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Ordering of Dipeptide Chains on Cu Surfaces through 2D Cocrystallization

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Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D -70569 Stuttgart, Germany, and Institut de Physique des Nanostructures, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland
Cite this: J. Am. Chem. Soc. 2007, 129, 51, 15742–15743
Publication Date (Web):November 30, 2007
https://doi.org/10.1021/ja075118v
Copyright © 2007 American Chemical Society

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    Abstract

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    We report on the induced ordering of dispersed chiral diphenylalanine (Phe−Phe) chains grown on the anisotropic Cu(110) and isotropic Cu(100) surfaces. Scanning tunneling microscopy (STM) data reveal that 2D extended hybrid molecular motifs can be fabricated by utilizing terephthalic acid (TPA) molecules as linkers. These act as a molecular “glue” to bridge the isolated Phe−Phe chains without altering the global chirality of the final structures. Our results demonstrate the applicability and effectiveness of this 2D analogue of the 3D cocrystallization approach.

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     Max-Planck-Institut für Festkörperforschung.

    §

     Present address: Department of Chemistry, University of Warwick, Coventry CV4 7AL, U.K.

     Ecole Polytechnique Fédérale de Lausanne.

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    Experimental details and STM data of pure Phe−Phe chains on Cu(110) and Cu(100) surfaces. This material is available free of charge via the Internet at http://pubs.acs.org.

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