 2020, 49 (35) , 12128-12135. https://doi.org/10.1039/D0DT02436H
  22. Christoph Helling, Stephan Schulz. Long‐Lived Radicals of the Heavier Group 15 Elements Arsenic, Antimony, and Bismuth. European Journal of Inorganic Chemistry 2020, 2020 (34) , 3209-3221. https://doi.org/10.1002/ejic.202000571
  23. Crispin Lichtenberg. Main‐Group Metal Complexes in Selective Bond Formations Through Radical Pathways. Chemistry – A European Journal 2020, 26 (44) , 9674-9687. https://doi.org/10.1002/chem.202000194
  24. Christoph Helling, George E. Cutsail, Hanns Weinert, Christoph Wölper, Stephan Schulz. Ligand Effects on the Electronic Structure of Heteroleptic Antimony‐Centered Radicals. Angewandte Chemie 2020, 132 (19) , 7631-7638. https://doi.org/10.1002/ange.202000586
  25. Christoph Helling, George E. Cutsail, Hanns Weinert, Christoph Wölper, Stephan Schulz. Ligand Effects on the Electronic Structure of Heteroleptic Antimony‐Centered Radicals. Angewandte Chemie International Edition 2020, 59 (19) , 7561-7568. https://doi.org/10.1002/anie.202000586
  26. Wenqing Wang, Gengwen Tan, Rui Feng, Yong Fang, Chao Chen, Huapeng Ruan, Yue Zhao, Xinping Wang. Stable, yet “naked”, azo radical anion ArNNAr − and dianion ArNNAr 2− (Ar = 4-CN-2,6- i Pr 2 -C 6 H 2 ) with selective CO 2 activation. Chemical Communications 2020, 56 (22) , 3285-3288. https://doi.org/10.1039/C9CC07382E
  27. Haiyan Cui, Dengmengfei Xiao, Li Zhang, Huapeng Ruan, Yong Fang, Yue Zhao, Gengwen Tan, Lili Zhao, Gernot Frenking, Matthias Driess, Xinping Wang. Isolable cyclic radical cations of heavy main-group elements. Chemical Communications 2020, 56 (14) , 2167-2170. https://doi.org/10.1039/C9CC09582A
  28. Mahendra K. Sharma, Sebastian Blomeyer, Beate Neumann, Hans‐Georg Stammler, Maurice Gastel, Alexander Hinz, Rajendra S. Ghadwal. Crystalline Divinyldiarsene Radical Cations and Dications. Angewandte Chemie 2019, 131 (49) , 17763-17767. https://doi.org/10.1002/ange.201909144
  29. Mahendra K. Sharma, Sebastian Blomeyer, Beate Neumann, Hans‐Georg Stammler, Maurice Gastel, Alexander Hinz, Rajendra S. Ghadwal. Crystalline Divinyldiarsene Radical Cations and Dications. Angewandte Chemie International Edition 2019, 58 (49) , 17599-17603. https://doi.org/10.1002/anie.201909144
  30. Ryan J. Schwamm, Martyn P. Coles. Distibanes and Distibenes from Reduction of Sb(NON R )Cl by using Mg I Reagents. Chemistry – A European Journal 2019, 25 (62) , 14183-14191. https://doi.org/10.1002/chem.201903175
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  32. Manas Kumar Mondal, Li Zhang, Zhongtao Feng, Shuxuan Tang, Rui Feng, Yue Zhao, Gengwen Tan, Huapeng Ruan, Xinping Wang. Tricoordinate Nontrigonal Pnictogen‐Centered Radical Anions: Isolation, Characterization, and Reactivity. Angewandte Chemie 2019, 131 (44) , 15976-15980. https://doi.org/10.1002/ange.201910139
  33. Manas Kumar Mondal, Li Zhang, Zhongtao Feng, Shuxuan Tang, Rui Feng, Yue Zhao, Gengwen Tan, Huapeng Ruan, Xinping Wang. Tricoordinate Nontrigonal Pnictogen‐Centered Radical Anions: Isolation, Characterization, and Reactivity. Angewandte Chemie International Edition 2019, 58 (44) , 15829-15833. https://doi.org/10.1002/anie.201910139
