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Reactivity of an Aryl-Substituted Silicon−Silicon Triple Bond: Reactions of a 1,2-Diaryldisilyne with Alkenes

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Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
[email protected]
Cite this: J. Am. Chem. Soc. 2010, 132, 8, 2546–2547
Publication Date (Web):February 3, 2010
https://doi.org/10.1021/ja9108566
Copyright © 2010 American Chemical Society
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Abstract

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The reactivity of a bulky, diaryl-substituted disilyne, Ar−Si≡Si−Ar, was examined for the first time. Reaction of the disilyne with ethylene yielded an ethylene-bridged bis(silacyclopropane), which is interpreted as a further reaction product of the initially formed 1,2-disilacyclobutene species with ethylene. A cyclohexane fused with a 1,2-disilacyclobutene was obtained in the reaction with cyclohexene. In the reaction with 2,3-dimethyl-1,3-butadiene, a tricyclo derivative was isolated from the complex product mixture.

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Experimental details, characterization data for new compounds, and crystallographic data for 2, 3, and 4 (CIF). This material is available free of charge via the Internet at http://pubs.acs.org.

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