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Porous Germanates:  Synthesis, Structure, and Inclusion Properties of Ge7O14.5F2·[(CH3)2NH2]3(H2O)0.86

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The Department of Chemistry and Biochemistry, Goldwater Center for Science and Engineering Arizona State University, Tempe, Arizona 85287-1604
Cite this: J. Am. Chem. Soc. 1998, 120, 33, 8567–8568
Publication Date (Web):August 8, 1998
https://doi.org/10.1021/ja9813919
Copyright © 1998 American Chemical Society

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    Crystallographic data for Ge7O14.5F2·[(CH3)2NH2]3 (H2O)0.86 (ASU-12), including crystal structure analysis report, positional parameters, thermal parameters, and interatomic distances and angles (28 pages, print/PDF). See any current masthead page for ordering information and Web access instructions.

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    51. Xiqiao Wang, John Corn, Frank Hagelberg. Endohedral complexes of Polyhedral Oligomeric Silsesquioxane (POSS) cages with transition metal dihydrides. Chemical Physics 2013, 426 , 48-53. https://doi.org/10.1016/j.chemphys.2013.09.003
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    75. Kirsten E. Christensen, Lei Shi, Liqiu Tang, Tony Conradsson, Mike S. Dadachov, Xiaodong Zou. Design of three-dimensional open-framework structures from inorganic clusters. 2007, 682-689. https://doi.org/10.1016/S0167-2991(07)80908-6
    76. Maureen R. Regan, Ipsita A. Banerjee. In situ growth of CoPt nanoparticles in porous germania nanospheres. Materials Letters 2007, 61 (1) , 71-75. https://doi.org/10.1016/j.matlet.2006.04.008
    77. Maureen R. Regan, Ipsita A. Banerjee. Preparation of Au–Pd bimetallic nanoparticles in porous germania nanospheres: A study of their morphology and catalytic activity. Scripta Materialia 2006, 54 (5) , 909-914. https://doi.org/10.1016/j.scriptamat.2005.10.068
    78. Julien Dutour, Gérard Férey, Caroline Mellot-Draznieks. Structures and energetics of open-framework germanates; Exploration of hypothetical zeolitic GeO2 structures based on D4R units. Solid State Sciences 2006, 8 (3-4) , 241-247. https://doi.org/10.1016/j.solidstatesciences.2006.02.015
    79. Sergio Fernández-Armas, José L. Mesa, José L. Pizarro, U-Chan Chung, María I. Arriortua, Teófilo Rojo. Two new two-dimensional organically templated phosphite compounds: (C6H16N2)0.5[M(HPO3)F], M=Fe(II) and Co(II): Solvothermal synthesis, crystal structures, thermal, spectroscopic, and magnetic properties. Journal of Solid State Chemistry 2005, 178 (11) , 3554-3562. https://doi.org/10.1016/j.jssc.2005.09.032
    80. Chao Qin, Lei Gao, Enbo Wang. Germanium: Inorganic ChemistryBased in part on the article Germanium: Inorganic Chemistry by Frank Glockling which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .. 2005https://doi.org/10.1002/9781119951438.eibc0074
    81. Chao Qin, Lei Gao, Enbo Wang. Germanium: Inorganic ChemistryBased in part on the article Germanium: Inorganic Chemistry by Frank Glockling which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .. 2005https://doi.org/10.1002/0470862106.ia079
    82. Yan Xu, Wei Fan, S. P. Elangovan, Masaru Ogura, Tatsuya Okubo. [Ge 9 O 14 (OH) 12 ](C 6 N 2 H 16 ) 2 ·H 2 O: A Novel Germanate with Ge−O Helical Chains Formed by Hydrothermal Synthesis that Can Separate trans and cis Isomers in Situ. European Journal of Inorganic Chemistry 2004, 2004 (23) , 4547-4549. https://doi.org/10.1002/ejic.200400566