  34. Jacqueline Ramler, Jordi Poater, Florian Hirsch, Benedikt Ritschel, Ingo Fischer, F. Matthias Bickelhaupt, Crispin Lichtenberg. Carbon monoxide insertion at a heavy p-block element: unprecedented formation of a cationic bismuth carbamoyl. Chemical Science 2019, 10 (15) , 4169-4176. https://doi.org/10.1039/C9SC00278B
  35. Guocang Wang, Lucas A. Freeman, Diane A. Dickie, Réka Mokrai, Zoltán Benkő, Robert J. Gilliard. Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex. Chemistry – A European Journal 2019, 25 (17) , 4335-4339. https://doi.org/10.1002/chem.201900458
  36. Liu Leo Liu, Levy L. Cao, Jiliang Zhou, Douglas W. Stephan. Facile Cleavage of the P=P Double Bond in Vinyl-Substituted Diphosphenes. Angewandte Chemie 2019, 131 (1) , 279-283. https://doi.org/10.1002/ange.201812592
  37. Liu Leo Liu, Levy L. Cao, Jiliang Zhou, Douglas W. Stephan. Facile Cleavage of the P=P Double Bond in Vinyl-Substituted Diphosphenes. Angewandte Chemie International Edition 2019, 58 (1) , 273-277. https://doi.org/10.1002/anie.201812592
  38. Maciej Witwicki. Density functional theory and ab initio studies on hyperfine coupling constants of phosphinyl radicals. International Journal of Quantum Chemistry 2018, 118 (23) , e25779. https://doi.org/10.1002/qua.25779
  39. Chelladurai Ganesamoorthy, Christoph Helling, Christoph Wölper, Walter Frank, Eckhard Bill, George E. Cutsail, Stephan Schulz. From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond. Nature Communications 2018, 9 (1) https://doi.org/10.1038/s41467-017-02581-2
  40. Julia Krüger, Juliane Schoening, Chelladurai Ganesamoorthy, Lukas John, Christoph Wölper, Stephan Schulz. Synthesis and X-ray Crystal Structures of Ga-substituted Distibenes [L( X )GaSb] 2. Zeitschrift für anorganische und allgemeine Chemie 2018, 644 (17) , 1028-1033. https://doi.org/10.1002/zaac.201800204
  41. Gengwen Tan, Xinping Wang. Isolable Radical Ions of Main-Group Elements: Structures, Bonding and Properties. Chinese Journal of Chemistry 2018, 36 (7) , 573-586. https://doi.org/10.1002/cjoc.201700802
  42. Alexander Hinz, Jose M. Goicoechea. Limitations of Steric Bulk: Towards Phospha‐germynes and Phospha‐stannynes. Chemistry – A European Journal 2018, 24 (29) , 7358-7363. https://doi.org/10.1002/chem.201801329
  43. Iva Vránová, Tereza Dušková, Milan Erben, Roman Jambor, Aleš Růžička, Libor Dostál. Trapping of the N,C,N-chelated organobismuth(I) compound, [2,6-(Me2NCH2)2C6H3]Bi, by its coordination toward selected transition metal fragments. Journal of Organometallic Chemistry 2018, 863 , 15-20. https://doi.org/10.1016/j.jorganchem.2018.03.024
  44. Pere Vilarrubias. The dipnictenes R-E=E′-R′ (E=P, As, Sb, Bi) revisited: a TDDFT and multi-reference study of some aspects of its electronic spectroscopy. Molecular Physics 2017, 115 (20) , 2597-2604. https://doi.org/10.1080/00268976.2017.1338366
  45. Gengwen Tan, Jing Li, Li Zhang, Chao Chen, Yue Zhao, Xinping Wang, You Song, Yi‐Quan Zhang, Matthias Driess. The Charge Transfer Approach to Heavier Main‐Group Element Radicals in Transition‐Metal Complexes. Angewandte Chemie 2017, 129 (41) , 12915-12919. https://doi.org/10.1002/ange.201707501
  46. Gengwen Tan, Jing Li, Li Zhang, Chao Chen, Yue Zhao, Xinping Wang, You Song, Yi‐Quan Zhang, Matthias Driess. The Charge Transfer Approach to Heavier Main‐Group Element Radicals in Transition‐Metal Complexes. Angewandte Chemie International Edition 2017, 56 (41) , 12741-12745. https://doi.org/10.1002/anie.201707501
