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Turn-on Phosphorescence by Metal Coordination to a Multivalent Terpyridine Ligand: A New Paradigm for Luminescent Sensors

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Department of Chemistry “G. Ciamician”, University of Bologna, 40126 Bologna, Italy
Aix-Marseille Université, CNRS, CINaM UMR 7325, 163 Ave. de Luminy, 13288 Marseille, France
Cite this: J. Am. Chem. Soc. 2014, 136, 17, 6395–6400
Publication Date (Web):April 11, 2014
https://doi.org/10.1021/ja501458s
Copyright © 2014 American Chemical Society
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Abstract

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A hexathiobenzene molecule carrying six terpyridine (tpy) units at the periphery has been designed to couple the aggregation induced phosphorescence, displayed by the core in the solid state, to the metal binding properties of the tpy units. Upon Mg2+ complexation in THF solution, phosphorescence of the hexathiobenzene core is turned on. Metal ion coordination yields the formation of a supramolecular polymer which hinders intramolecular rotations and motions of the core chromophore, thus favoring radiative deactivation of the luminescent excited state. Upon excitation of the [Mg(tpy)2]2+ units of the polymeric structure, sensitization of the core phosphorescence takes place with >90% efficiency. The light-harvesting polymeric antenna can be disassembled upon fluoride ion addition, thereby switching off luminescence and offering a new tool for fluoride ion sensing. This unique system can, thus, serve as cation or anion sensor.

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  2. Yun-Wu Li, Jing Li, Xiao-Yu Wan, Da-Fei Sheng, Hui Yan, Shan-Shan Zhang, Hui-Yan Ma, Su-Na Wang, Da-Cheng Li, Zhi-Yong Gao, Jian-Min Dou, Di Sun. Nanocage-Based N-Rich Metal–Organic Framework for Luminescence Sensing toward Fe3+ and Cu2+ Ions. Inorganic Chemistry 2021, 60 (2) , 671-681. https://doi.org/10.1021/acs.inorgchem.0c02629
  3. Jing Yang, Tingting Wang, Ran Guo, Decui Yao, Weiwei Guo, Shuo Liu, Zhiqiang Li, Yige Wang, Huanrong Li. Self-Healing Material with Reversible Luminescence Switch Behavior. ACS Applied Materials & Interfaces 2020, 12 (48) , 54026-54034. https://doi.org/10.1021/acsami.0c13509
  4. Tianyu Yang, Zhoubin Deng, Ke-Hu Wang, Pengfei Li, Danfeng Huang, Yingpeng Su, Yulai Hu. Synthesis of CF3-Substituted 1,6-Dihydropyridazines by Copper-Promoted Cascade Oxidation/Cyclization of Trifluoromethylated Homoallylic N-Acylhydrazines. The Journal of Organic Chemistry 2020, 85 (19) , 12304-12314. https://doi.org/10.1021/acs.joc.0c01568
  5. Alphy Sebastian, Edamana Prasad. Cyanide Sensing in Water Using a Copper Metallogel through “Turn-on” Fluorescence. Langmuir 2020, 36 (35) , 10537-10547. https://doi.org/10.1021/acs.langmuir.0c01803
  6. Yiming Li, Gui-Fei Huo, Bingqing Liu, Bo Song, Yuan Zhang, Xiaomin Qian, Heng Wang, Guang-Qiang Yin, Alexander Filosa, Wenfang Sun, Saw Wai Hla, Hai-Bo Yang, Xiaopeng Li. Giant Concentric Metallosupramolecule with Aggregation-Induced Phosphorescent Emission. Journal of the American Chemical Society 2020, 142 (34) , 14638-14648. https://doi.org/10.1021/jacs.0c06680
  7. Leixin Xiao, Zhiwei Wang, Chunfeng Zhang, Xiaoyu Xie, Haibo Ma, Qian Peng, Zhongfu An, Xiaoyong Wang, Zhigang Shuai, Min Xiao. Long Persistent Luminescence Enabled by Dissociation of Triplet Intermediate States in an Organic Guest/Host System. The Journal of Physical Chemistry Letters 2020, 11 (9) , 3582-3588. https://doi.org/10.1021/acs.jpclett.0c00880
  8. Kazuyuki Ninomiya, Naoki Shida, Takanobu Nishikawa, Takuya Ishihara, Hiroki Nishiyama, Ikuyoshi Tomita, Shinsuke Inagi. Postfunctionalization of a Perfluoroarene-Containing π-Conjugated Polymer via Nucleophilic Aromatic Substitution Reaction. ACS Macro Letters 2020, 9 (2) , 284-289. https://doi.org/10.1021/acsmacrolett.9b01020
