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Hydroxyl-Bonded Ru on Metallic TiN Surface Catalyzing CO2 Reduction with H2O by Infrared Light

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    Article

    Hydroxyl-Bonded Ru on Metallic TiN Surface Catalyzing CO2 Reduction with H2O by Infrared Light
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    • Bo Su
      Bo Su
      State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China
      More by Bo Su
    • Yuehua Kong
      Yuehua Kong
      State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China
      More by Yuehua Kong
    • Sibo Wang*
      Sibo Wang
      State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China
      *Email: [email protected]
      More by Sibo Wang
      Orcidhttps://orcid.org/0000-0003-2656-9169
    • Shouwei Zuo
      Shouwei Zuo
      KAUST Catalysis Center, Physical Sciences and Engineering Division, King Abdullah University of Science and Technology, Thuwal 23955, Saudi Arabia
      More by Shouwei Zuo
    • Wei Lin
      Wei Lin
      State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China
      More by Wei Lin
      Orcidhttps://orcid.org/0000-0002-5046-4765
    • Yuanxing Fang
      Yuanxing Fang
      State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China
      More by Yuanxing Fang
      Orcidhttps://orcid.org/0000-0001-7603-5531
    • Yidong Hou
      Yidong Hou
      State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China
      More by Yidong Hou
      Orcidhttps://orcid.org/0000-0002-6983-3700
    • Guigang Zhang
      Guigang Zhang
      State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China
      More by Guigang Zhang
      Orcidhttps://orcid.org/0000-0002-9913-488X
    • Huabin Zhang
      Huabin Zhang
      KAUST Catalysis Center, Physical Sciences and Engineering Division, King Abdullah University of Science and Technology, Thuwal 23955, Saudi Arabia
      More by Huabin Zhang
      Orcidhttps://orcid.org/0000-0003-1601-2471
    • Xinchen Wang*
      Xinchen Wang
      State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, P. R. China
      *Email: [email protected]
      More by Xinchen Wang
      Orcidhttps://orcid.org/0000-0002-2490-3568
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2023, 145, 50, 27415–27423
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    https://doi.org/10.1021/jacs.3c08311
    Published December 11, 2023
    Copyright © 2023 American Chemical Society
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    Abstract

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    Synchronized conversion of CO2 and H2O into hydrocarbons and oxygen via infrared-ignited photocatalysis remains a challenge. Herein, the hydroxyl-coordinated single-site Ru is anchored precisely on the metallic TiN surface by a NaBH4/NaOH reforming method to construct an infrared-responsive HO-Ru/TiN photocatalyst. Aberration-corrected high-angle annular dark-field scanning transmission electron microscopy (ac-HAADF-STEM) and X-ray absorption spectroscopy (XAS) confirm the atomic distribution of the Ru species. XAS and density functional theory (DFT) calculations unveil the formation of surface HO-RuN5–Ti Lewis pair sites, which achieves efficient CO2 polarization/activation via dual coordination with the C and O atoms of CO2 on HO-Ru/TiN. Also, implanting the Ru species on the TiN surface powerfully boosts the separation and transfer of photoinduced charges. Under infrared irradiation, the HO-Ru/TiN catalyst shows a superior CO2-to-CO transformation activity coupled with H2O oxidation to release O2, and the CO2 reduction rate can further be promoted by about 3-fold under simulated sunlight. With the key reaction intermediates determined by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and predicted by DFT simulations, a possible photoredox mechanism of the CO2 reduction system is proposed.