  47. Shun-suke Asami, Katsunori Suzuki, Makoto Yamashita. Two-electron Reduction of Diboryldiphosphene: Formation of Intramolecular Charge-transfer Complex of Dianionic B − =P–P=B − Species. Chemistry Letters 2017, 46 (5) , 686-689. https://doi.org/10.1246/cl.170106
  48. Shun-suke Asami, Shintaro Ishida, Takeaki Iwamoto, Katsunori Suzuki, Makoto Yamashita. Isolation and Characterization of Radical Anions Derived from a Boryl-Substituted Diphosphene. Angewandte Chemie 2017, 129 (6) , 1680-1684. https://doi.org/10.1002/ange.201611762
  49. Shun‐suke Asami, Shintaro Ishida, Takeaki Iwamoto, Katsunori Suzuki, Makoto Yamashita. Isolation and Characterization of Radical Anions Derived from a Boryl‐Substituted Diphosphene. Angewandte Chemie International Edition 2017, 56 (6) , 1658-1662. https://doi.org/10.1002/anie.201611762
  50. Tao Li, Houjia Wei, Yong Fang, Lei Wang, Sheng Chen, Zaichao Zhang, Yue Zhao, Gengwen Tan, Xinping Wang. Elusive Antimony-Centered Radical Cations: Isolation, Characterization, Crystal Structures, and Reactivity Studies. Angewandte Chemie 2017, 129 (2) , 647-651. https://doi.org/10.1002/ange.201610334
  51. Tao Li, Houjia Wei, Yong Fang, Lei Wang, Sheng Chen, Zaichao Zhang, Yue Zhao, Gengwen Tan, Xinping Wang. Elusive Antimony-Centered Radical Cations: Isolation, Characterization, Crystal Structures, and Reactivity Studies. Angewandte Chemie International Edition 2017, 56 (2) , 632-636. https://doi.org/10.1002/anie.201610334
  52. Masaaki Yoshifuji. Sterically Protected Diphosphenes. European Journal of Inorganic Chemistry 2016, 2016 (5) , 607-615. https://doi.org/10.1002/ejic.201500990
  53. Alexander Hinz, Julia Rothe, Axel Schulz, Alexander Villinger. Reduction of dichloro(diaza-phospha)stibanes – isolation of a donor-stabilized distibenium dication. Dalton Transactions 2016, 45 (14) , 6044-6052. https://doi.org/10.1039/C5DT02711J
  54. Christin Kirst, Bela E. Bode, David B. Cordes, Phillip S. Nejman, Alexandra M. Z. Slawin, Konstantin Karaghiosoff, J. Derek Woollins. Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation. Dalton Transactions 2016, 45 (15) , 6348-6351. https://doi.org/10.1039/C6DT00304D
  55. Benedict M. Gardner, Gábor Balázs, Manfred Scheer, Ashley J. Wooles, Floriana Tuna, Eric J. L. McInnes, Jonathan McMaster, William Lewis, Alexander J. Blake, Stephen T. Liddle. Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex. Angewandte Chemie 2015, 127 (50) , 15465-15469. https://doi.org/10.1002/ange.201508600
  56. Benedict M. Gardner, Gábor Balázs, Manfred Scheer, Ashley J. Wooles, Floriana Tuna, Eric J. L. McInnes, Jonathan McMaster, William Lewis, Alexander J. Blake, Stephen T. Liddle. Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex. Angewandte Chemie International Edition 2015, 54 (50) , 15250-15254. https://doi.org/10.1002/anie.201508600
  57. Takahiro Sasamori, Norihiro Tokitoh, Rainer Streubel. π-Electron Redox Systems of Heavier Group 15 Elements. 2015,,, 563-578. https://doi.org/10.1002/9781118858981.ch20
  58. . Organic Redox Systems. 2016,,https://doi.org/10.1002/9781118858981
  59. Iva Vránová, Mercedes Alonso, Rabindranath Lo, Robert Sedlák, Roman Jambor, Aleš Růžička, Frank De Proft, Pavel Hobza, Libor Dostál. From Dibismuthenes to Three- and Two-Coordinated Bismuthinidenes by Fine Ligand Tuning: Evidence for Aromatic BiC 3 N Rings through a Combined Experimental and Theoretical Study. Chemistry - A European Journal 2015, 21 (47) , 16917-16928. https://doi.org/10.1002/chem.201502724
