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Mixed-Valent Click Intertwined Polymer Units Containing Biferrocenium Chloride Side Chains Form Nanosnakes that Encapsulate Gold Nanoparticles

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ISM, UMR CNRS 5255, Univ. Bordeaux, 351 Cours de la Libération, 33405 Talence Cedex, France
Laboratoire de Chimie de Coordination, UPR CNRS 8241, 205 Route de Narbonne, 31077 Toulouse Cedex 04, France
Cite this: J. Am. Chem. Soc. 2014, 136, 40, 13995–13998
Publication Date (Web):September 25, 2014
https://doi.org/10.1021/ja5079267
Copyright © 2014 American Chemical Society
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Abstract

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Polymers containing triazolylbiferrocene are synthesized by ROMP or radical chain reactions and react with HAuCl4 to provide class-2 mixed-valent triazolylbiferrocenium polyelectrolyte networks (observed inter alia by TEM and AFM) that encapsulate gold nanoparticles (AuNPs). With triazolylbiferrocenium in the side polymer chain, the intertwined polymer networks form nanosnakes, unlike with triazolylbiferrocenium in the main polymer chain. By contrast, simple ferrocene-containing polymers do not form such a ferricenium network upon reaction with AuIII, but only small AuNPs, showing that the triazolyl ligand, the cationic charge, and the biferrocenium structure are coresponsible for such network formations.

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Experimental methods, 1D and 2D (1H) and (13C) NMR spectroscopy, infrared, UV–vis, and mass spectra, SEC, DLS, cyclic voltammograms, TEM and AFM data. This material is available free of charge via the Internet at http://pubs.acs.org.

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