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Synthesis of Kinetically Stabilized 1,2-Dihydrodisilenes

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† Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
‡ Kyoto University Pioneering Research Unit for Next Generation, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
§ Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan
∥ Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Myodaiji, Okazaki 444-8585, Japan
⊥ Advanced Technology Support Division, RIKEN Advanced Science Institute, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan
[email protected]; [email protected]
Cite this: J. Am. Chem. Soc. 2012, 134, 9, 4120–4123
Publication Date (Web):February 22, 2012
https://doi.org/10.1021/ja300694p
Copyright © 2012 American Chemical Society
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Abstract

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Kinetically stabilized 1,2-dihydrodisilenes were successfully synthesized and isolated by the introduction of sterically protecting bulky aryl groups. These 1,2-dihydrodisilenes exhibit distinct Si═Si double-bond character in both solution and the solid state. The Si–H bonds in these 1,2-dihydrodisilenes exhibit higher s character than those of typical σ4,λ4-hydrosilanes. Moderate heating of these 1,2-dihydrodisilenes in solution resulted in their isomerization to the corresponding trihydrodisilanes, with an intramolecular hydrogen migration as the rate-determining step.

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Experimental procedures, analytical data for new compounds, computational results, and X-ray crystallographic data (CIF). This material is available free of charge via the Internet at http://pubs.acs.org.

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