Post-Synthetically Elaborated BODIPY-Based Porous Organic Polymers (POPs) for the Photochemical Detoxification of a Sulfur Mustard SimulantClick to copy article linkArticle link copied!
- Ahmet AtilganAhmet AtilganDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United StatesMore by Ahmet Atilgan
- M. Mustafa CetinM. Mustafa CetinDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United StatesDepartment of Bioinformatics and Genetics, Faculty of Engineering and Natural Science, Kadir Has University, 34083 Cibali Campus Fatih, Istanbul, TurkeyMore by M. Mustafa Cetin
- Jierui YuJierui YuDepartment of Chemistry and Biochemistry, Southern Illinois University, 1245 Lincoln Drive, Carbondale, Illinois 62901, United StatesMore by Jierui Yu
- Yassine BeldjoudiYassine BeldjoudiDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United StatesMore by Yassine Beldjoudi
- Jian LiuJian LiuDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United StatesMore by Jian Liu
- Charlotte L. SternCharlotte L. SternDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United StatesMore by Charlotte L. Stern
- Furkan M. CetinFurkan M. CetinDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United StatesMore by Furkan M. Cetin
- Timur IslamogluTimur IslamogluDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United StatesMore by Timur Islamoglu
- Omar K. FarhaOmar K. FarhaDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United StatesMore by Omar K. Farha
- Pravas Deria*Pravas Deria*[email protected]Department of Chemistry and Biochemistry, Southern Illinois University, 1245 Lincoln Drive, Carbondale, Illinois 62901, United StatesMore by Pravas Deria
- J. Fraser Stoddart*J. Fraser Stoddart*[email protected]Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United StatesInstitute of Molecular Design and Synthesis, Tianjin University, 92 Weijin Road, Nankai District, Tianjin 300072, P. R. ChinaSchool of Chemistry, University of New South Wales, Sydney, NSW 2052, AustraliaMore by J. Fraser Stoddart
- Joseph T. Hupp*Joseph T. Hupp*[email protected]Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United StatesMore by Joseph T. Hupp
Abstract

Designing new materials for the effective detoxification of chemical warfare agents (CWAs) is of current interest given the recent use of CWAs. Although halogenated boron-dipyrromethene derivatives (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene or BDP or BODIPY) at the 2 and 6 positions have been extensively explored as efficient photosensitizers for generating singlet oxygen (1O2) in homogeneous media, their utilization in the design of porous organic polymers (POPs) has remained elusive due to the difficulty of controlling polymerization processes through cross-coupling synthesis pathways. Our approach to overcome these difficulties and prepare halogenated BODIPY-based porous organic polymers (X-BDP-POP where X = Br or I) represents an attractive alternative through post-synthesis modification (PSM) of the parent hydrogenated polymer. Upon synthesis of both the parent polymer, H-BDP-POP, and its post-synthetically modified derivatives, Br-BDP-POP and I-BDP-POP, the BET surface areas of all POPs have been measured and found to be 640, 430, and 400 m2·g–1, respectively. In addition, the insertion of heavy halogen atoms at the 2 and 6 positions of the BODIPY unit leads to the quenching of fluorescence (both polymer and solution-phase monomer forms) and the enhancement of phosphorescence (particularly for the iodo versions of the polymers and monomers), as a result of efficient intersystem crossing. The heterogeneous photocatalytic activities of both the parent POP and its derivatives for the detoxification of the sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES), have been examined; the results show a significant enhancement in the generation of singlet oxygen (1O2). Both the bromination and iodination of H-BDP-POP served to shorten by 5-fold of the time needed for the selective and catalytic photo-oxidation of CEES to 2-chloroethyl ethyl sulfoxide (CEESO).
Cited By
Smart citations by scite.ai include citation statements extracted from the full text of the citing article. The number of the statements may be higher than the number of citations provided by ACS Publications if one paper cites another multiple times or lower if scite has not yet processed some of the citing articles.
This article is cited by 111 publications.