  60. Takahiro Sasamori, Koki Hirano, Hideaki Miyake, Norihiro Tokitoh. Photochemical ( E )–( Z ) Isomerization of the P=C Double Bond in Triphospha[3]radialene–[M(CO) 5 ] (M = W, Cr) Complexes. Chemistry Letters 2015, 44 (9) , 1240-1242. https://doi.org/10.1246/cl.150422
  61. Ryan J. Schwamm, Jeffrey R. Harmer, Matthias Lein, Christopher M. Fitchett, Simon Granville, Martyn P. Coles. Isolation and Characterization of a Bismuth(II) Radical. Angewandte Chemie 2015, 127 (36) , 10776-10779. https://doi.org/10.1002/ange.201504632
  62. Ryan J. Schwamm, Jeffrey R. Harmer, Matthias Lein, Christopher M. Fitchett, Simon Granville, Martyn P. Coles. Isolation and Characterization of a Bismuth(II) Radical. Angewandte Chemie International Edition 2015, 54 (36) , 10630-10633. https://doi.org/10.1002/anie.201504632
  63. Maciej Witwicki. Theoretical Characterisation of Phosphinyl Radicals and Their Magnetic Properties: g Matrix. ChemPhysChem 2015, 16 (9) , 1912-1925. https://doi.org/10.1002/cphc.201500121
  64. Angelika Brückner, Alexander Hinz, Jacqueline B. Priebe, Axel Schulz, Alexander Villinger. Cyclische Gruppe-15-Radikalkationen. Angewandte Chemie 2015, 127 (25) , 7534-7538. https://doi.org/10.1002/ange.201502054
  65. Angelika Brückner, Alexander Hinz, Jacqueline B. Priebe, Axel Schulz, Alexander Villinger. Cyclic Group 15 Radical Cations. Angewandte Chemie International Edition 2015, 54 (25) , 7426-7430. https://doi.org/10.1002/anie.201502054
  66. James S. Jones, Baofei Pan, François P. Gabbaï. Group 15 Metal-Metal Bonds. 2015,,, 519-558. https://doi.org/10.1002/9783527673353.ch15
  67. . Molecular Metal-Metal Bonds. 2015,,https://doi.org/10.1002/9783527673353
  68. Ole Mallow, Monther A. Khanfar, Moritz Malischewski, Pamela Finke, Malte Hesse, Enno Lork, Timo Augenstein, Frank Breher, Jeffrey R. Harmer, Nadezhda V. Vasilieva, Andrey Zibarev, Artem S. Bogomyakov, Konrad Seppelt, Jens Beckmann. Diaryldichalcogenide radical cations. Chemical Science 2015, 6 (1) , 497-504. https://doi.org/10.1039/C4SC02964J
  69. Xiaobo Pan, Xingyong Wang, Zaichao Zhang, Xinping Wang. Two phosphaalkene radical cations with inverse spin density distributions. Dalton Transactions 2015, 44 (34) , 15099-15102. https://doi.org/10.1039/C5DT00656B
  70. Takahiro Sasamori, Michiyasu Sakagami, Norihiro Tokitoh. Bromination of a Stable 1,2-Bis(ferrocenyl)dibismuthene: Synthesis of a 1,2-Dibromodibismuthane Derivative. Heteroatom Chemistry 2014, 25 (5) , 306-312. https://doi.org/10.1002/hc.21154
  71. Baolin Li, Shota Tsujimoto, Yongming Li, Hayato Tsuji, Kohei Tamao, Daisuke Hashizume, Tsukasa Matsuo. Synthesis and Characterization of Diphosphenes Bearing Fused-Ring Bulky Rind Groups. Heteroatom Chemistry 2014, 25 (6) , 612-618. https://doi.org/10.1002/hc.21197
  72. Shintaro Ishida, Fumiya Hirakawa, Ko Furukawa, Kenji Yoza, Takeaki Iwamoto. Persistent Antimony- and Bismuth-Centered Radicals in Solution. Angewandte Chemie 2014, 126 (42) , 11354-11358. https://doi.org/10.1002/ange.201405509
  73. Shintaro Ishida, Fumiya Hirakawa, Ko Furukawa, Kenji Yoza, Takeaki Iwamoto. Persistent Antimony- and Bismuth-Centered Radicals in Solution. Angewandte Chemie International Edition 2014, 53 (42) , 11172-11176. https://doi.org/10.1002/anie.201405509
