Reticular Nanoscience: Bottom-Up Assembly Nanotechnology
- Jacopo AndreoJacopo AndreoBasque Center for Materials, UPV/EHU Science Park, Leioa, 48940, SpainMore by Jacopo Andreo
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- Romy EttlingerRomy EttlingerSchool of Chemistry, University of St. Andrews, St. Andrews, KY16 9ST, United KingdomMore by Romy Ettlinger
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- Orysia ZarembaOrysia ZarembaBasque Center for Materials, UPV/EHU Science Park, Leioa, 48940, SpainMore by Orysia Zaremba
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- Quim PeñaQuim PeñaDepartment of Nanomedicine and Theranostics, Institute for Experimental Molecular Imaging, RWTH Aachen University, Aachen, 52074, GermanyMore by Quim Peña
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- Ulrich LächeltUlrich LächeltDivision of Pharmaceutical Technology and Biopharmaceutics, University of Vienna, Vienna, 1090, AustriaMore by Ulrich Lächelt
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- Roberto Fernández de LuisRoberto Fernández de LuisBasque Center for Materials, UPV/EHU Science Park, Leioa, 48940, SpainMore by Roberto Fernández de Luis
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- Ralph FreundRalph FreundInstitute of Physics, Chair of Solid State and Materials Chemistry, Augsburg University, Augsburg, 86150, GermanyMore by Ralph Freund
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- Stefano CanossaStefano CanossaDepartment of Nanochemistry, Max Planck Institute for Solid State Research, Stuttgart, 70569, GermanyMore by Stefano Canossa
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- Evelyn PloetzEvelyn PloetzDepartment of Chemisrty and Center for NanoScience (CeNS), Ludwig-Maximilians-Universität München (LMU), Munich, 81377, GermanyMore by Evelyn Ploetz
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- Wei ZhuWei ZhuMOE International Joint Research Laboratory on Synthetic Biology and Medicines, School of Biology and Biological Engineering, South China University of Technology, Guangzhou, 510006, P. R. ChinaMore by Wei Zhu
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- Christian S. DiercksChristian S. DiercksThe Scripps Research Institute, SR202, 10550 North Torrey Pines Road, La Jolla, California 92037, United StatesMore by Christian S. Diercks
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- Harald GrögerHarald GrögerChair of Industrial Organic Chemistry and Biotechnology, Faculty of Chemistry, Bielefeld University, Bielefeld, 33615, GermanyMore by Harald Gröger
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- Stefan Wuttke*Stefan Wuttke*E-mail: [email protected]Basque Center for Materials, UPV/EHU Science Park, Leioa, 48940, SpainIkerbasque, Basque Foundation for Science, Bilbao, 48009, SpainMore by Stefan Wuttke
Abstract
The chemistry of metal–organic and covalent organic frameworks (MOFs and COFs) is perhaps the most diverse and inclusive among the chemical sciences, and yet it can be radically expanded by blending it with nanotechnology. The result is reticular nanoscience, an area of reticular chemistry that has an immense potential in virtually any technological field. In this perspective, we explore the extension of such an interdisciplinary reach by surveying the explored and unexplored possibilities that framework nanoparticles can offer. We localize these unique nanosized reticular materials at the juncture between the molecular and the macroscopic worlds, and describe the resulting synthetic and analytical chemistry, which is fundamentally different from conventional frameworks. Such differences are mirrored in the properties that reticular nanoparticles exhibit, which we described while referring to the present state-of-the-art and future promising applications in medicine, catalysis, energy-related applications, and sensors. Finally, the bottom-up approach of reticular nanoscience, inspired by nature, is brought to its full extension by introducing the concept of augmented reticular chemistry. Its approach departs from a single-particle scale to reach higher mesoscopic and even macroscopic dimensions, where framework nanoparticles become building units themselves and the resulting supermaterials approach new levels of sophistication of structures and properties.
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