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Significant Enhancement of Hydrogen Evolution Reaction Activity by Negatively Charged Pt through Light Doping of W

  • Daiya Kobayashi*
    Daiya Kobayashi
    Nippon Soda Co. Ltd., Chiba Research Center, 12-54 Goi-minamikaigan, Ichihara, Chiba 290-0045, Japan
    Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan
    *[email protected]
  • Hirokazu Kobayashi*
    Hirokazu Kobayashi
    Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan
    *[email protected]
  • Dongshuang Wu
    Dongshuang Wu
    Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan
  • Shinya Okazoe
    Shinya Okazoe
    Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan
  • Kohei Kusada
    Kohei Kusada
    Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan
    More by Kohei Kusada
  • Tomokazu Yamamoto
    Tomokazu Yamamoto
    Department of Applied Quantum Physics and Nuclear Engineering, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan
    Kyushu University and the Ultramicroscopy Research Center, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan
  • Takaaki Toriyama
    Takaaki Toriyama
    Kyushu University and the Ultramicroscopy Research Center, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan
  • Syo Matsumura
    Syo Matsumura
    Department of Applied Quantum Physics and Nuclear Engineering, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan
    Kyushu University and the Ultramicroscopy Research Center, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan
    INAMORI Frontier Research Center, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan
  • Shogo Kawaguchi
    Shogo Kawaguchi
    Japan Synchrotron Radiation Research Institute (JASRI), SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan
  • Yoshiki Kubota
    Yoshiki Kubota
    Department of Physical Science, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
  • Susan Meñez Aspera
    Susan Meñez Aspera
    National Institute of Technology, Akashi College, 679-3 Nishioka, Uozumi, Akashi, Hyogo 674-8501 Japan
  • Hiroshi Nakanishi
    Hiroshi Nakanishi
    National Institute of Technology, Akashi College, 679-3 Nishioka, Uozumi, Akashi, Hyogo 674-8501 Japan
  • Shigebumi Arai
    Shigebumi Arai
    Nippon Soda Co. Ltd., Chiba Research Center, 12-54 Goi-minamikaigan, Ichihara, Chiba 290-0045, Japan
  • , and 
  • Hiroshi Kitagawa*
    Hiroshi Kitagawa
    Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan
    INAMORI Frontier Research Center, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan
    Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
    *[email protected]
Cite this: J. Am. Chem. Soc. 2020, 142, 41, 17250–17254
Publication Date (Web):September 30, 2020
https://doi.org/10.1021/jacs.0c07143
Copyright © 2020 American Chemical Society

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    Supporting Info (1)»

    Abstract

    Abstract Image

    We report novel PtW solid-solution nanoparticles (NPs) produced through electrochemical cleaning of core/shell PtW@WO3 NPs. The resulting PtW NPs achieved a record hydrogen evolution reaction (HER) performance as a class of Pt-based solid-solution alloys. A current density of 10 mA cm–2 was reached with an overpotential of 19.4 mV, which is significantly lower than that of a commercial Pt catalyst (26.3 mV). The PtW NPs also exhibited long-term stability. Theoretical calculations revealed that negatively charged Pt atoms adjacent to a W atom provide favorable hydrogen adsorption energies for the HER, realizing significantly enhanced HER activity.

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    • Experimental details, TEM images, XPS spectra, STEM-EDX mapping images, results of electrochemical measurements, and calculation conditions for catalytic activities (PDF)

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