  9. Lei Wang, Bo Song, Sandra Khalife, Yiming Li, Li-June Ming, Shi Bai, Yaping Xu, Hao Yu, Ming Wang, Heng Wang, Xiaopeng Li. Introducing Seven Transition Metal Ions into Terpyridine-Based Supramolecules: Self-Assembly and Dynamic Ligand Exchange Study. Journal of the American Chemical Society 2020, 142 (4) , 1811-1821. https://doi.org/10.1021/jacs.9b09497
  10. Marco Villa, Benedetta Del Secco, Luca Ravotto, Myriam Roy, Enrico Rampazzo, Nelsi Zaccheroni, Luca Prodi, Marc Gingras, Sergei A. Vinogradov, Paola Ceroni. Bright Phosphorescence of All-Organic Chromophores Confined within Water-Soluble Silica Nanoparticles. The Journal of Physical Chemistry C 2019, 123 (49) , 29884-29890. https://doi.org/10.1021/acs.jpcc.9b09206
  11. Yifan Gong, Yunyun Zhou, Bingbing Yue, Bin Wu, Ruyi Sun, Sanyin Qu, Liangliang Zhu. Multiwavelength Anti-Kasha’s Rule Emission on Self-Assembly of Azulene-Functionalized Persulfurated Arene. The Journal of Physical Chemistry C 2019, 123 (36) , 22511-22518. https://doi.org/10.1021/acs.jpcc.9b06731
  12. Wei-Rong Cui, Cheng-Rong Zhang, Wei Jiang, Ru-Ping Liang, Jian-Ding Qiu. Covalent Organic Framework Nanosheets for Fluorescence Sensing via Metal Coordination. ACS Applied Nano Materials 2019, 2 (8) , 5342-5349. https://doi.org/10.1021/acsanm.9b01366
  13. Huifang Shi, Liang Zou, Kaiwei Huang, He Wang, Chen Sun, Shan Wang, Huili Ma, Yarong He, Jianpu Wang, Haidong Yu, Wei Yao, Zhongfu An, Qiang Zhao, Wei Huang. A Highly Efficient Red Metal-free Organic Phosphor for Time-Resolved Luminescence Imaging and Photodynamic Therapy. ACS Applied Materials & Interfaces 2019, 11 (20) , 18103-18110. https://doi.org/10.1021/acsami.9b01615
  14. Sophia Katharina Peter, Corinna Kaulen, Alexander Hoffmann, Wojciech Ogieglo, Silvia Karthäuser, Melanie Homberger, Sonja Herres-Pawlis, Ulrich Simon. Stepwise Growth of Ruthenium Terpyridine Complexes on Au Surfaces. The Journal of Physical Chemistry C 2019, 123 (11) , 6537-6548. https://doi.org/10.1021/acs.jpcc.8b12039
  15. Jin Yuan, Ling Wang, Yitong Wang, Shuli Dong, Jingcheng Hao. Eu3+-Controlled Fluorescent Bilayer Vesicles. Langmuir 2019, 35 (11) , 4125-4132. https://doi.org/10.1021/acs.langmuir.9b00302
  16. Anqi Lv, Wenpeng Ye, Xueyan Jiang, Nan Gan, Huifang Shi, Wei Yao, Huili Ma, Zhongfu An, Wei Huang. Room-Temperature Phosphorescence from Metal-Free Organic Materials in Solution: Origin and Molecular Design. The Journal of Physical Chemistry Letters 2019, 10 (5) , 1037-1042. https://doi.org/10.1021/acs.jpclett.9b00221
  17. Xingmao Chang, Zhixuan Zhou, Congdi Shang, Gang Wang, Zhaolong Wang, Yanyu Qi, Zhong-Yu Li, Heng Wang, Liping Cao, Xiaopeng Li, Yu Fang, Peter J. Stang. Coordination-Driven Self-Assembled Metallacycles Incorporating Pyrene: Fluorescence Mutability, Tunability, and Aromatic Amine Sensing. Journal of the American Chemical Society 2019, 141 (4) , 1757-1765. https://doi.org/10.1021/jacs.8b12749
  18. Oleksandra Veselska, Caroline Dessal, Sihem Melizi, Nathalie Guillou, Darjan Podbevšek, Gilles Ledoux, Erik Elkaim, Alexandra Fateeva, Aude Demessence. New Lamellar Silver Thiolate Coordination Polymers with Tunable Photoluminescence Energies by Metal Substitution. Inorganic Chemistry 2019, 58 (1) , 99-105. https://doi.org/10.1021/acs.inorgchem.8b01257
  19. Lei Wang, Ran Liu, Jiali Gu, Bo Song, Heng Wang, Xin Jiang, Keren Zhang, Xin Han, Xin-Qi Hao, Shi Bai, Ming Wang, Xiaohong Li, Bingqian Xu, Xiaopeng Li. Self-Assembly of Supramolecular Fractals from Generation 1 to 5. Journal of the American Chemical Society 2018, 140 (43) , 14087-14096. https://doi.org/10.1021/jacs.8b05530
  20. Lifang Bian, Huifang Shi, Xuan Wang, Kun Ling, Huili Ma, Mengping Li, Zhichao Cheng, Chaoqun Ma, Suzhi Cai, Qi Wu, Nan Gan, Xiangfei Xu, Zhongfu An, Wei Huang. Simultaneously Enhancing Efficiency and Lifetime of Ultralong Organic Phosphorescence Materials by Molecular Self-Assembly. Journal of the American Chemical Society 2018, 140 (34) , 10734-10739. https://doi.org/10.1021/jacs.8b03867
