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Synthesis of Copolymers by Alternating ROMP (AROMP)

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Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400
[email protected]; [email protected]
Cite this: J. Am. Chem. Soc. 2009, 131, 10, 3444–3445
Publication Date (Web):February 18, 2009
https://doi.org/10.1021/ja809661k
Copyright © 2009 American Chemical Society
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Abstract

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The alternating polymerization of cyclobutene 1-carboxylic esters and cyclohexene derivatives with the precatalyst [(H2IMes)(3-Br-pyr)2Cl2Ru═CHPh] is described. This reaction is synthetically accessible and provides (AB)n heteropolymers with an alternating backbone and alternating functionality. The regiocontrol of heteropolymer formation derives from the inability of the cyclobutene ester and cyclohexene monomers to undergo homopolymerization in combination with the favorable kinetics of cross polymerization.

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