  74. Robert Kretschmer, David A. Ruiz, Curtis E. Moore, Arnold L. Rheingold, Guy Bertrand. Ein-, Zwei- und Drei-Elektronen-Reduktion eines CAAC-SbCl 3 - Addukts. Angewandte Chemie 2014, 126 (31) , 8315-8318. https://doi.org/10.1002/ange.201404849
  75. Robert Kretschmer, David A. Ruiz, Curtis E. Moore, Arnold L. Rheingold, Guy Bertrand. One-, Two-, and Three-Electron Reduction of a Cyclic Alkyl(amino)carbene-SbCl 3 Adduct. Angewandte Chemie International Edition 2014, 53 (31) , 8176-8179. https://doi.org/10.1002/anie.201404849
  76. Shigeru Nagase. Theory and Calculations of Molecules Containing Heavier Main Group Elements and Fullerenes Encaging Transition Metals: Interplay with Experiment. Bulletin of the Chemical Society of Japan 2014, 87 (2) , 167-195. https://doi.org/10.1246/bcsj.20130266
  77. Takahiro Sasamori. The Synthesis and Properties of Bimetallic d-^|^pi; Electron Systems Containing Metallocenyl Substituents of Fe or Ru, and ^|^pi;-Electron Spacers of Heavier Main Group Elements from Group 14 or 15. Journal of Synthetic Organic Chemistry, Japan 2014, 72 (11) , 1279-1289. https://doi.org/10.5059/yukigoseikyokaishi.72.1279
  78. Michiyasu Sakagami, Takahiro Sasamori, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh. 1,2-Bis(ferrocenyl)dipnictenes: Bimetallic Systems with a Pn=Pn Heavy π-Spacer (Pn: P, Sb, and Bi). Bulletin of the Chemical Society of Japan 2013, 86 (10) , 1132-1143. https://doi.org/10.1246/bcsj.20130174
  79. Michiyasu Sakagami, Takahiro Sasamori, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh. 1,2-Bis(ferrocenyl)-Substituted Distibene and Dibismuthene: SbSb and BiBi Units as π Spacers between Two Ferrocenyl Units. Chemistry - An Asian Journal 2013, 8 (4) , 690-693. https://doi.org/10.1002/asia.201201227
  80. J.D. Protasiewicz. Multiply Bonded Compounds of Group 15 Elements. 2013,,, 325-348. https://doi.org/10.1016/B978-0-08-097774-4.00114-5
  81. . Comprehensive Inorganic Chemistry II. 2013,,https://doi.org/
  82. T. Chivers, J. Konu. Stable and Persistent Radicals of Group 13-17 Elements. 2013,,, 349-373. https://doi.org/10.1016/B978-0-08-097774-4.00116-9
  83. . Comprehensive Inorganic Chemistry II. 2013,,https://doi.org/
  84. Conor G. E. Fleming, Alexandra M. Z. Slawin, Kasun S. Athukorala Arachchige, Rebecca Randall, Michael Bühl, Petr Kilian. Synthetic and computational study of geminally bis(supermesityl) substituted phosphorus compounds. Dalton Trans. 2013, 42 (5) , 1437-1450. https://doi.org/10.1039/C2DT31971C
  85. Takahiro Sasamori, Michiyasu Sakagami, Masatoshi Niwa, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh. Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene. Chemical Communications 2012, 48 (68) , 8562. https://doi.org/10.1039/c2cc33277a
  86. Stephan Schulz. Low-Valent Organometallics-Synthesis, Reactivity, and Potential Applications. Chemistry - A European Journal 2010, 16 (22) , 6416-6428. https://doi.org/10.1002/chem.201000580
  87. Akihiro Tsurusaki, Noriyoshi Nagahora, Takahiro Sasamori, Kazunari Matsuda, Yoshihiko Kanemitsu, Yasuaki Watanabe, Yoshinobu Hosoi, Yukio Furukawa, Norihiro Tokitoh. Synthesis, Structures, and Reactivity of Kinetically Stabilized Anthryldiphosphene Derivatives. Bulletin of the Chemical Society of Japan 2010, 83 (5) , 456-478. https://doi.org/10.1246/bcsj.20090295
