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Inorganic Approach to Stabilizing Nanoscale Toroidicity in a Tetraicosanuclear Fe18Dy6 Single Molecule Magnet

  • Hagen Kaemmerer
    Hagen Kaemmerer
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany
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    Orcidhttp://orcid.org/0000-0003-0037-6668
  • , 
  • Amer Baniodeh
    Amer Baniodeh
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany
    Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
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  • , 
  • Yan Peng*
    Yan Peng
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany
    Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
    *Email: [email protected]
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    Orcidhttp://orcid.org/0000-0002-5962-4833
  • , 
  • Eufemio Moreno-Pineda
    Eufemio Moreno-Pineda
    Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
    Depto. de Química-Física, Escuela de Química, Facultad de Ciencias Naturales, Exactas y Tecnología, Universidad de Panamá, Panamá, Panamá
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    Orcidhttp://orcid.org/0000-0002-9643-0341
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  • Michael Schulze
    Michael Schulze
    Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
    Physikalisches Institut, Karlsruhe Institute of Technology, Wolfgang-Gaede-Str. 1, 76131 Karlsruhe, Germany
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    Orcidhttp://orcid.org/0000-0002-7169-0630
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  • Christopher E. Anson
    Christopher E. Anson
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany
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    Orcidhttp://orcid.org/0000-0001-7992-7797
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  • Wolfgang Wernsdorfer
    Wolfgang Wernsdorfer
    Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
    Physikalisches Institut, Karlsruhe Institute of Technology, Wolfgang-Gaede-Str. 1, 76131 Karlsruhe, Germany
    Institute for Quantum Materials and Technologies (IQMT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
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    Orcidhttp://orcid.org/0000-0003-4602-5257
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  • Jürgen Schnack*
    Jürgen Schnack
    Fakultät für Physik, Universität Bielefeld, Postfach 100131, 33501 Bielefeld, Germany
    *Email: [email protected]
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  • , and 
  • Annie K. Powell*
    Annie K. Powell
    Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany
    Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
    Institute for Quantum Materials and Technologies (IQMT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
    *Email: [email protected]
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    Orcidhttp://orcid.org/0000-0003-3944-7427
Cite this: J. Am. Chem. Soc. 2020, 142, 35, 14838–14842
Publication Date (Web):August 11, 2020
https://doi.org/10.1021/jacs.0c07168
Copyright © 2020 American Chemical Society
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    Abstract

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    Cyclic coordination clusters (CCCs) are proving to provide an extra dimension in terms of exotic magnetic behavior as a result of their finite but cyclized chain structures. The Fe18Dy6 CCC is a Single Molecule Magnet with the highest nuclearity among Ln containing clusters. The three isostructural compounds [Fe18Ln6(μ-OH)6(ampd)12(Hampd)12(PhCO2)24](NO3)6·38MeCN for Ln = DyIII (1), LuIII (2), or YIII (3), where H2ampd = 2-amino-2-methyl-1,3-propanediol, are reported. These can be described in terms of the cyclization of six {Fe3Ln(μOH)(ampd)2(Hampd)2(PhCO2)4}+ units with six nitrate counterions to give the neutral cluster. The overall structure consists of two giant Dy3 triangles sandwiching a strongly antiferromagnetically coupled Fe18 ring, leading to a toroidal arrangement of the anisotropy axis of the Dy ions, making this the biggest toroidal arrangement on a molecular level known so far.

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    • Crystallographic data for Fe18Y6 (CIF)

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