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Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes

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Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States
[email protected]
Cite this: J. Am. Chem. Soc. 2012, 134, 48, 19922–19934
Publication Date (Web):November 15, 2012
https://doi.org/10.1021/ja310351e
Copyright © 2012 American Chemical Society
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    Abstract

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    A series of monoligated L·PdII(Ar)X complexes (L = dialkyl biaryl phosphine) have been prepared and studied in an effort to better understand an unusual dearomative rearrangement previously documented in these systems. Experimental and theoretical evidence suggest a concerted process involving the unprecedented PdII-mediated insertion of an aryl group into an unactivated arene.

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    Procedural, spectroscopic, and X-ray crystallographic (CIF) data; kinetic graphs, including those used to determine relative rate constants; coordinates for all calculated complexes and other computational data; complete ref 35. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Your Mendeley pairing has expired. Please reconnect