Realizing High Capacity and Zero Strain in Layered Oxide Cathodes via Lithium Dual-Site Substitution for Sodium-Ion BatteriesClick to copy article linkArticle link copied!
- Zhonghan WuZhonghan WuFrontiers Science Center for New Organic Matter, Renewable Energy Conversion and Storage Center (RECAST), Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, P. R. ChinaMore by Zhonghan Wu
- Youxuan NiYouxuan NiFrontiers Science Center for New Organic Matter, Renewable Energy Conversion and Storage Center (RECAST), Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, P. R. ChinaMore by Youxuan Ni
- Sha TanSha TanChemistry Division, Brookhaven National Laboratory Upton, New York 11973, United StatesMore by Sha Tan
- Enyuan HuEnyuan HuChemistry Division, Brookhaven National Laboratory Upton, New York 11973, United StatesMore by Enyuan Hu
- Lunhua HeLunhua HeBeijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, P. R. ChinaSongshan Lake Materials Laboratory, Dongguan 523808, P. R. ChinaSpallation Neutron Source Science Center, Dongguan 523803, P. R. ChinaMore by Lunhua He
- Jiuding LiuJiuding LiuFrontiers Science Center for New Organic Matter, Renewable Energy Conversion and Storage Center (RECAST), Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, P. R. ChinaMore by Jiuding Liu
- Machuan HouMachuan HouFrontiers Science Center for New Organic Matter, Renewable Energy Conversion and Storage Center (RECAST), Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, P. R. ChinaMore by Machuan Hou
- Peixin JiaoPeixin JiaoFrontiers Science Center for New Organic Matter, Renewable Energy Conversion and Storage Center (RECAST), Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, P. R. ChinaMore by Peixin Jiao
- Kai Zhang*Kai Zhang*Email: [email protected]Frontiers Science Center for New Organic Matter, Renewable Energy Conversion and Storage Center (RECAST), Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, P. R. ChinaHaihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. ChinaMore by Kai Zhang
- Fangyi Cheng*Fangyi Cheng*Email: [email protected]Frontiers Science Center for New Organic Matter, Renewable Energy Conversion and Storage Center (RECAST), Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, P. R. ChinaHaihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. ChinaMore by Fangyi Cheng
- Jun ChenJun ChenFrontiers Science Center for New Organic Matter, Renewable Energy Conversion and Storage Center (RECAST), Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, P. R. ChinaHaihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, P. R. ChinaMore by Jun Chen
Abstract
Sodium-ion batteries have garnered unprecedented attention as an electrochemical energy storage technology, but it remains challenging to design high-energy-density cathode materials with low structural strain during the dynamic (de)sodiation processes. Herein, we report a P2-layered lithium dual-site-substituted Na0.7Li0.03[Mg0.15Li0.07Mn0.75]O2 (NMLMO) cathode material, in which Li ions occupy both transition-metal (TM) and alkali-metal (AM) sites. The combination of theoretical calculations and experimental characterizations reveals that LiTM creates Na–O–Li electronic configurations to boost the capacity derived from the oxygen anionic redox, while LiAM serves as LiO6 prismatic pillars to stabilize the layered structure through suppressing the detrimental phase transitions. As a result, NMLMO delivers a high specific capacity of 266 mAh g–1 and simultaneously exhibits the nearly zero-strain characteristic within a wide voltage range of 1.5–4.6 V. Our findings highlight the effective way of dual-site substitution to break the capacity–stability trade-off in cathode materials for advanced rechargeable batteries.
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