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Mechanochemical Activation and Patterning of an Adhesive Surface toward Nanoparticle Deposition

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Department of Chemistry and Department of Chemical and Biological Engineering, Northwestern University 2145 Sheridan Road, Evanston, Illinois 60208, United States
UNAM-Institute of Materials Science and Nanotechnology, Bilkent University, 06800 Ankara, Turkey
§ Department of Chemistry, Bilkent University, 06800 Ankara, Turkey
Cite this: J. Am. Chem. Soc. 2015, 137, 5, 1726–1729
Publication Date (Web):January 18, 2015
https://doi.org/10.1021/ja507983x
Copyright © 2015 American Chemical Society
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Abstract

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Mechanical pulling of adhesive tape creates radicals on the tape’s surface. These radicals are capable of reducing metal salts to the corresponding metal nanoparticles. In this way, the mechanically activated tape can be decorated with various types of nanoparticles, including Au, Ag, Pd, or Cu. While retaining their mechanical properties and remaining “sticky,” the tapes can exhibit new properties derived from the presence of metal nanoparticles (e.g., bacteriostaticity, increased electrical conductivity). They can also be patterned with nanoparticles only at selective locations of mechanical activation.

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