    83. Zhi-En Lin, Jie Zhang, Shou-Tian Zheng, Guo-Yu Yang. Syntheses and structures of two new 3D open-framework germanates constructed from Ge9O18(OH)4 clusters. Microporous and Mesoporous Materials 2004, 74 (1-3) , 205-211. https://doi.org/10.1016/j.micromeso.2004.06.020
    84. C. THOMPSON, N. R. CHAMPNESS, A. N. KHLOBYSTOV, C. J. ROBERTS, M. SCHRÖDER, S. J. B. TENDLER, M. J. WILKINSON. Using microscopic techniques to reveal the mechanism of anion exchange in crystalline co‐ordination polymers. Journal of Microscopy 2004, 214 (3) , 261-271. https://doi.org/10.1111/j.0022-2720.2004.01346.x
    85. Yan Xu, Masaru Ogura, Tatsuya Okubo. Hydrothermal synthesis and structure of ASU-14 topological framework by using ethylenediamine as a structure-directing agent. Microporous and Mesoporous Materials 2004, 70 (1-3) , 1-6. https://doi.org/10.1016/j.micromeso.2003.12.015
    86. Avelino Corma, Mark E. Davis. Issues in the Synthesis of Crystalline Molecular Sieves: Towards the Crystallization of Low Framework‐Density Structures. ChemPhysChem 2004, 5 (3) , 304-313. https://doi.org/10.1002/cphc.200300997
    87. A. Corma. Towards a rationalization of zeolite and zeolitic materials synthesis. 2004, 25-40. https://doi.org/10.1016/S0167-2991(04)80782-1
    88. Yan Xu, Wei Fan, Naotaka Chino, Kazuhiro Uehara, Shirou Hikichi, Noritaka Mizuno, Masaru Ogura, Tatsuya Okubo. The Hydrothermal Synthesis and Crystal Structure of (H2O)[Ge5O10] and [(CH3)4N][Ge10O20OH], Two Novel Porous Germanates. Chemistry Letters 2004, 33 (1) , 74-75. https://doi.org/10.1246/cl.2004.74
    89. Tong-Bu Lu, Rudy L Luck. Interlocking frameworks. A consequence of enlarging spacers from 4-pyridinecarboxylate to 4-(4-pyridyl)benzoate. Inorganica Chimica Acta 2003, 351 , 345-355. https://doi.org/10.1016/S0020-1693(03)00215-9
    90. Yaming Zhou, Haoguo Zhu, Zhenxia Chen, Minqin Chen, Yan Xu, Haoyu Zhang, Dongyuan Zhao. A Large 24-Membered-Ring Germanate Zeolite-Type Open-Framework Structure with Three-Dimensional Intersecting Channels. Angewandte Chemie 2001, 113 (11) , 2224-2226. https://doi.org/10.1002/1521-3757(20010601)113:11<2224::AID-ANGE2224>3.0.CO;2-1
    91. Yaming Zhou, Haoguo Zhu, Zhenxia Chen, Minqin Chen, Yan Xu, Haoyu Zhang, Dongyuan Zhao. A Large 24-Membered-Ring Germanate Zeolite-Type Open-Framework Structure with Three-Dimensional Intersecting Channels. Angewandte Chemie International Edition 2001, 40 (11) , 2166-2168. https://doi.org/10.1002/1521-3773(20010601)40:11<2166::AID-ANIE2166>3.0.CO;2-C
    92. Kil Sik Min, Myunghyun Paik Suh. Self-Assembly and Selective Guest Binding of Three-Dimensional Open-Framework Solids from a Macrocyclic Complex as a Trifunctional Metal Building Block. Chemistry 2001, 7 (1) , 303-313. https://doi.org/10.1002/1521-3765(20010105)7:1<303::AID-CHEM303>3.0.CO;2-H
    93. T Conradsson, M.S Dadachov, X.D Zou. Synthesis and structure of (Me3N)6[Ge32O64](H2O)4.5, a thermally stable novel zeotype with 3D interconnected 12-ring channels. Microporous and Mesoporous Materials 2000, 41 (1-3) , 183-191. https://doi.org/10.1016/S1387-1811(00)00288-2
    94. Nelson H. Morgon, Luciano A. Xavier, José M. Riveros. Gas-phase nucleophilic reactions of Ge(OCH3)4: experimental and computational characterization of pentacoordinated Ge anions. International Journal of Mass Spectrometry 2000, 195-196 , 363-375. https://doi.org/10.1016/S1387-3806(99)00189-X
    95. Concepción Cascales, Enrique Gutiérrez-Puebla, Marta Iglesias, M. Angeles Monge, Caridad Ruíz-Valero. Ein Ge-Zeolithanalogon mit Übergangsmetallkomplexe enthaltenden Tunneln. Angewandte Chemie 1999, 111 (16) , 2592-2595. https://doi.org/10.1002/(SICI)1521-3757(19990816)111:16<2592::AID-ANGE2592>3.0.CO;2-C