Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
Iridium Metal Complexes as an Unambiguous Probe of Intramolecular Vibrational Redistribution

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2008, 130, 36, 11842-11843
    Communication

    Iridium Metal Complexes as an Unambiguous Probe of Intramolecular Vibrational Redistribution
    Click to copy article linkArticle link copied!

    View Author Information
    Organic Semiconductor Centre, SUPA, School of Physics and Astronomy, University of St Andrews, North Haugh, St Andrews, Fife, KY16 9SS, United Kingdom, Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, United Kingdom, and Centre for Organic Photonics and Electronics, School of Molecular and Microbial Sciences, University of Queensland, Chemistry Building, Queensland 4072, Australia
    [email protected]
    †University of St Andrews.
    ‡University of Oxford.
    §University of Queensland.
    Other Access Options

    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2008, 130, 36, 11842–11843
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ja8036383
    Published August 14, 2008
    Copyright © 2008 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    Ultrafast luminescence spectroscopy has been undertaken on three iridium cored phosphorescent complexes, with the Ir(ppy)3 molecule being compared with two Ir(ppy)3 cored dendrimers. Energy dissipation by intramolecular vibrational redistribution (IVR) and cooling shows as a luminescence decay because it decreases the admixture of singlet character to the emitting triplet state. A larger amount of vibrational energy dissipates by IVR in dendrimer complexes. We have therefore found a methodology of obtaining unambiguous information on the IVR process and show its potential to study IVR rates as a function of vibrational energy.

    Copyright © 2008 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 19 publications.