  21. Lei Wang, Zhe Zhang, Xin Jiang, Jennifer A. Irvin, Changlin Liu, Ming Wang, Xiaopeng Li. Self-Assembly of Tetrameric and Hexameric Terpyridine-Based Macrocycles Using Cd(II), Zn(II), and Fe(II). Inorganic Chemistry 2018, 57 (7) , 3548-3558. https://doi.org/10.1021/acs.inorgchem.7b02361
  22. Zikai He, Chunqiao Ke, and Ben Zhong Tang . Journey of Aggregation-Induced Emission Research. ACS Omega 2018, 3 (3) , 3267-3277. https://doi.org/10.1021/acsomega.8b00062
  23. Chen Sun, Xueqin Ran, Xuan Wang, Zhichao Cheng, Qi Wu, Suzhi Cai, Long Gu, Nan Gan, Huixian Shi, Zhongfu An, Huifang Shi, and Wei Huang . Twisted Molecular Structure on Tuning Ultralong Organic Phosphorescence. The Journal of Physical Chemistry Letters 2018, 9 (2) , 335-339. https://doi.org/10.1021/acs.jpclett.7b02953
  24. Benjamin Doistau, Lorien Benda, Jean-Louis Cantin, Lise-Marie Chamoreau, Eliseo Ruiz, Valérie Marvaud, Bernold Hasenknopf, and Guillaume Vives . Six States Switching of Redox-Active Molecular Tweezers by Three Orthogonal Stimuli. Journal of the American Chemical Society 2017, 139 (27) , 9213-9220. https://doi.org/10.1021/jacs.7b02945
  25. Zhe Zhang, Heng Wang, Xu Wang, Yiming Li, Bo Song, Olapeju Bolarinwa, R. Alexander Reese, Tong Zhang, Xu-Qing Wang, Jianfeng Cai, Bingqian Xu, Ming Wang, Changlin Liu, Hai-Bo Yang, and Xiaopeng Li . Supersnowflakes: Stepwise Self-Assembly and Dynamic Exchange of Rhombus Star-Shaped Supramolecules. Journal of the American Chemical Society 2017, 139 (24) , 8174-8185. https://doi.org/10.1021/jacs.7b01326
  26. Safwan Aroua, Tanya K. Todorova, Paul Hommes, Lise-Marie Chamoreau, Hans-Ulrich Reissig, Victor Mougel, and Marc Fontecave . Synthesis, Characterization, and DFT Analysis of Bis-Terpyridyl-Based Molecular Cobalt Complexes. Inorganic Chemistry 2017, 56 (10) , 5930-5940. https://doi.org/10.1021/acs.inorgchem.7b00595
  27. Yoshiaki Shoji, Yasuhiro Ikabata, Qi Wang, Daisuke Nemoto, Atsushi Sakamoto, Naoki Tanaka, Junji Seino, Hiromi Nakai, and Takanori Fukushima . Unveiling a New Aspect of Simple Arylboronic Esters: Long-Lived Room-Temperature Phosphorescence from Heavy-Atom-Free Molecules. Journal of the American Chemical Society 2017, 139 (7) , 2728-2733. https://doi.org/10.1021/jacs.6b11984
  28. Hongwei Wu, Pei Zhao, Xin Li, Wenbo Chen, Hans Ågren, Qing Zhang, and Liangliang Zhu . Tuning for Visible Fluorescence and Near-Infrared Phosphorescence on a Unimolecular Mechanically Sensitive Platform via Adjustable CH−π Interaction. ACS Applied Materials & Interfaces 2017, 9 (4) , 3865-3872. https://doi.org/10.1021/acsami.6b15939
  29. Hongwei Wu, Yunyun Zhou, Liyuan Yin, Cheng Hang, Xin Li, Hans Ågren, Tao Yi, Qing Zhang, and Liangliang Zhu . Helical Self-Assembly-Induced Singlet–Triplet Emissive Switching in a Mechanically Sensitive System. Journal of the American Chemical Society 2017, 139 (2) , 785-791. https://doi.org/10.1021/jacs.6b10550
  30. Gregory D. Gutierrez, Graham T. Sazama, Tony Wu, Marc A. Baldo, and Timothy M. Swager . Red Phosphorescence from Benzo[2,1,3]thiadiazoles at Room Temperature. The Journal of Organic Chemistry 2016, 81 (11) , 4789-4796. https://doi.org/10.1021/acs.joc.6b00789
  31. Masaki Shimizu, Ryosuke Shigitani, Masaki Nakatani, Keiko Kuwabara, Yusuke Miyake, Kunihiko Tajima, Hayato Sakai, and Taku Hasobe . Siloxy Group-Induced Highly Efficient Room Temperature Phosphorescence with Long Lifetime. The Journal of Physical Chemistry C 2016, 120 (21) , 11631-11639. https://doi.org/10.1021/acs.jpcc.6b03276
  32. Huifang Shi, Zhongfu An, Pei-Zhou Li, Jun Yin, Guichuan Xing, Tingchao He, Hongzhong Chen, Jingui Wang, Handong Sun, Wei Huang, and Yanli Zhao . Enhancing Organic Phosphorescence by Manipulating Heavy-Atom Interaction. Crystal Growth & Design 2016, 16 (2) , 808-813. https://doi.org/10.1021/acs.cgd.5b01400
  33. Shuqin Wang Wang Zhang Yuan Yongming Zhang . Pure Organic Luminogens with Room Temperature Phosphorescence. 2016,,, 1-26. https://doi.org/10.1021/bk-2016-1227.ch001