- Calvin Samuel, Tokala Navaneetha, Junaid Ali, Viswanathan Baskar. Cerium(III) Phosphinate and Cerium(IV) Phosphostibonate Acting as Catalysts for Mild, Selective Sulfoxidation. Inorganic Chemistry 2025, 64
(2)
, 872-881. https://doi.org/10.1021/acs.inorgchem.4c03943
- Madhurima Sarkar, Suprabhat Sarkar, Monisha Saha, Khushi Luvani, Abhijit Patra. Intriguing Facets of Solution Processable Cross-Linked Porous Organic Polymers. Accounts of Materials Research 2024, 5
(11)
, 1353-1365. https://doi.org/10.1021/accountsmr.4c00197
- Zehao Zhao, Wenshuo Xu, Dongxin Yang, Weitao Gong. Construction of Donor–Acceptor-Type Conjugated Microporous Polymers by Oxidative Coupling of Boranil-Carbazole Mixed Monomers for Enhanced Photocatalytic Oxidation. ACS Applied Materials & Interfaces 2024, 16
(42)
, 57200-57208. https://doi.org/10.1021/acsami.4c13583
- Qiuyuan Lin, Zhiye Zheng, Shuting Xu, Sheng Ye, Hui Zhang, Zhikun Zhang, Hongyu Wang. Copper(II) Surface-Functionalized Porous Organic Polymers for One-Pot Synthesis of Sulfoxide via Chan-Lam Cross-Coupling and Photooxidation Reactions. ACS Applied Polymer Materials 2024, 6
(13)
, 7859-7867. https://doi.org/10.1021/acsapm.4c01427
- Wang-Kang Han, Xin Liu, Ruo-Meng Zhu, Jia-Xing Fu, Yong Liu, Jinfang Zhang, Huan Pang, Zhi-Guo Gu. Panchromatic Light-Harvesting Three-Dimensional Metal Covalent Organic Frameworks for Boosting Photocatalysis. ACS Applied Materials & Interfaces 2024, 16
(19)
, 24831-24839. https://doi.org/10.1021/acsami.4c04468
- Lifang Geng, Hui Li, Jiaming Liu, Zhijie Yang, Jingjing Wei. Molecular Stacking Dependent Molecular Oxygen Activation in Supramolecular Polymeric Photocatalysts. The Journal of Physical Chemistry Letters 2024, 15
(11)
, 3127-3134. https://doi.org/10.1021/acs.jpclett.4c00112
- Takahide Shimada, Takashi Kaneko, Yusuke Notsuka, Jinseok Kim, Shigeki Mori, Soji Shimizu, Jiwon Kim, Kenji Kamada, Dongho Kim, Yoshihisa Yamaoka, Hiroyuki Furuta, Masatoshi Ishida. Molecular Design for Stable Near-Infrared-II Two-Photon Excitation-Induced Photoacoustic Contrast Agents Based on Donor-Substituted BODIPYs. ACS Applied Optical Materials 2024, 2
(1)
, 211-219. https://doi.org/10.1021/acsaom.3c00400
- Meng Zhang, Man Cao, Zhi-Bing Sun, Zhen Han, Zhao-Yang Wang, Qian-You Wang, Shuang-Quan Zang. Modulating BODIPY-Based Silver Chalcogenide Cluster-Based Metal–Organic Frameworks for Real-Time Decontamination of a Gaseous Sulfur Mustard Simulant. Chemistry of Materials 2023, 35
(23)
, 10238-10246. https://doi.org/10.1021/acs.chemmater.3c02470
- Li Zhang, Chen Sun, Sai-Jin Xiao, Quan-Gen Tan, Gui-Ping Yang, Jia-Qi Fan, Yu-Ting Luo, Ru-Ping Liang, Jian-Ding Qiu. Deposition of Silver Nanostructures on Covalent Organic Frameworks for Photocatalytic Degradation of Sulfur Mustard Simulants. ACS Applied Nano Materials 2023, 6
(18)
, 17083-17091. https://doi.org/10.1021/acsanm.3c03262
- Kun Wu, Xin-Yi Liu, Pei-Wen Cheng, Yong-Liang Huang, Ji Zheng, Mo Xie, Weigang Lu, Dan Li. Linker Engineering for Reactive Oxygen Species Generation Efficiency in Ultra-Stable Nickel-Based Metal–Organic Frameworks. Journal of the American Chemical Society 2023, 145
(34)
, 18931-18938. https://doi.org/10.1021/jacs.3c05585
- Hongyu Li, Han Xu, Guanglin Wang, Junchang Chen, Dandan Ji, Yangyang Huang, Guoqing Cui, Hui He, Zhengqing Guo. Rational Design of Mesoporous Coordination Polymer Nanophotosensitizers for Photodynamic Tumor Ablation. ACS Applied Materials & Interfaces 2023, 15
(18)
, 21746-21753. https://doi.org/10.1021/acsami.2c22095
- Sk Rajab Ali, Mrinmoy De. Fe-Doped MoS2 Nanozyme for Antibacterial Activity and Detoxification of Mustard Gas Simulant. ACS Applied Materials & Interfaces 2022, 14
(38)
, 42940-42949. https://doi.org/10.1021/acsami.2c11245
- Di Chen, Dan Luo, Yanlei He, Jinya Tian, Yao Yu, Hongyu Wang, Jonathan L. Sessler, Xiaodong Chi. Calix[4]pyrrole-Based Azo-Bridged Porous Organic Polymer for Bromine Capture. Journal of the American Chemical Society 2022, 144
(37)
, 16755-16760. https://doi.org/10.1021/jacs.2c08327
- Ahmet Atilgan, Yassine Beldjoudi, Jierui Yu, Kent O. Kirlikovali, Jacob A. Weber, Jian Liu, Dahee Jung, Pravas Deria, Timur Islamoglu, J. Fraser Stoddart, Omar K. Farha, Joseph T. Hupp. BODIPY-Based Polymers of Intrinsic Microporosity for the Photocatalytic Detoxification of a Chemical Threat. ACS Applied Materials & Interfaces 2022, 14
(10)
, 12596-12605. https://doi.org/10.1021/acsami.1c21750
