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Interfacial Synthesis of Layer-Oriented 2D Conjugated Metal–Organic Framework Films toward Directional Charge Transport
- Zhiyong WangZhiyong WangCenter for Advancing Electronics Dresden (cfaed) and Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, GermanyMore by Zhiyong Wang
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- Lisa S. WalterLisa S. WalterI. Physical Institute, Faculty of Physics, Georg-August-University Göttingen, 37077 Göttingen, GermanyPhysics of Nanosystems, Department of Physics, Ludwig-Maximilians-University München, 80799 Munich, GermanyMore by Lisa S. Walter
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- Mao WangMao WangHelmholtz-Zentrum Dresden-Rossendorf, Institute of Ion Beam Physics and Materials Research, 01328 Dresden, GermanyMore by Mao Wang
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- Petko St. PetkovPetko St. PetkovFaculty of Chemistry and Pharmacy, University of Sofia, 1164 Sofia, BulgariaMore by Petko St. Petkov
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- Baokun LiangBaokun LiangCentral Facility for Electron Microscopy, Electron Microscopy of Materials Science Central, Facility for Electron Microscopy, Ulm University, 89081 Ulm, GermanyMore by Baokun Liang
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- Haoyuan QiHaoyuan QiCenter for Advancing Electronics Dresden (cfaed) and Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, GermanyCentral Facility for Electron Microscopy, Electron Microscopy of Materials Science Central, Facility for Electron Microscopy, Ulm University, 89081 Ulm, GermanyMore by Haoyuan Qi
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- Nguyen Ngan NguyenNguyen Ngan NguyenCenter for Advancing Electronics Dresden (cfaed) and Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, GermanyMore by Nguyen Ngan Nguyen
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- Mike HambschMike HambschCenter for Advancing Electronics Dresden (cfaed) and Faculty of Electrical and Computer Engineering, Technische Universität Dresden, 01062 Dresden, GermanyMore by Mike Hambsch
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- Haixia ZhongHaixia ZhongCenter for Advancing Electronics Dresden (cfaed) and Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, GermanyMore by Haixia Zhong
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- Mingchao WangMingchao WangCenter for Advancing Electronics Dresden (cfaed) and Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, GermanyMore by Mingchao Wang
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- SangWook ParkSangWook ParkCenter for Advancing Electronics Dresden (cfaed) and Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, GermanyMore by SangWook Park
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- Lukas RennLukas RennI. Physical Institute, Faculty of Physics, Georg-August-University Göttingen, 37077 Göttingen, GermanyPhysics of Nanosystems, Department of Physics, Ludwig-Maximilians-University München, 80799 Munich, GermanyMore by Lukas Renn
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- Kenji WatanabeKenji WatanabeNational Institute for Materials Science, 305-0047 Tsukua, JapanMore by Kenji Watanabe
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- Takashi TaniguchiTakashi TaniguchiNational Institute for Materials Science, 305-0047 Tsukua, JapanMore by Takashi Taniguchi
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- Stefan C. B. MannsfeldStefan C. B. MannsfeldCenter for Advancing Electronics Dresden (cfaed) and Faculty of Electrical and Computer Engineering, Technische Universität Dresden, 01062 Dresden, GermanyMore by Stefan C. B. Mannsfeld
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- Thomas HeineThomas HeineCenter for Advancing Electronics Dresden (cfaed) and Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, GermanyHelmholtz-Zentrum Dresden-Rossendorf, Institute of Resource Ecology, Leipzig Research Branch, 04316 Leipzig, GermanyDepartment of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 03722 KoreaMore by Thomas Heine
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- Ute KaiserUte KaiserCentral Facility for Electron Microscopy, Electron Microscopy of Materials Science Central, Facility for Electron Microscopy, Ulm University, 89081 Ulm, GermanyMore by Ute Kaiser
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- Shengqiang ZhouShengqiang ZhouHelmholtz-Zentrum Dresden-Rossendorf, Institute of Ion Beam Physics and Materials Research, 01328 Dresden, GermanyMore by Shengqiang Zhou
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- Ralf Thomas Weitz*Ralf Thomas Weitz*[email protected]I. Physical Institute, Faculty of Physics, Georg-August-University Göttingen, 37077 Göttingen, GermanyPhysics of Nanosystems, Department of Physics, Ludwig-Maximilians-University München, 80799 Munich, GermanyMore by Ralf Thomas Weitz
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- Xinliang Feng*Xinliang Feng*[email protected]Center for Advancing Electronics Dresden (cfaed) and Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, GermanyMax Planck Institute for Microstructure Physics, Weinberg 2, Halle (Saale), D-06120 GermanyMore by Xinliang Feng
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- Renhao Dong*Renhao Dong*[email protected]Center for Advancing Electronics Dresden (cfaed) and Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, GermanyMore by Renhao Dong
Abstract
The development of layer-oriented two-dimensional conjugated metal–organic frameworks (2D c-MOFs) enables access to direct charge transport, dial-in lateral/vertical electronic devices, and the unveiling of transport mechanisms but remains a significant synthetic challenge. Here we report the novel synthesis of metal-phthalocyanine-based p-type semiconducting 2D c-MOF films (Cu2[PcM–O8], M = Cu or Fe) with an unprecedented edge-on layer orientation at the air/water interface. The edge-on structure formation is guided by the preorganization of metal-phthalocyanine ligands, whose basal plane is perpendicular to the water surface due to their π–π interaction and hydrophobicity. Benefiting from the unique layer orientation, we are able to investigate the lateral and vertical conductivities by DC methods and thus demonstrate an anisotropic charge transport in the resulting Cu2[PcCu–O8] film. The directional conductivity studies combined with theoretical calculation identify that the intrinsic conductivity is dominated by charge transfer along the interlayer pathway. Moreover, a macroscopic (cm2 size) Hall-effect measurement reveals a Hall mobility of ∼4.4 cm2 V–1 s–1 for the obtained Cu2[PcCu–O8] film. The orientation control in semiconducting 2D c-MOFs will enable the development of various optoelectronic applications and the exploration of unique transport properties.
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