  34. Alexandre Jacques, Simon Cerfontaine, and Benjamin Elias . Access to Functionalized Luminescent Multi-2,2′:6′,2″-terpyridine Ligands. The Journal of Organic Chemistry 2015, 80 (21) , 11143-11148. https://doi.org/10.1021/acs.joc.5b01897
  35. Dongfang Qiu, Mengmeng Li, Qian Zhao, Hongwei Wang, and Chunxia Yang . Cyclometalated Platinum(II) Terpyridylacetylide with a Bis(arylamine) Donor as a Proton-Triggered Luminescence Chemosensor for Zn2+. Inorganic Chemistry 2015, 54 (16) , 7774-7782. https://doi.org/10.1021/acs.inorgchem.5b00756
  36. Lei You, Daijun Zha, and Eric V. Anslyn . Recent Advances in Supramolecular Analytical Chemistry Using Optical Sensing. Chemical Reviews 2015, 115 (15) , 7840-7892. https://doi.org/10.1021/cr5005524
  37. Verónica Cámara, Natalia Barquero, Delia Bautista, Juan Gil-Rubio, and José Vicente . Assembly of Heterometallic Rigid-Rod Complexes and Coordination Oligomers from Gold(I) Metalloligands. Inorganic Chemistry 2015, 54 (13) , 6147-6156. https://doi.org/10.1021/acs.inorgchem.5b00176
  38. Yuntao Zhou, Hebo Ye, and Lei You . Reactivity-Based Dynamic Covalent Chemistry: Reversible Binding and Chirality Discrimination of Monoalcohols. The Journal of Organic Chemistry 2015, 80 (5) , 2627-2633. https://doi.org/10.1021/jo502801g
  39. Bin Sun, Ming Wang, Zhichao Lou, Mingjun Huang, Chenglong Xu, Xiaohong Li, Li-Jun Chen, Yihua Yu, Grant L. Davis, Bingqian Xu, Hai-Bo Yang, and Xiaopeng Li . From Ring-in-Ring to Sphere-in-Sphere: Self-Assembly of Discrete 2D and 3D Architectures with Increasing Stability. Journal of the American Chemical Society 2015, 137 (4) , 1556-1564. https://doi.org/10.1021/ja511443p
  40. Ming Wang, Chao Wang, Xin-Qi Hao, Xiaohong Li, Tyler J Vaughn, Yan-Yan Zhang, Yihua Yu, Zhong-Yu Li, Mao-Ping Song, Hai-Bo Yang, and Xiaopeng Li . From Trigonal Bipyramidal to Platonic Solids: Self-Assembly and Self-Sorting Study of Terpyridine-Based 3D Architectures. Journal of the American Chemical Society 2014, 136 (29) , 10499-10507. https://doi.org/10.1021/ja505414x
  41. Mengzhu Wang, Feiyang Li, Yunxiang Lei, Fuming Xiao, Miaochang Liu, Shujuan Liu, Xiaobo Huang, Huayue Wu, Qiang Zhao. Excitation-dependent organic phosphors exhibiting different luminescence colors for information anti-counterfeiting. Chemical Engineering Journal 2022, 429 , 132288. https://doi.org/10.1016/j.cej.2021.132288
  42. Xiangling Deng, Sai-Li Zheng, Yuan-Hui Zhong, Jieying Hu, Lai-Hon Chung, Jun He. Conductive MOFs based on Thiol-functionalized Linkers: Challenges, Opportunities, and Recent Advances. Coordination Chemistry Reviews 2022, 450 , 214235. https://doi.org/10.1016/j.ccr.2021.214235
  43. Hong Wang, Yingying Yang, Liusong Chen, Yue Wang, Jiewei Li, Jianfeng Zhao. The stacking induced organic room temperature phosphorescence: A compact weak interaction mechanism. Chemical Physics Letters 2021, 780 , 138904. https://doi.org/10.1016/j.cplett.2021.138904
  44. Pan Liu, Zheng Chi, Ganhui Shi, Hao Dong, Chenchen Ma, Xuegang Chen. A terpyridine-based chemosensor for detection transition metal ions in aqueous solution: Synthesis and characterization. European Polymer Journal 2021, 159 , 110716. https://doi.org/10.1016/j.eurpolymj.2021.110716
  45. Shen Shen, Gleb Baryshnikov, Bingbing Yue, Bin Wu, Xuping Li, Man Zhang, Hans Ågren, Liangliang Zhu. Manipulating crystals through photoexcitation-induced molecular realignment. Journal of Materials Chemistry C 2021, 9 (35) , 11707-11714. https://doi.org/10.1039/D1TC01605A
  46. Swadhin Garain, Bidhan Chandra Garain, Muthusamy Eswaramoorthy, Swapan K. Pati, Subi J. George. Light‐Harvesting Supramolecular Phosphors: Highly Efficient Room Temperature Phosphorescence in Solution and Hydrogels. Angewandte Chemie 2021, 133 (36) , 19872-19876. https://doi.org/10.1002/ange.202107295
  47. Swadhin Garain, Bidhan Chandra Garain, Muthusamy Eswaramoorthy, Swapan K. Pati, Subi J. George. Light‐Harvesting Supramolecular Phosphors: Highly Efficient Room Temperature Phosphorescence in Solution and Hydrogels. Angewandte Chemie International Edition 2021, 60 (36) , 19720-19724. https://doi.org/10.1002/anie.202107295