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    • Experimental details; more FESEM/TEM images; XRD, EDX, and PL spectra; and transient photocurrent response (PDF)

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    62. Joel Jie Foo, Zi‐Jing Chiah, Sue‐Faye Ng, Wee‐Jun Ong. Strategic facet engineering of bismuth‐based photocatalysts for the applications in solar‐to‐chemical conversion. InfoScience 2024, 1 (1) https://doi.org/10.1002/inc2.12023
    63. Wenpeng Li, Yajie Chen, Jiajia Zhang, Fanze Zeng, Jinyu Bao, Lu Liu, Guohui Tian. Cocatalyst Embedded Ce‐BDC‐CeO 2 S‐Scheme Heterojunction Hollowed‐Out Octahedrons With Rich Defects for Efficient CO 2 Photoreduction. Small 2024, 20 (49) https://doi.org/10.1002/smll.202406487
    64. He Cui, Xiaoqian Wu, Shunli Li, Jiabo Wang, Ruoxue Wang, Yi Zhao, Kai Ge, YiDong Hu, Boxiong Shen, Yongfang Yang. Tannic Acid Selective Modulation Defects to Enhance the Photocatalytic CO 2 Reduction Activity of Layered Double Hydroxides. Small 2024, 20 (52) https://doi.org/10.1002/smll.202407221
    65. Bingzhu Li, Xiaohua Ma, Minjun Lei, Tian Wang, Zhiliang Jin. Graphdiyne‐Based Nickel–Cobalt Bimetallic Sulfide Cocatalyst for Efficient Photocatalytic Hydrogen Evolution. Solar RRL 2024, 8 (23) https://doi.org/10.1002/solr.202400600
    66. Xuedong Jing, Xiaoyun Mi, Wei Lu, Na Lu, Shiwen Du, Guodong Wang, Zhenyi Zhang. Edge effect-enhanced CO2 adsorption and photo-reduction over g-C3N4 nanosheet. Chinese Journal of Catalysis 2024, 67 , 112-123. https://doi.org/10.1016/S1872-2067(24)60141-5
    67. Yao CHEN, Chaoqiu CHEN, Wentao HAO, Wenlong WANG, Kun XIONG, Yong QIN. Size regulation of Pt cocatalysts and its effect on the performance of photocatalytic CO2 transformation to CH4. Journal of Fuel Chemistry and Technology 2024, 52 (12) , 1798-1809. https://doi.org/10.1016/S1872-5813(24)60472-X
    68. Akang Chen, Xinyuan Li, Mengyao Su, Yuemei Li, Baoyuan Xu, Tailei Hou, Changtao Xiao, Shuang Yu, Ruiwen Shao, Jia Liu, Weiqian Zhao, Yin Song, Leining Zhang, Jiatao Zhang. Topotactic cation exchange induced non-epitaxial atomic-organized interface in plasmonic metal-semiconductor hetero-films for efficient photoelectrochemical hydrogen evolution. Applied Catalysis B: Environment and Energy 2024, 358 , 124344. https://doi.org/10.1016/j.apcatb.2024.124344
    69. Yuxuan Zhang, Yubo Zhang, Han Wu, Yanyan Wang, Quan Gu. Tandem dual-heterojunctions in Au/ZnGa2O4/ZnO for promoted photocatalytic nonoxidative coupling of methane. Applied Catalysis B: Environment and Energy 2024, 358 , 124427. https://doi.org/10.1016/j.apcatb.2024.124427
    70. Kangwang Wang, Longfu Li, Peifeng Yu, Nannan Tang, Lingyong Zeng, Kuan Li, Chao Zhang, Rui Chen, Zaichen Xiang, Huichao Wang, Yongqing Cai, Kai Yan, Huixia Luo. Revealing the nontrivial topological surface states of catalysts for effective photochemical carbon dioxide conversion. Applied Catalysis B: Environment and Energy 2024, 358 , 124428. https://doi.org/10.1016/j.apcatb.2024.124428
    71. Cheng-Cheng Jiao, Guang-Xing Dong, Ke Su, You-Xiang Feng, Min Zhang, Tong-Bu Lu. The construction of InVO4/BiVO4 heterojunction via cation-exchange for efficient and highly selective CO2 photoreduction to methanol. Chinese Chemical Letters 2024, 3 , 110752. https://doi.org/10.1016/j.cclet.2024.110752
    72. Xianyu Deng, Jianjun Zhang, Kezhen Qi, Guijie Liang, Feiyan Xu, Jiaguo Yu. Ultrafast electron transfer at the In2O3/Nb2O5 S-scheme interface for CO2 photoreduction. Nature Communications 2024, 15 (1) https://doi.org/10.1038/s41467-024-49004-7
