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Supramolecular Control on Chemo- and Regioselectivity via Encapsulation of (NHC)-Au Catalyst within a Hexameric Self-Assembled Host

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Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca′ Foscari di Venezia, Calle Larga S Marta 2137, 30123, Venezia, Italy
Dipartimento di Processi Chimici per l′Ingegneria, Università di Padova, Via Marzolo 9, 35131 Padova, Italy
§ Van’t Hoff Institute for Molecular Sciences, University of Amsterdam, Postbus 94720, 1090 GE Amsterdam, The Netherlands
Cite this: J. Am. Chem. Soc. 2011, 133, 9, 2848–2851
Publication Date (Web):February 14, 2011
https://doi.org/10.1021/ja111106x
Copyright © 2011 American Chemical Society

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    Abstract

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    The encapsulation of a Au(I) catalyst within a self-assembled, hydrogen bonded, hexameric capsule dramatically changes its catalytic activity, leading to unusual products due to the steric requirements of the host’s cavity.

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