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Exploiting the Specific Isotope-Selective Adsorption of Metal–Organic Framework for Hydrogen Isotope Separation

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    Exploiting the Specific Isotope-Selective Adsorption of Metal–Organic Framework for Hydrogen Isotope Separation
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    • Raeesh Muhammad
      Raeesh Muhammad
      Department of Energy Engineering, Gyeongsang National University, Jinju 52725, Republic of Korea
      More by Raeesh Muhammad
      Orcidhttp://orcid.org/0000-0003-3448-5846
    • Seohyeon Jee
      Seohyeon Jee
      Department of Chemical and Biological Engineering, Sookmyung Women’s University, 100 Cheongpa-ro 47 gil, Yongsan-gu, Seoul 04310, Republic of Korea
      More by Seohyeon Jee
    • Minji Jung
      Minji Jung
      Department of Energy Engineering, Gyeongsang National University, Jinju 52725, Republic of Korea
      More by Minji Jung
    • Jaewoo Park
      Jaewoo Park
      Department of Energy Engineering, Gyeongsang National University, Jinju 52725, Republic of Korea
      More by Jaewoo Park
    • Sung Gu Kang*
      Sung Gu Kang
      School of Chemical Engineering, University of Ulsan, Ulsan 44610, Republic of Korea
      *[email protected] (DFT calculations)
      More by Sung Gu Kang
      Orcidhttp://orcid.org/0000-0003-1112-7077
    • Kyung Min Choi*
      Kyung Min Choi
      Department of Chemical and Biological Engineering, Sookmyung Women’s University, 100 Cheongpa-ro 47 gil, Yongsan-gu, Seoul 04310, Republic of Korea
      *[email protected] (material synthesis)
      More by Kyung Min Choi
      Orcidhttp://orcid.org/0000-0001-7181-902X
    • Hyunchul Oh*
      Hyunchul Oh
      Department of Energy Engineering, Gyeongsang National University, Jinju 52725, Republic of Korea
      Future Convergence Technology Research Institute, Jinju 52725, Republic of Korea
      *[email protected] (characterization)
      More by Hyunchul Oh
      Orcidhttp://orcid.org/0000-0001-6258-0002
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2021, 143, 22, 8232–8236
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    https://doi.org/10.1021/jacs.1c01694
    Published April 30, 2021
    Copyright © 2021 American Chemical Society
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    Abstract

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    Adsorptive separation using narrow-micropore adsorbents has demonstrated the potential to separate hydrogen isotopes. In this work, we employed an isotope-responsive separation using cobalt formate. A D2-responsive third sorption step was revealed, and consequently, a noticeable difference was observed in the uptakes of D2 and H2. This may have resulted from the additional space created for D2 due to its dense packing, as DFT calculations revealed that cobalt formate possesses 2.26 kJ/mol higher binding strength for D2 than for H2. The exploitation of this D2-responsive third sorption step renders a promising separation performance, with a D2/H2 selectivity of up to 44 at 25 K/1 bar. Lastly, cobalt formate was synthesized on a gram scale here, which makes it a prospect for commercialization.

    Copyright © 2021 American Chemical Society

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/jacs.1c01694.

    • Experimental details, structural characterization, thermal desorption spectra, and density functional theory calculations (PDF)

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    Cited By

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    This article is cited by 23 publications.

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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2021, 143, 22, 8232–8236
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jacs.1c01694
    Published April 30, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

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