    73. Yunjie Zou, Chengliang Mao, Mingkai Xu, Chao Xing, Ruizhao Wang, Geoffrey A. Ozin, Lan Ling. Surface frustrated Lewis pairs in titanium nitride enable gas phase heterogeneous CO2 photocatalysis. Nature Communications 2024, 15 (1) https://doi.org/10.1038/s41467-024-54951-2
    74. Jingyi Wu, Wei Wang, Xudan Chen, Qiquan Luo, Changzeng Yan, Zhen Jiao, Yuehui Li. Boosted Efficiency of Fe 2 O 3 for Photocatalytic CO 2 Reduction via Engineering Fe−O−Ti Bonding. Advanced Science 2024, https://doi.org/10.1002/advs.202409002
    75. Jing Wu, Pingping Wang, Yuzhe Fu, Yi Shen, Bin Wang, Feng Hu, Mengkai Zuo, Wei Huang, Dayu Wu. Substituent Modulated Electronic Properties of Cu(I) Active Site in Metal–Organic Halides for Boosting Hydrogen Evolution Reaction †. Chinese Journal of Chemistry 2024, 42 (22) , 2845-2852. https://doi.org/10.1002/cjoc.202400514
    76. Morigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin Zhao. Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO 2 /mesoporous TiO 2 framework structures for efficient photocatalytic CO 2 reduction performance. Dalton Transactions 2024, 53 (44) , 17963-17975. https://doi.org/10.1039/D4DT02014F
    77. Shaoquan Li, Zixian Li, Jianing Yue, Huijuan Wang, Yujun Wang, Wenli Su, Geoffrey I. N. Waterhouse, Lihong Liu, Wenkai Zhang, Yufei Zhao. Photocatalytic CO 2 Reduction by Near‐Infrared‐Light (1200 nm) Irradiation and a Ruthenium‐Intercalated NiAl‐Layered Double Hydroxide. Angewandte Chemie 2024, 136 (45) https://doi.org/10.1002/ange.202407638
    78. Shaoquan Li, Zixian Li, Jianing Yue, Huijuan Wang, Yujun Wang, Wenli Su, Geoffrey I. N. Waterhouse, Lihong Liu, Wenkai Zhang, Yufei Zhao. Photocatalytic CO 2 Reduction by Near‐Infrared‐Light (1200 nm) Irradiation and a Ruthenium‐Intercalated NiAl‐Layered Double Hydroxide. Angewandte Chemie International Edition 2024, 63 (45) https://doi.org/10.1002/anie.202407638
    79. Qiang Wang, Li Li, Rongrong Liu, Ping Wang, Yapeng Wang, Jun Liang. An Efficient Strategy for Tailoring Interfacial Charge Transfer Pathway on Semiconductor Photocatalysts: A Case of (BiFeO 3 ) x (SrTiO 3 ) 1− x /Mn 3 O 4. Advanced Functional Materials 2024, 34 (48) https://doi.org/10.1002/adfm.202408420
    80. Yuchen Han, Yue Han, Yuye Yan, Yingxia Zong, Ruiyang Zhao, Jishu Han, Lei Wang. Construction of hollow NiTiO3/CuCo2S4 double-shell nanospheres for efficient photocatalytic hydrogen evolution. Chemical Engineering Journal 2024, 500 , 156864. https://doi.org/10.1016/j.cej.2024.156864
    81. Yuanyuan Zhang, Shiye Lou, You Yin, Xing Lv, Hao Yu, Chendong Zhuge, Lina Zhang, Lili Liu, DongEn Zhang, Linxing Shi. “One stone two birds”—Solar energy driven CO2 reduction and seawater desalination coupling reactions using floatable and recyclable integrated system. Chemical Engineering Journal 2024, 500 , 157185. https://doi.org/10.1016/j.cej.2024.157185
    82. Jiaming Li, Yuan Li, Dmitry Selishchev, Gaoke Zhang. Near-infrared responsive photocatalysts for environmental remediation and energy conversion: A review. Chemosphere 2024, 367 , 143599. https://doi.org/10.1016/j.chemosphere.2024.143599
    83. Beyza Nur Günaydın, Ali Osman Çetinkaya, Milad Torabfam, Atacan Tütüncüoğlu, Cemre Irmak Kayalan, Mustafa Kemal Bayazıt, Meral Yüce, Hasan Kurt. Plasmonic group IVB transition metal nitrides: Fabrication methods and applications in biosensing, photovoltaics and photocatalysis. Advances in Colloid and Interface Science 2024, 333 , 103298. https://doi.org/10.1016/j.cis.2024.103298