  48. Hongzhuo Wu, Deliang Wang, Zheng Zhao, Dong Wang, Yu Xiong, Ben Zhong Tang. Tailoring Noncovalent Interactions to Activate Persistent Room‐Temperature Phosphorescence from Doped Polyacrylonitrile Films. Advanced Functional Materials 2021, 31 (32) , 2101656. https://doi.org/10.1002/adfm.202101656
  49. Xiaofei Sun, Huihui Gong, Yuxi Zhang, Yuxin Tian, Hongxing Zhang, Fuquan Bai, Jian Wang, Keli Zhong, Chuipeng Kong. Investigating phosphorescence capability of halogen-substituted metal-free organic molecules: A theoretical study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2021, 255 , 119642. https://doi.org/10.1016/j.saa.2021.119642
  50. Xin‐Shun Li, Yue Wu, Yiran Zhao, Zhen‐Qiang Yu. Employing Cholesterol Copolymerization Strategy for a Thermally Processable Organic Room‐Temperature Phosphorescence Material. Advanced Optical Materials 2021, 9 (6) , 2001893. https://doi.org/10.1002/adom.202001893
  51. Parvej Alam, Nelson L.C. Leung, Jing Zhang, Ryan T.K. Kwok, Jacky W.Y. Lam, Ben Zhong Tang. AIE-based luminescence probes for metal ion detection. Coordination Chemistry Reviews 2021, 429 , 213693. https://doi.org/10.1016/j.ccr.2020.213693
  52. Yi Xing, Yanjie Wang, Lulu Zhou, Liangliang Zhu. Highly tunable aggregate-induced phosphorescence properties in persulfurated arenes. Dyes and Pigments 2021, 186 , 109032. https://doi.org/10.1016/j.dyepig.2020.109032
  53. Lifen Chen, Ji-Hua Tan, Zhiwen Yang, Zhipeng Qiu, Yingxiao Mu, Zhiyong Yang, Wen-Cheng Chen, Shaomin Ji, Zhenguo Chi, Yanping Huo. High contrast temperature-responsive luminescence materials from purely organic molecule with persistent room-temperature phosphorescence. Journal of Luminescence 2021, 230 , 117731. https://doi.org/10.1016/j.jlumin.2020.117731
  54. Guang‐Qiang Yin, Sneha Kandapal, Chung‐Hao Liu, Heng Wang, Jianxiang Huang, Shu‐Ting Jiang, Tan Ji, Yu Yan, Sandra Khalife, Ruhong Zhou, Libin Ye, Bingqian Xu, Hai‐Bo Yang, Mu‐Ping Nieh, Xiaopeng Li. Metallo‐Helicoid with Double Rims: Polymerization Followed by Folding by Intramolecular Coordination. Angewandte Chemie International Edition 2021, 60 (3) , 1281-1289. https://doi.org/10.1002/anie.202010696
  55. Guang‐Qiang Yin, Sneha Kandapal, Chung‐Hao Liu, Heng Wang, Jianxiang Huang, Shu‐Ting Jiang, Tan Ji, Yu Yan, Sandra Khalife, Ruhong Zhou, Libin Ye, Bingqian Xu, Hai‐Bo Yang, Mu‐Ping Nieh, Xiaopeng Li. Metallo‐Helicoid with Double Rims: Polymerization Followed by Folding by Intramolecular Coordination. Angewandte Chemie 2021, 133 (3) , 1301-1309. https://doi.org/10.1002/ange.202010696
  56. Alberto Fernández‐Alarcón, José Manuel Guevara‐Vela, José Luis Casals‐Sainz, Aurora Costales, Evelio Francisco, Ángel Martín Pendás, Tomás Rocha Rinza. Photochemistry in Real Space: Batho‐ and Hypsochromism in the Water Dimer. Chemistry – A European Journal 2020, 26 (71) , 17035-17045. https://doi.org/10.1002/chem.202002854
  57. Weijun Zhao, Zikai He, Ben Zhong Tang. Room-temperature phosphorescence from organic aggregates. Nature Reviews Materials 2020, 5 (12) , 869-885. https://doi.org/10.1038/s41578-020-0223-z
  58. Andrea Nitti, Chiara Botta, Alessandra Forni, Elena Cariati, Elena Lucenti, Dario Pasini. Crystallization-induced room-temperature phosphorescence in fumaramides. CrystEngComm 2020, 22 (45) , 7782-7785. https://doi.org/10.1039/D0CE01253J
  59. Mengru Wei, Hangqi Zhong, Jin Zhou, Weidong Liu, Wenbin Xi, Pengfei Xu, Qianqian Qiu, Zhaosheng Qian, Hui Feng. A phosphorescence “turn-on” probe for the detection and imaging of Al3+ based on aggregation-induced emission. Talanta 2020, 219 , 121298. https://doi.org/10.1016/j.talanta.2020.121298
  60. Pan Liu, Ganhui Shi, Xuegang Chen. Terpyridine-Containing π-Conjugated Polymers for Light-Emitting and Photovoltaic Materials. Frontiers in Chemistry 2020, 8 https://doi.org/10.3389/fchem.2020.592055