- Xiangui Ma, Mengmeng Lv, Fangxin Du, Cunqi Wu, Baohua Lou, Abdallah M. Zeid, Guobao Xu. Dimeric G-Quadruplex: An Efficient Probe for Ultrasensitive Fluorescence Detection of Mustard Compounds. Analytical Chemistry 2022, 94
(9)
, 4112-4118. https://doi.org/10.1021/acs.analchem.2c00124
- Giulia Bonfant, Davide Balestri, Jacopo Perego, Angiolina Comotti, Silvia Bracco, Matthieu Koepf, Marcello Gennari, Luciano Marchiò. Phosphine Oxide Porous Organic Polymers Incorporating Cobalt(II) Ions: Synthesis, Characterization, and Investigation of H2 Production. ACS Omega 2022, 7
(7)
, 6104-6112. https://doi.org/10.1021/acsomega.1c06522
- Yajiao Hao, Edgar K. Papazyan, Yong Ba, Yangyang Liu. Mechanism-Guided Design of Metal–Organic Framework Composites for Selective Photooxidation of a Mustard Gas Simulant under Solvent-Free Conditions. ACS Catalysis 2022, 12
(1)
, 363-371. https://doi.org/10.1021/acscatal.1c04755
- Yanhong Chen, Shenzhen Chang, Haiyan An, Yanqin Li, Qingshan Zhu, Huiyun Luo, Yaohui Huang. Two Polymorphic Polyoxometalate-Based Metal–Organic Frameworks for the Efficient Synthesis of Functionalized Sulfoxides and Detoxification of Mustard Gas Simulants. ACS Sustainable Chemistry & Engineering 2021, 9
(46)
, 15683-15693. https://doi.org/10.1021/acssuschemeng.1c06433
- Bingyan Zhou, Zixu Chen, Shengyu Feng, Dengxu Wang, Hongzhi Liu. Engineering Functionality in Organic Porous Networks by Multicomponent Polymerization. Macromolecules 2021, 54
(16)
, 7642-7652. https://doi.org/10.1021/acs.macromol.1c00777
- Zi-Hao Long, Dong Luo, Kun Wu, Zi-Ye Chen, Ming-Min Wu, Xiao-Ping Zhou, Dan Li. Superoxide Ion and Singlet Oxygen Photogenerated by Metalloporphyrin-Based Metal–Organic Frameworks for Highly Efficient and Selective Photooxidation of a Sulfur Mustard Simulant. ACS Applied Materials & Interfaces 2021, 13
(31)
, 37102-37110. https://doi.org/10.1021/acsami.1c08840
- Meng-Hua Li, Shu-Li Lv, Ming-Hua You, Mei-Jin Lin. Construction of Novel Polyoxometalate/Perylenediimide Hybrid Heterostructures for Enhanced Photocatalytic Oxidation of Mustard Gas Simulants. Crystal Growth & Design 2021, 21
(8)
, 4738-4745. https://doi.org/10.1021/acs.cgd.1c00576
- Yajiao Hao, Brandon M. Liu, Timothy F. Bennett, Charlotte G. Monsour, Matthias Selke, Yangyang Liu. Determination of Singlet Oxygen Quantum Yield of a Porphyrinic Metal–Organic Framework. The Journal of Physical Chemistry C 2021, 125
(13)
, 7392-7400. https://doi.org/10.1021/acs.jpcc.1c00310
- Pei-Pei Jia, Lin Xu, Yi-Xiong Hu, Wei-Jian Li, Xu-Qing Wang, Qing-Hui Ling, Xueliang Shi, Guang-Qiang Yin, Xiaopeng Li, Haitao Sun, Yanrong Jiang, Hai-Bo Yang. Orthogonal Self-Assembly of a Two-Step Fluorescence-Resonance Energy Transfer System with Improved Photosensitization Efficiency and Photooxidation Activity. Journal of the American Chemical Society 2021, 143
(1)
, 399-408. https://doi.org/10.1021/jacs.0c11370
- Peiyang Gu, Feiyang Tan, Wuzi Zhao, Jingwen Dong, Shiyuan Zhou, Xiaoqiong Hao, Shengsheng Gu, Guangfeng Liu, Danfeng Wang. Facile post-quaternization of conjugated microporous polymer for markedly efficient photodegradation and artificial photosynthesis of H2O2. Separation and Purification Technology 2025, 360 , 130928. https://doi.org/10.1016/j.seppur.2024.130928
- Hengtao Lei, Changyan Zhu, Lin Lin, Xueyan Han, Yongyue Ding, Jian Song, Yuyang Tian, Guangshan Zhu. Rational modulation of covalent organic frameworks heterogeneous catalyst: Structural cationization effect on accelerating photocatalytic oxidation process. Applied Catalysis B: Environment and Energy 2025, 361 , 124654. https://doi.org/10.1016/j.apcatb.2024.124654
- Xuan-Zong Yang, Zhao-Gao Zhang, Cheng-Long Xin, Hui Liu, Shengsheng Yu, Ling-Bao Xing. Artificial light-harvesting system with sequential energy transfer in photocatalytic C P coupling based on supramolecular organic framework of triphenylamine. Journal of Colloid and Interface Science 2025, 680 , 587-595. https://doi.org/10.1016/j.jcis.2024.11.028
- Zhi-Peng Tao, Chen-Ning Li, Lin Liu, Kechao Wang, Yun Jeong Hwang, Daqiang Yuan, Zheng-Bo Han. Facet-dependent reactive oxygen species generation regulates photocatalytic oxidation of benzylamines. Journal of Catalysis 2025, 442 , 115931. https://doi.org/10.1016/j.jcat.2024.115931