    1. Bastian Schluschaß, Jan-Hendrik Borter, Severine Rupp, Serhiy Demeshko, Christian Herwig, Christian Limberg, Nicholas A. Maciulis, Jessica Schneider, Christian Würtele, Vera Krewald, Dirk Schwarzer, Sven Schneider. Cyanate Formation via Photolytic Splitting of Dinitrogen. JACS Au 2021, 1 (6) , 879-894. https://doi.org/10.1021/jacsau.1c00117
    2. Allison M. Brown, Catherine E. McCusker, Monica C. Carey, Ana Maria Blanco-Rodríguez, Michael Towrie, Ian P. Clark, Antonín Vlček, James K. McCusker. Vibrational Relaxation and Redistribution Dynamics in Ruthenium(II) Polypyridyl-Based Charge-Transfer Excited States: A Combined Ultrafast Electronic and Infrared Absorption Study. The Journal of Physical Chemistry A 2018, 122 (40) , 7941-7953. https://doi.org/10.1021/acs.jpca.8b06197
    3. Seungjun Yi, Jin-Hyoung Kim, Yang-Jin Cho, Jiwon Lee, Tae-Sup Choi, Dae Won Cho, Chyongjin Pac, Won-Sik Han, Ho-Jin Son, and Sang Ook Kang . Stable Blue Phosphorescence Iridium(III) Cyclometalated Complexes Prompted by Intramolecular Hydrogen Bond in Ancillary Ligand. Inorganic Chemistry 2016, 55 (7) , 3324-3331. https://doi.org/10.1021/acs.inorgchem.5b02511
    4. Fabrizio Messina, Enrico Pomarico, Mahsa Silatani, Etienne Baranoff, and Majed Chergui . Ligand-Centred Fluorescence and Electronic Relaxation Cascade at Vibrational Time Scales in Transition-Metal Complexes. The Journal of Physical Chemistry Letters 2015, 6 (22) , 4475-4480. https://doi.org/10.1021/acs.jpclett.5b02146
    5. Gordon J. Hedley, Arvydas Ruseckas and Ifor D. W. Samuel. Vibrational Energy Flow Controls Internal Conversion in a Transition Metal Complex. The Journal of Physical Chemistry A 2010, 114 (34) , 8961-8968. https://doi.org/10.1021/jp101087v
    6. Rajib Ghosh, Jahur A. Mondal, Hirendra N. Ghosh and Dipak K. Palit. Ultrafast Dynamics of the Excited States of the Uranyl Ion in Solutions. The Journal of Physical Chemistry A 2010, 114 (16) , 5263-5270. https://doi.org/10.1021/jp912039r
    7. Gordon J. Hedley, Arvydas Ruseckas and Ifor D. W. Samuel. Ultrafast Intersystem Crossing in a Red Phosphorescent Iridium Complex. The Journal of Physical Chemistry A 2009, 113 (1) , 2-4. https://doi.org/10.1021/jp808944n
    8. Agustina Cotic, Ivana Ramírez-Wierzbicki, Alejandro Cadranel. Harnessing high-energy MLCT excited states for artificial photosynthesis. Coordination Chemistry Reviews 2024, 514 , 215878. https://doi.org/10.1016/j.ccr.2024.215878
    9. Agustina Cotic, Koen Veys, Daniel Escudero, Alejandro Cadranel. Unusually high energy barriers for internal conversion in a {Ru(bpy)} chromophore. Physical Chemistry Chemical Physics 2022, 24 (43) , 26428-26437. https://doi.org/10.1039/D2CP03160D
    10. Majed Chergui. Ultrafast molecular photophysics in the deep-ultraviolet. The Journal of Chemical Physics 2019, 150 (7) https://doi.org/10.1063/1.5082644
    11. Qinchao Sun, Bogdan Dereka, Eric Vauthey, Latévi M. Lawson Daku, Andreas Hauser. Ultrafast transient IR spectroscopy and DFT calculations of ruthenium( ii ) polypyridyl complexes. Chemical Science 2017, 8 (1) , 223-230. https://doi.org/10.1039/C6SC01220E
    12. Yongquan Wu, Guanjie Zeng, Nannan Lvyue, Weihua Wu, Tianyu Jiang, Rongle Wu, Wei Guo, Xun Li, Xiaolin Fan. Triethylene glycol-modified iridium( iii ) complexes for fluorescence imaging of Schistosoma japonicum. Journal of Materials Chemistry B 2017, 5 (25) , 4973-4980. https://doi.org/10.1039/C7TB00662D
    13. Victor F. Plyusnin, Ivan P. Pozdnyakov, Vjacheslav P. Grivin, Aleksey I. Solovyev, Helge Lemmetyinen, Nikolai V. Tkachenko, Stanislav V. Larionov. Femtosecond spectroscopy of the dithiolate Cu( ii ) and Ni( ii ) complexes. Dalton Trans. 2014, 43 (47) , 17766-17774. https://doi.org/10.1039/C4DT01407C
    14. Chien‐Yu Chen, Huei‐Ru Tsai, Kun‐Yi Lu, Husan‐Hsiao Yao, Yu‐Han Ou Yang, Chien‐Hong Cheng, I‐Chia Chen. Triscyclometalated Iridium(III) Fluoro‐Substituted Carbene Complexes: Character of Emitting Triplet States and Excited State Dynamics. Journal of the Chinese Chemical Society 2013, 60 (7) , 965-973. https://doi.org/10.1002/jccs.201300161
    15. Ellen F. Reid, Paul L. Burn, Shih-Chun Lo, Conor F. Hogan. Solution and solid-state electrochemiluminescence of a fac-tris(2-phenylpyridyl)iridium(III)-cored dendrimer. Electrochimica Acta 2013, 100 , 72-77. https://doi.org/10.1016/j.electacta.2013.03.094
    16. C. Nemirow, J. Fine, Z. Lu, K. Diri, A.I. Krylov, C. Wittig. Photoionization of tris(2-phenylpyridine)iridium. Molecular Physics 2012, 110 (15-16) , 1893-1908. https://doi.org/10.1080/00268976.2012.689871
    17. Cheng-Huei Lin, Che-Wei Hsu, Jia-Ling Liao, Yi-Ming Cheng, Yun Chi, Tsung-Yi Lin, Min-Wen Chung, Pi-Tai Chou, Gene-Hsiang Lee, Chih-Hao Chang, Chin-Yao Shih, Chi-Lung Ho. Phosphorescent OLEDs assembled using Os(ii) phosphors and a bipolar host material consisting of both carbazole and dibenzophosphole oxide. Journal of Materials Chemistry 2012, 22 (21) , 10684. https://doi.org/10.1039/c2jm16674g
    18. A. Ruseckas, J. C. Ribierre, P. E. Shaw, S. V. Staton, P. L. Burn, I. D. W. Samuel. Singlet energy transfer and singlet-singlet annihilation in light-emitting blends of organic semiconductors. Applied Physics Letters 2009, 95 (18) , 183305. https://doi.org/10.1063/1.3253422
    19. Nathan J. Patmore. Photophysical properties of metal complexes. Annual Reports Section "A" (Inorganic Chemistry) 2009, 105 , 525. https://doi.org/10.1039/b818289m
    Download PDF
    Go to Journal of the American Chemical Society
    Get e-Alerts
    Get e-Alerts

    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2008, 130, 36, 11842–11843
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ja8036383
    Published August 14, 2008
    Copyright © 2008 American Chemical Society
    Request reuse permissions

    Article Views

    872

    Altmetric

    -

    Citations

    19
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.