  61. Naoki Shida, Satoshi Owaki, Hiroshi Eguchi, Takanobu Nishikawa, Ikuyoshi Tomita, Shinsuke Inagi. Bis(pentafluorophenyl)- o -carborane and its arylthio derivatives: synthesis, electrochemistry and optical properties. Dalton Transactions 2020, 49 (37) , 12985-12989. https://doi.org/10.1039/D0DT02205E
  62. Zhu Wu, Jörn Nitsch, Julia Schuster, Alexandra Friedrich, Katharina Edkins, Marcel Loebnitz, Fabian Dinkelbach, Vladimir Stepanenko, Frank Würthner, Christel M. Marian, Lei Ji, Todd B. Marder. Persistent Room Temperature Phosphorescence from Triarylboranes: A Combined Experimental and Theoretical Study. Angewandte Chemie 2020, 132 (39) , 17285-17292. https://doi.org/10.1002/ange.202007610
  63. Zhu Wu, Jörn Nitsch, Julia Schuster, Alexandra Friedrich, Katharina Edkins, Marcel Loebnitz, Fabian Dinkelbach, Vladimir Stepanenko, Frank Würthner, Christel M. Marian, Lei Ji, Todd B. Marder. Persistent Room Temperature Phosphorescence from Triarylboranes: A Combined Experimental and Theoretical Study. Angewandte Chemie International Edition 2020, 59 (39) , 17137-17144. https://doi.org/10.1002/anie.202007610
  64. Harsh Bhatia, Debdas Ray. Asymmetric-donor (D 2 D 2 ′)–acceptor (A) conjugates for simultaneously accessing intrinsic blue-RTP and blue-TADF. Materials Advances 2020, 1 (6) , 1858-1865. https://doi.org/10.1039/D0MA00382D
  65. Jinjin Zhang, Huayu Qiu, Tian He, Yang Li, Shouchun Yin. Fluorescent Supramolecular Polymers Formed by Crown Ether-Based Host-Guest Interaction. Frontiers in Chemistry 2020, 8 https://doi.org/10.3389/fchem.2020.00560
  66. Ehsan Hamzehpoor, Dmitrii F. Perepichka. Crystal Engineering of Room Temperature Phosphorescence in Organic Solids. Angewandte Chemie 2020, 132 (25) , 10063-10067. https://doi.org/10.1002/ange.201913393
  67. Ehsan Hamzehpoor, Dmitrii F. Perepichka. Crystal Engineering of Room Temperature Phosphorescence in Organic Solids. Angewandte Chemie International Edition 2020, 59 (25) , 9977-9981. https://doi.org/10.1002/anie.201913393
  68. Peifa Wei, Xuepeng Zhang, Junkai Liu, Guo‐Gang Shan, Haoke Zhang, Ji Qi, Weijun Zhao, Herman H.‐Y. Sung, Ian D. Williams, Jacky W. Y. Lam, Ben Zhong Tang. New Wine in Old Bottles: Prolonging Room‐Temperature Phosphorescence of Crown Ethers by Supramolecular Interactions. Angewandte Chemie 2020, 132 (24) , 9379-9384. https://doi.org/10.1002/ange.201912155
  69. Peifa Wei, Xuepeng Zhang, Junkai Liu, Guo‐Gang Shan, Haoke Zhang, Ji Qi, Weijun Zhao, Herman H.‐Y. Sung, Ian D. Williams, Jacky W. Y. Lam, Ben Zhong Tang. New Wine in Old Bottles: Prolonging Room‐Temperature Phosphorescence of Crown Ethers by Supramolecular Interactions. Angewandte Chemie International Edition 2020, 59 (24) , 9293-9298. https://doi.org/10.1002/anie.201912155
  70. Steffen Riebe, Christoph Wölper, Jan Balszuweit, Matthias Hayduk, Matias Ezequiel Gutierrez Suburu, Cristian A. Strassert, Nikos L. Doltsinis, Jens Voskuhl. Understanding the Role of Chalcogens in Ether‐Based Luminophores with Aggregation‐Induced Fluorescence and Phosphorescence. ChemPhotoChem 2020, 4 (6) , 398-406. https://doi.org/10.1002/cptc.202000002
  71. Chao Liu, Kaiyu Zhang, Qinxing Sun, Weina Li. Bile acid-terpyridine conjugates: Steroidal skeleton controlled AIE effect and metal-tunable fluorescence and supramolecular assembly properties. Tetrahedron 2020, 76 (26) , 131283. https://doi.org/10.1016/j.tet.2020.131283
  72. Xiaoyong Jia, Bingbing Yue, Lulu Zhou, Xiling Niu, Weiling Wu, Liangliang Zhu. Fluorescence to multi-colored phosphorescence interconversion of a novel, asterisk-shaped luminogen via multiple external stimuli. Chemical Communications 2020, 56 (31) , 4336-4339. https://doi.org/10.1039/D0CC00371A
  73. Solomon Omwoma. Trace Metal Detection in Aqueous Reservoirs Using Stilbene Intercalated Layered Rare-Earth Hydroxide Tablets. Journal of Analytical Methods in Chemistry 2020, 2020 , 1-9. https://doi.org/10.1155/2020/9712872