- Yi Ting Wang, Gui Hua Chen, Qi Wang, Hao Zang, Qiang Wang, Yuan Fang Li, Hong Yan Zou, Lei Zhan, Jian Wei Xie, Cheng Zhi Huang, Shu Jun Zhen. Ultra‐Fast Degradation of Mustard Gas Simulant by Titanium Dioxide‐Phosphomolybdic Acid Sub‐1 nm Nanobelts. Small 2025, 21
(1)
https://doi.org/10.1002/smll.202407980
- Yana Chen, Zewen Shen, Yezi Hu, Haotian Zhang, Lisha Yin, Guixia Zhao, Guangtong Hai, Xiubing Huang. Photocatalytic detoxification of a sulfur mustard simulant using donor-enhanced porphyrin-based covalent-organic frameworks. Nanoscale 2025, 25 https://doi.org/10.1039/D4NR05302H
- Jan Hynek, Daniel T. Payne, Lok Kumar Shrestha, Mandeep K. Chahal, Renzhi Ma, Jiang Dong, Katsuhiko Ariga, Yusuke Yamauchi, Jonathan P. Hill. Mild selective photochemical oxidation of an organic sulfide using OxP-polyimide porous polymers as singlet oxygen generators. Science and Technology of Advanced Materials 2024, 25
(1)
https://doi.org/10.1080/14686996.2024.2322458
- Miroslav Labaška, Miroslav Gál, Tomáš Mackuľak, Jozef Švorec, Jozef Kučera, Jozef Helenin, Veronika Svitková, Jozef Ryba. Neutralizing the threat: A comprehensive review of chemical warfare agent decontamination strategies. Journal of Environmental Chemical Engineering 2024, 12
(6)
, 114243. https://doi.org/10.1016/j.jece.2024.114243
- Guiping Yang, Qing Xu, Gaofeng Zeng. Developments of photo‐/electro‐catalysis based on covalent organic frameworks: A review. Electron 2024, 2
(4)
https://doi.org/10.1002/elt2.39
- Ramin Ghiai, Sedigheh Alavinia, Ramin Ghorbani‐Vaghei, Ardeshir Khazaei. Cu (ii) Immobilized on Mesoporous Poly (Guanidine–Triazine–Sulfonamide) (PGTSA/Cu): A New Catalyst for the Synthesis of Tetrazolo[1,5‐a]pyrimidines. Applied Organometallic Chemistry 2024, 40 https://doi.org/10.1002/aoc.7831
- Jian Song, Hengtao Lei, Yuhui Zhai, Zilong Dou, Yongyue Ding, Xueyan Han, Fengchao Cui, Yuyang Tian, Guangshan Zhu. Exclusive generation of a superoxide radical by a porous aromatic framework for fast photocatalytic decontamination of mustard gas simulant in room air. Chemical Science 2024, 15
(38)
, 15717-15724. https://doi.org/10.1039/D4SC04551C
- Jing Dong, Di Zhang, Peixuan Zhang, Chengpeng Liu, Jie Li, Jing Bai, Yingnan Chi, Changwen Hu. Polyoxometalates for the decontamination of chemical warfare agents: From structure and composition regulation to performance enhancement. Coordination Chemistry Reviews 2024, 517 , 215998. https://doi.org/10.1016/j.ccr.2024.215998
- Guobang Li, Tianyu Qiu, Qi Wu, Zhao Zhao, Lili Wang, Yangguang Li, Yun Geng, Huaqiao Tan. Pyrene‐Alkyne‐Based Conjugated Porous Polymers with Skeleton Distortion‐Mediated ⋅O
2
−
and
1
O
2
Generation for High‐Selectivity Organic Photosynthesis. Angewandte Chemie 2024, 136
(33)
https://doi.org/10.1002/ange.202405396
- Guobang Li, Tianyu Qiu, Qi Wu, Zhao Zhao, Lili Wang, Yangguang Li, Yun Geng, Huaqiao Tan. Pyrene‐Alkyne‐Based Conjugated Porous Polymers with Skeleton Distortion‐Mediated ⋅O
2
−
and
1
O
2
Generation for High‐Selectivity Organic Photosynthesis. Angewandte Chemie International Edition 2024, 63
(33)
https://doi.org/10.1002/anie.202405396
- Xupeng Zhang, Yuying Liu, Pengfei Shen, Liqiu Ren, Donglai Han, Ming Feng, Heng‐Guo Wang. Engineering an Artificial Coating Layer of Metal Porphyrin‐Based Porous Organic Polymers Toward High Stable Aqueous Zinc‐Ion Batteries. Advanced Functional Materials 2024, 34
(33)
https://doi.org/10.1002/adfm.202400032
- Qingshan Zhu, Haiyan An, Yuting Wei, Hao Sun, Jie Fu, Tie-Qi Xu. Confining polyoxometalates in porphyrin-based porous cationic polymer toward boosting visible-light-driven synthesis of sulfoxides and detoxification of mustard gas simulants. Journal of Catalysis 2024, 436 , 115627. https://doi.org/10.1016/j.jcat.2024.115627
- Zhiye Zheng, Qiuyuan Lin, Ying Gao, Xiaofan Ji, Jonathan L. Sessler, Hongyu Wang. Recent advances in iodine adsorption from water. Coordination Chemistry Reviews 2024, 511 , 215860. https://doi.org/10.1016/j.ccr.2024.215860
- Jinfeng Zhou, Xiangqian Li, Chunjie Chu, Jinping Cao. One-pot synthesis of a porphyrin functionalized metal-organic frameworks as a recyclable visible-light-driven photosensitizer for efficient detoxification of a sulfur mustard simulant in air. Microporous and Mesoporous Materials 2024, 375 , 113163. https://doi.org/10.1016/j.micromeso.2024.113163
- Taotao Huang, Qian Chen, Hui Jiang, Kui Zhang. Research Progress in the Degradation of Chemical Warfare Agent Simulants Using Metal–Organic Frameworks. Nanomaterials 2024, 14
(13)
, 1108. https://doi.org/10.3390/nano14131108
