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Synthesis and Reactions of a Stable 1,2-Diaryl-1,2-dibromodisilene: A Precursor for Substituted Disilenes and a 1,2-Diaryldisilyne

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Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan, Department of Theoretical Molecular Science, Institute for Molecular Science, Myodaiji, Okazaki 444-8585, Japan, and Department of Chemistry, School of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan
[email protected]
†Kyoto University.
‡Institute for Molecular Science.
§Waseda University.
Cite this: J. Am. Chem. Soc. 2008, 130, 42, 13856–13857
Publication Date (Web):September 26, 2008
https://doi.org/10.1021/ja8061002
Copyright © 2008 American Chemical Society
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Abstract

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Synthesis and isolation of the stable diaryldibromodisilene, Bbt(Br)Si═Si(Br)Bbt, has been accomplished for the first time. The dibromodisilene underwent substitution reactions with organometallic reagents on the low-coordinated silicon atom to afford the corresponding substituted disilenes. Furthermore, the reaction of 1 with t-BuLi afforded the corresponding 1,2-diaryldisilyne, BbtSi≡SiBbt, the characters of which were revealed by spectroscopic and crystallographic analyses.

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