  88. Olivier Back, Bruno Donnadieu, Pattiyil Parameswaran, Gernot Frenking, Guy Bertrand. Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications. Nature Chemistry 2010, 2 (5) , 369-373. https://doi.org/10.1038/nchem.617
  89. Teruyuki Matsumoto, Takahiro Sasamori, Nobuhiro Takeda, Norihiro Tokitoh. Synthesis and properties of group 9 metal complexes bearing a β-ketophosphenato ligand. Journal of Organometallic Chemistry 2010, 695 (7) , 1019-1025. https://doi.org/10.1016/j.jorganchem.2009.10.022
  90. Takahiro Sasamori, Teruyuki Matsumoto, Norihiro Tokitoh. Synthesis of rhodium–carbonyl complexes bearing a novel P,N-chelating ligand of Schiff-base type. Polyhedron 2010, 29 (1) , 425-433. https://doi.org/10.1016/j.poly.2009.06.043
  91. Takahiro Sasamori, Akimi Hori, Yoshikazu Kaneko, Norihiro Tokitoh. Synthesis, structures and properties of biferrocenyl- and ruthenocenyl-substituted diphosphenes. New Journal of Chemistry 2010, 34 (8) , 1560. https://doi.org/10.1039/c0nj00062k
  92. Norihiro Tokitoh, Akihiro Tsurusaki, Takahiro Sasamori. A Unique Thermal Reaction of 9-Anthryldiphosphene Leading to the Formation of a Triphosphirane Derivative. Phosphorus, Sulfur, and Silicon and the Related Elements 2009, 184 (4) , 979-986. https://doi.org/10.1080/10426500902719479
  93. . Nature of Organic Ion-Radicals and Their Ground-State Electronic Structure. 2008,,, 1-83. https://doi.org/10.1201/9781420008395.ch1
  94. Zory Vlad Todres. Ion-Radical Organic Chemistry. 2008,,https://doi.org/10.1201/9781420008395
  95. Noriyoshi Nagahora, Takahiro Sasamori, Norihiro Tokitoh. Chalcogenation reactions of a stable ferrocenyldiphosphene: Formation of thia‐, selena‐, and telluradiphosphiranes. Heteroatom Chemistry 2008, 19 (5) , 443-449. https://doi.org/10.1002/hc.20449
  96. Norihiro Tokitoh, Keiji Wakita, Takeshi Matsumoto, Takahiro Sasamori, Renji Okazaki, Nozomi Takagi, Masahiro Kimura, Shigeru Nagase. The Chemistry of Stable Silabenzenes. Journal of the Chinese Chemical Society 2008, 55 (3) , 487-507. https://doi.org/10.1002/jccs.200800073
  97. Noriyoshi Nagahora, Takahiro Sasamori, Yoshinobu Hosoi, Yukio Furukawa, Norihiro Tokitoh. Generation, isolation, and reactivity of a kinetically stabilized diphosphene anion radical. Journal of Organometallic Chemistry 2008, 693 (4) , 625-632. https://doi.org/10.1016/j.jorganchem.2007.10.061
  98. René T. Boeré, Alan M. Bond, Steve Cronin, Noel W. Duffy, Paul Hazendonk, Jason D. Masuda, Kyle Pollard, Tracey L. Roemmele, Peter Tran, Yuankui Zhang. Photophysical, dynamic and redox behavior of tris(2,6-diisopropylphenyl)phosphine. New J. Chem. 2008, 32 (2) , 214-231. https://doi.org/10.1039/B709602J
  99. Takahiro Sasamori, Norihiro Tokitoh. Doubly bonded systems between heavier Group 15 elements. Dalton Trans. 2008, 99 (11) , 1395-1408. https://doi.org/10.1039/B715033D
  100. Noriyoshi Nagahora, Takahiro Sasamori, Yasuaki Watanabe, Yukio Furukawa, Norihiro Tokitoh. Kinetically Stabilized 1,1′-Bis[( E )-diphosphenyl]ferrocenes: Syntheses, Structures, Properties, and Reactivity. Bulletin of the Chemical Society of Japan 2007, 80 (10) , 1884-1900. https://doi.org/10.1246/bcsj.80.1884

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