- Sushil Sharma, Sakshi Chawla, Vidushi Gupta, Arijit K. De, Sanchita Sengupta. BODIPY-based regioisomers and a donor–acceptor rotor as organic photosensitizers for maximizing singlet oxygen quantum yields and for the photooxidation of thioanisole. Materials Advances 2024, 5
(8)
, 3334-3344. https://doi.org/10.1039/D4MA00117F
- Keke Zhang, Fengwei Huang, Xiaoyun Dong, Kanghui Xiong, Xianjun Lang. Benzotrithiophene-based sp2 carbon-conjugated microporous polymers for green light-triggered oxidation of amines to imines. Materials Today Chemistry 2024, 35 , 101879. https://doi.org/10.1016/j.mtchem.2023.101879
- Lingling Zhang, Liwei Wu, Junhui Bao, Longhui Li, Zejun Liu, Feng Bai, Jie Ju, Xi Yao. Spherical cationic polymer networks with porphyrin photosensitizer for sustainable and efficient photocatalysis. Nano Research 2023, 122 https://doi.org/10.1007/s12274-023-6395-2
- Shilpi Jaiswal, Arkaprabha Giri, Dipendranath Mandal, Madhurima Sarkar, Abhijit Patra. UV‐to‐NIR Harvesting Conjugated Porous Polymer Nanocomposite: Upconversion and Plasmon Expedited Thioether Photooxidation. Angewandte Chemie 2023, 135
(49)
https://doi.org/10.1002/ange.202312910
- Shilpi Jaiswal, Arkaprabha Giri, Dipendranath Mandal, Madhurima Sarkar, Abhijit Patra. UV‐to‐NIR Harvesting Conjugated Porous Polymer Nanocomposite: Upconversion and Plasmon Expedited Thioether Photooxidation. Angewandte Chemie International Edition 2023, 62
(49)
https://doi.org/10.1002/anie.202312910
- Jing Hao, Feifan Lang, Liqin Hao, Yi Yang, Lulu Zhang, Hao Zhang, Quan-Wen Li, Jiandong Pang, Xian-He Bu. Enhancing the singlet oxygen capture and release rate of metal−organic frameworks through interpenetration tuning. Chinese Chemical Letters 2023, 34
(12)
, 108310. https://doi.org/10.1016/j.cclet.2023.108310
- Yajun Fang, Yuntian Yang, Rui Xu, Mingyun Liang, Qi Mou, Shuixia Chen, Jehan Kim, Long Yi Jin, Myongsoo Lee, Zhegang Huang. Hierarchical porous photosensitizers with efficient photooxidation. Nature Communications 2023, 14
(1)
https://doi.org/10.1038/s41467-023-38283-1
- Gioele Colombo, Anita Cinco, Stefano Brenna, Julien Furrer, Bruno Therrien, G. Attilio Ardizzoia. Luminescent blue emissive bis(alkynyl) borane compounds with a N,O-coordinated ligand. Dyes and Pigments 2023, 220 , 111722. https://doi.org/10.1016/j.dyepig.2023.111722
- Seyoung Koo, Dong Won Kang. Emerging porous solids and sonochemistry. CrystEngComm 2023, 25
(43)
, 5994-6005. https://doi.org/10.1039/D3CE00826F
- Kun Wu, Xin-Yi Liu, Mo Xie, Pei-Wen Cheng, Ji Zheng, Weigang Lu, Dan Li. Rational design of D− π − A− π − D porous organic polymer with polarized π for photocatalytic aerobic oxidation. Applied Catalysis B: Environmental 2023, 334 , 122847. https://doi.org/10.1016/j.apcatb.2023.122847
- Victor Quezada‐Novoa, Hatem M. Titi, Francisco Yarur Villanueva, Mark W. B. Wilson, Ashlee J. Howarth. The Effect of Linker‐to‐Metal Energy Transfer on the Photooxidation Performance of an Isostructural Series of Pyrene‐Based Rare‐Earth Metal–Organic Frameworks. Small 2023, 19
(36)
https://doi.org/10.1002/smll.202302173
- Bibi Amna, Ayşe Ateş, Turan Ozturk. Pd/Cu-catalyzed sonogashira cross-coupling polycondensation: A promising approach for synthesizing conjugated polymers with useful applications. European Polymer Journal 2023, 196 , 112275. https://doi.org/10.1016/j.eurpolymj.2023.112275
- Ying Jiang, Qiao Ding, Ruo Yuan, Guangpeng Liu, Yali Yuan. Photoactive conjugated microporous polymer@C60 with quencher on tailed Y-triangular DNA structure for high-performance signal-off photoelectrochemical biosensing. Journal of Hazardous Materials 2023, 457 , 131724. https://doi.org/10.1016/j.jhazmat.2023.131724
- Ze-Jiu Diao, Guan-Zhou Wu, Tian-Jing Zhang, Hang-Ou Qi, Jing-Jing Li, Ming Lu, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun. Fabrication of dianthracene-based hyper-cross-linked polymers for selective photocatalytic oxidation of organic sulfides. Journal of Materials Chemistry A 2023, 11
(30)
, 16293-16302. https://doi.org/10.1039/D3TA02467A
- Ratul Paul, Priyanka Kalita, Duy Quang Dao, Indranil Mondal, Bishal Boro, John Mondal. Linker Independent Regioselective Protonation Triggered Detoxification of Sulfur Mustards with Smart Porous Organic Photopolymer. Small 2023, 19
(34)
https://doi.org/10.1002/smll.202302045
