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    Janus Micelles Induced by Olefin Metathesis
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    Institut für Organische Chemie, Johannes Gutenberg-Universität Mainz, D-55099 Mainz, Germany
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2008, 130, 18, 5876–5877
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    https://doi.org/10.1021/ja801919y
    Published April 15, 2008
    Copyright © 2008 American Chemical Society
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    Abstract

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    A facile one-step procedure for hydrophobic modification and simultaneous TEM contrast enhancement via a regioselective olefin metathesis reaction using Grubbs’ catalyst is presented. Polyether diblock copolymers were investigated, and both the chain ends of the hydrophilic and the hydrophobic block were hydrophobically modified. Modification of the hydrophilic block results in nonsymmetric supramolecular structures (Janus micelles) which self-assemble into larger hierarchically organized super-micelles.

    Copyright © 2008 American Chemical Society

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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2008, 130, 18, 5876–5877
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ja801919y
    Published April 15, 2008
    Copyright © 2008 American Chemical Society
    Request reuse permissions

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