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Access to a Stable Si2N2 Four-Membered Ring with Non-Kekulé Singlet Biradical Character from a Disilyne

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Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan
[email protected]
Cite this: J. Am. Chem. Soc. 2011, 133, 32, 12478–12481
Publication Date (Web):July 21, 2011
https://doi.org/10.1021/ja2059846
Copyright © 2011 American Chemical Society
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Abstract

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The reactions of 1,1,4,4-tetrakis[bis(trimethylsilyl)methyl]-1,4-diisopropyltetrasila-2-yne 1 with an equivalent amount of trans- and cis-3,3′,5,5′-tetramethylazobenzenes produced a Si2N2 four-membered ring biradicaloid [RSi(μ-NAr)2SiR] 2 (R = SiiPr[CH(SiMe3)2]2, Ar = 3,5-Me2C6H3), which was isolated as air- and moisture-sensitive dark purple crystals. Compound 2 displays no EPR signal, and the molecular structure of 2 was characterized by NMR spectroscopy and X-ray crystallography, revealing that 2 has a planar centrosymmetric Si2N2 four-membered ring. The Si1–Si1′ distance is 2.63380(9) Å, and there is no bond interaction between the Si1 and Si1′ atoms of 2. The reactions of 2 with methanol and carbon tetrachloride show that 2 has both closed-shell and radical-type reactivity.

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The experimental procedures of 2, 3, and 4; UV–vis spectral chart of 2; computational results on the model compounds 2′ and 4′; table of crystallographic data including atomic positional and thermal parameters for 2 and 4 (PDF/CIF). This material is available free of charge via the Internet at http://pubs.acs.org.

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