  74. Wenbin Xi, Junru Yu, Mengru Wei, Qianqian Qiu, Pengfei Xu, Zhaosheng Qian, Hui Feng. Photophysical Switching between Aggregation‐Induced Phosphorescence and Dual‐State Emission by Isomeric Substitution. Chemistry – A European Journal 2020, 26 (17) , 3733-3737. https://doi.org/10.1002/chem.202000233
  75. Marco Villa, Simone D’Agostino, Piera Sabatino, Raymond Noel, José Busto, Myriam Roy, Marc Gingras, Paola Ceroni. Pentasulfurated benzene-cored asterisks: relationship between crystal structure and luminescence properties. New Journal of Chemistry 2020, 44 (8) , 3249-3254. https://doi.org/10.1039/C9NJ05905A
  76. Taoyu Weng, Gleb Baryshnikov, Chao Deng, Xuping Li, Bin Wu, Hongwei Wu, Hans Ågren, Qi Zou, Tao Zeng, Liangliang Zhu. A Fluorescence–Phosphorescence–Phosphorescence Triple‐Channel Emission Strategy for Full‐Color Luminescence. Small 2020, 16 (7) , 1906475. https://doi.org/10.1002/smll.201906475
  77. He Wang, Huifang Shi, Wenpeng Ye, Xiaokang Yao, Qian Wang, Chaomin Dong, Wenyong Jia, Huili Ma, Suzhi Cai, Kaiwei Huang, Lishun Fu, Yanyun Zhang, Jiahuan Zhi, Long Gu, Yanli Zhao, Zhongfu An, Wei Huang. Amorphous Ionic Polymers with Color‐Tunable Ultralong Organic Phosphorescence. Angewandte Chemie 2019, 131 (52) , 18952-18958. https://doi.org/10.1002/ange.201911331
  78. He Wang, Huifang Shi, Wenpeng Ye, Xiaokang Yao, Qian Wang, Chaomin Dong, Wenyong Jia, Huili Ma, Suzhi Cai, Kaiwei Huang, Lishun Fu, Yanyun Zhang, Jiahuan Zhi, Long Gu, Yanli Zhao, Zhongfu An, Wei Huang. Amorphous Ionic Polymers with Color‐Tunable Ultralong Organic Phosphorescence. Angewandte Chemie International Edition 2019, 58 (52) , 18776-18782. https://doi.org/10.1002/anie.201911331
  79. Chuan Dong, Jin Yuan, Heinz Hoffmann, Jingcheng Hao. Self-assembly and photo-responsive behavior of bis-terpyridyl Eu3+-complex L1. New Journal of Chemistry 2019, 43 (48) , 19355-19364. https://doi.org/10.1039/C9NJ04252K
  80. Zengjie Liu, Jiarui Wu, Chunyu Wang, Jie Yang, Yan Wang, Ying-Wei Yang. Stimuli-responsive fluorescent supramolecular polymer network based on a monofunctionalized leaning tower[6]arene. Chinese Chemical Letters 2019, 30 (12) , 2299-2303. https://doi.org/10.1016/j.cclet.2019.10.023
  81. Weijun Zhao, Tsz Shing Cheung, Nan Jiang, Wenbin Huang, Jacky W. Y. Lam, Xuepeng Zhang, Zikai He, Ben Zhong Tang. Boosting the efficiency of organic persistent room-temperature phosphorescence by intramolecular triplet-triplet energy transfer. Nature Communications 2019, 10 (1) https://doi.org/10.1038/s41467-019-09561-8
  82. Lorien Benda, Benjamin Doistau, Caroline Rossi-Gendron, Lise-Marie Chamoreau, Bernold Hasenknopf, Guillaume Vives. Substrate-dependent allosteric regulation by switchable catalytic molecular tweezers. Communications Chemistry 2019, 2 (1) https://doi.org/10.1038/s42004-019-0246-9
  83. Jianhui Yuan, Qi Zhou, Xuelin Dong, Binbin Zhang, Qin Wang, Yajiang Yang, Yonggui Liao, Hong Wang. Dissolved oxygen-assisted enhancing room temperature phosphorescence of palladium-porphyrin in micelle-hybridized supramolecular gels under UV irradiation. Dyes and Pigments 2019, 170 , 107654. https://doi.org/10.1016/j.dyepig.2019.107654
  84. Tobias Blockhaus, Christian Klein‐Heßling, Peter M. Zehetmaier, Fabian L. Zott, Harish Jangra, Konstantin Karaghiosoff, Karlheinz Sünkel. Ferrocenes with a Persulfurated Cyclopentadienyl Ring: Synthesis, Structural Studies, and Optoelectronic Properties. Chemistry – A European Journal 2019, 25 (55) , 12684-12688. https://doi.org/10.1002/chem.201903033
  85. Yu Yan, Guang-Qiang Yin, Sandra Khalife, Zhan-Hang He, Chen Xu, Xiaopeng Li. Self-assembly of emissive metallocycles with tetraphenylethylene, BODIPY and terpyridine in one system. Supramolecular Chemistry 2019, 31 (8) , 597-605. https://doi.org/10.1080/10610278.2019.1659266
  86. Tingting Zhang, Heqi Gao, Anqi Lv, Ziyi Wang, Yongyang Gong, Dan Ding, Huili Ma, Yongming Zhang, Wang Zhang Yuan. Hydrogen bonding boosted the persistent room temperature phosphorescence of pure organic compounds for multiple applications. Journal of Materials Chemistry C 2019, 7 (29) , 9095-9101. https://doi.org/10.1039/C9TC02879J