- Priyanka Kalita, Ratul Paul, Ankita Boruah, Duy Quang Dao, Asim Bhaumik, John Mondal. A critical review on emerging photoactive porous materials for sulfide oxidation and sulfur mustard decontamination. Green Chemistry 2023, 25
(15)
, 5789-5812. https://doi.org/10.1039/D3GC01149F
- Guang-Chen Guo, Lihua Ma, Xiao-Di Li, Song Guo, Tong-Bu Lu, Zhi-Ming Zhang. Engineering earth-abundant copper(
i
) sensitizing centers in metal–organic frameworks for efficient photosynthesis. Journal of Materials Chemistry A 2023, 11
(26)
, 14052-14057. https://doi.org/10.1039/D3TA02142D
- Ze‐Jiu Diao, Si‐Yi Liu, Hui Wen, Guoliang Liu, Tao Yang, Jing‐Jing Li, Xiao‐Qin Liu, Lin‐Bing Sun. Detachable Porous Organic Polymers Responsive to Light and Heat. Angewandte Chemie 2023, 135
(21)
https://doi.org/10.1002/ange.202301739
- Ze‐Jiu Diao, Si‐Yi Liu, Hui Wen, Guoliang Liu, Tao Yang, Jing‐Jing Li, Xiao‐Qin Liu, Lin‐Bing Sun. Detachable Porous Organic Polymers Responsive to Light and Heat. Angewandte Chemie International Edition 2023, 62
(21)
https://doi.org/10.1002/anie.202301739
- Lorena Mendive‐Tapia, Laia Miret‐Casals, Nicole D. Barth, Jinling Wang, Anne de Bray, Massimiliano Beltramo, Vincent Robert, Christophe Ampe, David J. Hodson, Annemieke Madder, Marc Vendrell. Acid‐Resistant BODIPY Amino Acids for Peptide‐Based Fluorescence Imaging of GPR54 Receptors in Pancreatic Islets. Angewandte Chemie 2023, 135
(20)
https://doi.org/10.1002/ange.202302688
- Lorena Mendive‐Tapia, Laia Miret‐Casals, Nicole D. Barth, Jinling Wang, Anne de Bray, Massimiliano Beltramo, Vincent Robert, Christophe Ampe, David J. Hodson, Annemieke Madder, Marc Vendrell. Acid‐Resistant BODIPY Amino Acids for Peptide‐Based Fluorescence Imaging of GPR54 Receptors in Pancreatic Islets. Angewandte Chemie International Edition 2023, 62
(20)
https://doi.org/10.1002/anie.202302688
- Priyanka Kalita, Ratul Paul, Chih-Wen Pao, Rupak Chatterjee, Asim Bhaumik, John Mondal. Putting forward a Ni-metallosalphen-based porous organic polymer for detoxification of sulfur mustard gas simulant. Chemical Communications 2023, 59
(34)
, 5067-5070. https://doi.org/10.1039/D3CC00349C
- Nan Li, Lanlan Huo, Wenjing Shen, Chenghong Qiang, Mianmian Wu, Guifang Sun, Qingfei Li, Minghao Shi, Jiangquan Ma. Porous organic polymers for superefficient removal of pollutants from water: Design, synthesis and adsorption performance. Journal of Cleaner Production 2023, 396 , 136558. https://doi.org/10.1016/j.jclepro.2023.136558
- Vida Izadkhah, Ramin Ghorbani-Vaghei, Sedigheh Alavinia, Simin Asadabadi, Nafiseh Emami, Saeed Jamehbozorgi. Fabrication of zirconium metal-organic-framework/poly triazine-phosphanimine nanocomposite for dye adsorption from contaminated water: Isotherms and kinetics models. Journal of Molecular Structure 2023, 1275 , 134691. https://doi.org/10.1016/j.molstruc.2022.134691
- Grace C. Thaggard, Gabrielle A. Leith, Daniil Sosnin, Corey R. Martin, Kyoung Chul Park, Margaret K. McBride, Jaewoong Lim, Brandon J. Yarbrough, Buddhima K. P. Maldeni Kankanamalage, Gina R. Wilson, Austin R. Hill, Mark D. Smith, Sophya Garashchuk, Andrew B. Greytak, Ivan Aprahamian, Natalia B. Shustova. Confinement‐Driven Photophysics in Hydrazone‐Based Hierarchical Materials. Angewandte Chemie 2023, 135
(2)
https://doi.org/10.1002/ange.202211776
- Grace C. Thaggard, Gabrielle A. Leith, Daniil Sosnin, Corey R. Martin, Kyoung Chul Park, Margaret K. McBride, Jaewoong Lim, Brandon J. Yarbrough, Buddhima K. P. Maldeni Kankanamalage, Gina R. Wilson, Austin R. Hill, Mark D. Smith, Sophya Garashchuk, Andrew B. Greytak, Ivan Aprahamian, Natalia B. Shustova. Confinement‐Driven Photophysics in Hydrazone‐Based Hierarchical Materials. Angewandte Chemie International Edition 2023, 62
(2)
https://doi.org/10.1002/anie.202211776
- Peipei Jia, Yixiong Hu, Zhiyong Zeng, Yute Wang, Bo Song, Yanrong Jiang, Haitao Sun, Ming Wang, Wenwei Qiu, Lin Xu. Construction of FRET-based metallacycles with efficient photosensitization efficiency and photocatalytic activity. Chinese Chemical Letters 2023, 34
(1)
, 107511. https://doi.org/10.1016/j.cclet.2022.05.025
- Kai Sheng, Xian-Qiang Huang, Ran Wang, Wei-Zhe Wang, Zhi-Yong Gao, Chen-Ho Tung, Di Sun. Decagram-scale synthesis of heterometallic Ag/Ti cluster as sustainable catalyst for selective oxidation of sulfides. Journal of Catalysis 2023, 417 , 185-193. https://doi.org/10.1016/j.jcat.2022.12.007