  87. Tingting Lin, Xing Su, Kai Wang, Minjie Li, Hongwei Guo, Lulu Liu, Bo Zou, Yu-Mo Zhang, Yifei Liu, Sean Xiao-An Zhang. An AIE fluorescent switch with multi-stimuli responsive properties and applications for quantitatively detecting pH value, sulfite anion and hydrostatic pressure. Materials Chemistry Frontiers 2019, 3 (6) , 1052-1061. https://doi.org/10.1039/C8QM00544C
  88. Jing Wang, Jing Liang, Xu Liu, Han Xiao, Bin Lan, Hai-Bo Liu. Mixed organic ligand-based colorimetric and ratiometric chemosensors for Co2+: structure–activity relationships. Analytical and Bioanalytical Chemistry 2019, 411 (12) , 2663-2674. https://doi.org/10.1007/s00216-019-01707-3
  89. Guilin Chen, Zaicai Zhou, Hui Feng, Chenyan Zhang, Yifan Wang, Zhaosheng Qian, Jianwei Pan. An aggregation-induced phosphorescence probe for calcium ion-specific detection and live-cell imaging in Arabidopsis thaliana. Chemical Communications 2019, 55 (33) , 4841-4844. https://doi.org/10.1039/C9CC01580A
  90. Man-Man Fang, Jie Yang, Zhen Li. Recent Advances in Purely Organic Room Temperature Phosphorescence Polymer. Chinese Journal of Polymer Science 2019, 37 (4) , 383-393. https://doi.org/10.1007/s10118-019-2218-z
  91. Hongwei Wu, Weijie Chi, Gleb Baryshnikov, Bin Wu, Yifan Gong, Dongxiao Zheng, Xin Li, Yanli Zhao, Xiaogang Liu, Hans Ågren, Liangliang Zhu. Crystal Multi‐Conformational Control Through Deformable Carbon‐Sulfur Bond for Singlet‐Triplet Emissive Tuning. Angewandte Chemie 2019, 131 (13) , 4372-4377. https://doi.org/10.1002/ange.201900703
  92. Hongwei Wu, Weijie Chi, Gleb Baryshnikov, Bin Wu, Yifan Gong, Dongxiao Zheng, Xin Li, Yanli Zhao, Xiaogang Liu, Hans Ågren, Liangliang Zhu. Crystal Multi‐Conformational Control Through Deformable Carbon‐Sulfur Bond for Singlet‐Triplet Emissive Tuning. Angewandte Chemie International Edition 2019, 58 (13) , 4328-4333. https://doi.org/10.1002/anie.201900703
  93. Marco Villa, Myriam Roy, Giacomo Bergamini, Marc Gingras, Paola Ceroni. A turn-on phosphorescent sensor of Pb 2+ in water by the formation of a coordination polymer. Dalton Transactions 2019, 48 (12) , 3815-3818. https://doi.org/10.1039/C9DT00251K
  94. Tingting Zhang, Zihao Zhao, Huili Ma, Yongming Zhang, Wang Zhang Yuan. Polymorphic Pure Organic Luminogens with Through‐Space Conjugation and Persistent Room‐Temperature Phosphorescence. Chemistry – An Asian Journal 2019, 14 (6) , 884-889. https://doi.org/10.1002/asia.201801727
  95. Xiaoyong Jia, Cancan Shao, Xin Bai, Qiaohui Zhou, Bin Wu, Linjun Wang, Bingbing Yue, Haiming Zhu, Liangliang Zhu. Photoexcitation-controlled self-recoverable molecular aggregation for flicker phosphorescence. Proceedings of the National Academy of Sciences 2019, 116 (11) , 4816-4821. https://doi.org/10.1073/pnas.1821991116
  96. Bo Li, Tian He, Xi Shen, Danting Tang, Shouchun Yin. Fluorescent supramolecular polymers with aggregation induced emission properties. Polymer Chemistry 2019, 10 (7) , 796-818. https://doi.org/10.1039/C8PY01396A
  97. Qian Ma, Pin Li, Zhiqiang Gao, Sam Fong Yau Li. Rapid, sensitive and highly specific label-free fluorescence biosensor for microRNA by branched rolling circle amplification. Sensors and Actuators B: Chemical 2019, 281 , 424-431. https://doi.org/10.1016/j.snb.2018.10.141
  98. Xianggui Kong, Xinrui Wang, Huimin Cheng, Yufei Zhao, Wenying Shi. Activating room temperature phosphorescence by organic materials using synergistic effects. Journal of Materials Chemistry C 2019, 7 (2) , 230-236. https://doi.org/10.1039/C8TC04482A
  99. Masaki Shimizu. Precious Metal-Free Organic Small Molecule Luminophores That Exhibit Room Temperature Phosphorescence. 2019,,, 43-76. https://doi.org/10.1007/978-3-319-99037-8_3
  100. Motahare-Sadat Hosseini, Issa Amjadi, Moheb Sheikhi, Masoud Mozafari. Supramolecular metallopolymers. 2019,,, 83-110. https://doi.org/10.1016/B978-0-12-816349-8.00005-9
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