- Victoria G. Snider, Craig L. Hill. Functionalized reactive polymers for the removal of chemical warfare agents: A review. Journal of Hazardous Materials 2023, 442 , 130015. https://doi.org/10.1016/j.jhazmat.2022.130015
- Ramin Ghiai, Sedigheh Alavinia, Ramin Ghorbani-Vaghei, Alireza Gharakhani. Ni(
ii
) immobilized on poly(guanidine–triazine–sulfonamide) (PGTSA/Ni): a mesoporous nanocatalyst for synthesis of imines. RSC Advances 2022, 12
(53)
, 34425-34437. https://doi.org/10.1039/D2RA06196A
- Yixuan Wang, Xinyi Yang, Chuang Liu, Zhaodong Liu, Qianrong Fang, Fuquan Bai, Shiping Wang, Xuyuan Hou, Bingtao Feng, Banglin Chen, Bo Zou. Maximized Green Photoluminescence in Tb‐Based Metal–Organic Framework via Pressure‐Treated Engineering. Angewandte Chemie 2022, 134
(48)
https://doi.org/10.1002/ange.202210836
- Yixuan Wang, Xinyi Yang, Chuang Liu, Zhaodong Liu, Qianrong Fang, Fuquan Bai, Shiping Wang, Xuyuan Hou, Bingtao Feng, Banglin Chen, Bo Zou. Maximized Green Photoluminescence in Tb‐Based Metal–Organic Framework via Pressure‐Treated Engineering. Angewandte Chemie International Edition 2022, 61
(48)
https://doi.org/10.1002/anie.202210836
- Shan-Shan Zhu, Lin Zuo, Yan Liu, Bing Yu. 1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN)-based porous organic polymers for visible-light-driven organic transformations in water under aerobic oxidation. Green Chemistry 2022, 24
(22)
, 8725-8732. https://doi.org/10.1039/D2GC02950B
- Priksha Rana, Nishi Singh, Poulomi Majumdar, Surya Prakash Singh. Evolution of BODIPY/aza-BODIPY dyes for organic photoredox/energy transfer catalysis. Coordination Chemistry Reviews 2022, 470 , 214698. https://doi.org/10.1016/j.ccr.2022.214698
- Pavel Melnikov, Alexander Bobrov, Yuriy Marfin. On the Use of Polymer-Based Composites for the Creation of Optical Sensors: A Review. Polymers 2022, 14
(20)
, 4448. https://doi.org/10.3390/polym14204448
- Arkaprabha Giri, Abhijit Patra. Porous Organic Polymers: Promising Testbed for Heterogeneous Reactive Oxygen Species Mediated Photocatalysis and Nonredox CO
2
Fixation. The Chemical Record 2022, 22
(9)
https://doi.org/10.1002/tcr.202200071
- Arkaprabha Giri, Yashna Khakre, G. Shreeraj, Tapas Kumar Dutta, Subhankar Kundu, Abhijit Patra. The order–disorder conundrum: a trade-off between crystalline and amorphous porous organic polymers for task-specific applications. Journal of Materials Chemistry A 2022, 10
(33)
, 17077-17121. https://doi.org/10.1039/D2TA01546C
- Yanhong Chen, Haiyan An, Shenzhen Chang, Yanqin Li, Qingshan Zhu, Huiyun Luo, Yaohui Huang. A POM-based porous supramolecular framework for efficient sulfide–sulfoxide transformations with a low molar O/S ratio. Inorganic Chemistry Frontiers 2022, 9
(13)
, 3282-3294. https://doi.org/10.1039/D2QI00525E
- Shuai Li, Lu Dai, Li Li, Anwang Dong, Jiani Li, Xiangjian Meng, Bo Wang, Pengfei Li. Post-oxidation of a fully conjugated benzotrithiophene-based COF for photocatalytic detoxification of a sulfur mustard simulant. Journal of Materials Chemistry A 2022, 10
(25)
, 13325-13332. https://doi.org/10.1039/D2TA01864K
- J.-F. Zhou, J.-J. Ling, G. Li, S. Zhang, D. Zhu. The molecule-level photoreactor: accurate embedded iodine-substituted boron dipyrromethene dye within zeolitic imidazolate framework-8 for highly efficient oxidization of sulfides under visible light. Materials Today Chemistry 2022, 24 , 100774. https://doi.org/10.1016/j.mtchem.2022.100774
- Hyojin Kim, Jinwoo Shin, Dong Won Kang, Youngseo Kim, Ji Hyeon Kim, Minjung Kang, Jong Hyeak Choe, Sungnam Park, Jong Seung Kim, Chang Seop Hong. Photocatalytic detoxification of a sulfur mustard simulant under realistic conditions by imidazoline-based porous organic polymer composites. Cell Reports Physical Science 2022, 3
(5)
, 100888. https://doi.org/10.1016/j.xcrp.2022.100888
- Flavio L. Portwich, Yves Carstensen, Anindita Dasgupta, Stephan Kupfer, Ralf Wyrwa, Helmar Görls, Christian Eggeling, Benjamin Dietzek, Stefanie Gräfe, Maria Wächtler, Robert Kretschmer. A Highly Fluorescent Dinuclear Aluminium Complex with Near‐Unity Quantum Yield**. Angewandte Chemie International Edition 2022, 61
(17)
https://doi.org/10.1002/anie.202117499
- Flavio L. Portwich, Yves Carstensen, Anindita Dasgupta, Stephan Kupfer, Ralf Wyrwa, Helmar Görls, Christian Eggeling, Benjamin Dietzek, Stefanie Gräfe, Maria Wächtler, Robert Kretschmer. Ein stark fluoreszierender zweikerniger Aluminiumkomplex mit nahezu 100 %iger Quantenausbeute**. Angewandte Chemie 2022, 134
(17)
https://doi.org/10.1002/ange.202117499
- Hye Min Choi, Ye Ji Kim, E Tae Choi, Tai Yong Lee, Suk Joong Lee. Use of porphyrin-containing polymers of intrinsic microporosity as selective photocatalysts for oxidative detoxification of chemical warfare agent simulant. Journal of Porphyrins and Phthalocyanines 2022, 26
(04)
, 340-347. https://doi.org/10.1142/S1088424622500213
- Emmanuel Oheix, Edmond Gravel, Eric Doris. Vapor phase catalytic photooxidation of sulfides to sulfoxides: application to the neutralization of sulfur mustard simulants. Catalysis Science & Technology 2022, 12
(6)
, 1751-1755. https://doi.org/10.1039/D1CY02349G
- Yao Wang, Kaikai Ma, Jiaquan Bai, Tao Xu, Wendong Han, Chen Wang, Zhenxia Chen, Kent O. Kirlikovali, Peng Li, Jisheng Xiao, Omar K. Farha. Chemically Engineered Porous Molecular Coatings as Reactive Oxygen Species Generators and Reservoirs for Long‐Lasting Self‐Cleaning Textiles. Angewandte Chemie 2022, 134
(8)
https://doi.org/10.1002/ange.202115956
- Yao Wang, Kaikai Ma, Jiaquan Bai, Tao Xu, Wendong Han, Chen Wang, Zhenxia Chen, Kent O. Kirlikovali, Peng Li, Jisheng Xiao, Omar K. Farha. Chemically Engineered Porous Molecular Coatings as Reactive Oxygen Species Generators and Reservoirs for Long‐Lasting Self‐Cleaning Textiles. Angewandte Chemie International Edition 2022, 61
(8)
https://doi.org/10.1002/anie.202115956
- Xing-Hao Du, Zhiyong Jiang, Zhipeng Liu, Chao Xu. BODIPY-linked conjugated porous polymers for dye wastewater treatment. Microporous and Mesoporous Materials 2022, 332 , 111711. https://doi.org/10.1016/j.micromeso.2022.111711
- Gabrielle A. Leith, Corey R. Martin, Abhijai Mathur, Preecha Kittikhunnatham, Kyoung Chul Park, Natalia B. Shustova. Dynamically Controlled Electronic Behavior of Stimuli‐Responsive Materials: Exploring Dimensionality and Connectivity. Advanced Energy Materials 2022, 12
(4)
https://doi.org/10.1002/aenm.202100441
- Holger Helten. Organoboron and Related Group 13 Polymers. 2022, 71-134. https://doi.org/10.1016/B978-0-12-820206-7.00155-4
- Wenhao Sun, Yonggang Xiang, Zhihui Jiang, Shengyao Wang, Nan Yang, Shangbin Jin, Linhao Sun, Huailong Teng, Hao Chen. Designed polymeric conjugation motivates tunable activation of molecular oxygen in heterogeneous organic photosynthesis. Science Bulletin 2022, 67
(1)
, 61-70. https://doi.org/10.1016/j.scib.2021.07.016
- Shanshan Zhu, Lin Zuo, Yan Liu, Bing Yu. 4czipn-Based Porous Organic Polymers for Visible-Light-Driven Organic Transformations in Water Under Aerobic Oxidation. SSRN Electronic Journal 2022, 51 https://doi.org/10.2139/ssrn.4157070
- Mariam Barawi, Laura Collado, Miguel Gomez‐Mendoza, Freddy E. Oropeza, Marta Liras, Victor A. de la Peña O'Shea. Conjugated Porous Polymers: Ground‐Breaking Materials for Solar Energy Conversion. Advanced Energy Materials 2021, 11
(43)
https://doi.org/10.1002/aenm.202101530
- Ji Hyeon Kim, Hongryeol Yun, Dong Won Kang, Jinwoo Shin, Minjung Kang, Nem Singh, Ji-Eun Jeong, Chang Seop Hong, Jong Seung Kim. Isomeric sp2-C-conjugated porous organic polymer-mediated photo- and sono-catalytic detoxification of sulfur mustard simulant under ambient conditions. Matter 2021, 4
(11)
, 3774-3785. https://doi.org/10.1016/j.matt.2021.10.005
- Yuan‐Zhao Peng, Guang‐Chen Guo, Song Guo, Li‐Hui Kong, Tong‐Bu Lu, Zhi‐Ming Zhang. Charge Transfer from Donor to Acceptor in Conjugated Microporous Polymer for Enhanced Photosensitization. Angewandte Chemie 2021, 133
(40)
, 22233-22240. https://doi.org/10.1002/ange.202109968
- Yuan‐Zhao Peng, Guang‐Chen Guo, Song Guo, Li‐Hui Kong, Tong‐Bu Lu, Zhi‐Ming Zhang. Charge Transfer from Donor to Acceptor in Conjugated Microporous Polymer for Enhanced Photosensitization. Angewandte Chemie International Edition 2021, 60
(40)
, 22062-22069. https://doi.org/10.1002/anie.202109968
- Mingjie Liu, Junnan Liu, Kai Zhou, Jingwen Chen, Qi Sun, Zongbi Bao, Qiwei Yang, Yiwen Yang, Qilong Ren, Zhiguo Zhang. Turn‐On Photocatalysis: Creating Lone‐Pair Donor–Acceptor Bonds in Organic Photosensitizer to Enhance Intersystem Crossing. Advanced Science 2021, 8
(18)
https://doi.org/10.1002/advs.202100631
- Jeehye Byun, Yeongran Hong, Kai A.I. Zhang. Beyond the batch: Process and material design of polymeric photocatalysts for flow photochemistry. Chem Catalysis 2021, 1
(4)
, 771-781. https://doi.org/10.1016/j.checat.2021.08.003
Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.
Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.