    84. Ran Yang, Xiangli Shi, Qianjin Ye, Qin Li, Qiong Zhang, Di Li, Deli Jiang. Molybdenum diselenide/polymeric carbon nitride dual-homojunction photocatalyst with multi-step charge transfer for efficient catalytic carbon dioxide reduction. Journal of Colloid and Interface Science 2024, 673 , 985-996. https://doi.org/10.1016/j.jcis.2024.06.050
    85. Jiani Qin, Yanli Dong, Xiaojuan Lai, Bo Su, Bao Pan, Chuanyi Wang, Sibo Wang. Oxygen vacancy-rich CoMoO4/Carbon nitride S-scheme heterojunction for boosted photocatalytic H2 production: Microstructure regulation and charge transfer mechanism. Journal of Materials Science & Technology 2024, 198 , 176-185. https://doi.org/10.1016/j.jmst.2024.02.032
    86. Muhammad Salman Nasir, Bowen Sheng, Ying Zhao, Haotian Ye, Jun Song, Jinglin Li, Ping Wang, Tao Wang, Xinqiang Wang, Zhen Huang, Baowen Zhou. An integrated photocatalytic redox architecture for simultaneous overall conversion of CO2 and H2O toward CH4 and H2O2. Science Bulletin 2024, 8 https://doi.org/10.1016/j.scib.2024.11.021
    87. Le Liao, Guanshun Xie, Changqiang Yu, Zhaohui Huang, Senlin Zhang, Tongzheng Zhang, Xiuqiang Xie, Nan Zhang. Active site-exposed Bi 2 WO 6 @BiOCl heterostructures for photocatalytic hydrogenation of nitroaromatic compounds. Nanoscale 2024, 16 (42) , 19704-19714. https://doi.org/10.1039/D4NR03346A
    88. Dandan Zheng, Yahan Wu, Xintuo Yang, Sibo Wang, Yuanxing Fang. Developing Polymeric Carbon Nitrides for Photocatalytic H 2 O 2 Production. ChemSusChem 2024, 17 (20) https://doi.org/10.1002/cssc.202400528
    89. Wei Wu, Zhaocen Dong, Mantao Chen, Waner Li, An Liao, Qing Liu, Yachao Zhang, Zhixin Zhou, Chao Zeng, Xuezhong Gong, Chunhui Dai. Metal–Salen‐Incorporated conjugated microporous polymers as robust artificial leaves for solar‐driven reduction of atmospheric CO 2 with H 2 O. Carbon Energy 2024, 13 https://doi.org/10.1002/cey2.646
    90. Yuan Tang, Zhong-Fei Xu, Yan Sun, Chunyang Wang, Yuchen Guo, Weichang Hao, Xin Tan, Jinhua Ye, Tao Yu. Simultaneous and efficient utilization of photogenerated electrons and holes: a case of single-atom Pd-anchored CdS twins. Energy & Environmental Science 2024, 17 (20) , 7882-7894. https://doi.org/10.1039/D4EE03092C
    91. Chenxi Tang, Tengfei Bao, Shuming Li, Xuejing Li, Heng Rao, Ping She, Jun‐sheng Qin. Rapid Charge Transfer Endowed by Hollow‐structured Z‐Scheme Heterojunction for Coupling Benzylamine Oxidation With CO 2 Reduction. Advanced Functional Materials 2024, 573 https://doi.org/10.1002/adfm.202415280
    92. Qing Chen, Jia-Le Li, Qiao-Ling Mo, Fang-Xing Xiao. Photocarrier relay modulating solar CO2-to-syngas conversion. Chemical Engineering Journal 2024, 497 , 154584. https://doi.org/10.1016/j.cej.2024.154584
    93. Xu Kong, Kai Wang, Hai Yu, Zhiliang Jin. Construction of Z-scheme heterojunction interfacial charge transfer pathways in ZnIn 2 S 4 @NENU-5 for photocatalytic hydrogen evolution. Nanoscale 2024, 16 (37) , 17505-17518. https://doi.org/10.1039/D4NR02587C
    94. Bangli Feng, Qian Wang, Peng Liu, Zibo Yuan, Danxuan Pan, Mingfu Ye, Kejing Shen, Zhifeng Xin. Z-scheme heterojunction enhanced photocatalytic performance for CO 2 reduction to CH 4. Nanoscale 2024, 16 (37) , 17616-17623. https://doi.org/10.1039/D4NR02897J
    95. Yaoling Pan, Zhenyu Bao, Chen Wang, Zhengyu Wang, Penghui Xu, Xinwen Bai, Xiaowei Shi, Huajun Zheng, Hong‐En Wang, Lingxia Zheng. Electrochemical Hydrogenation of Quinoline Enabled by Cu 0 ‐Cu + Dual Sites Coupled with Efficient Biomass Valorization in Aqueous Solution. Advanced Functional Materials 2024, 10 https://doi.org/10.1002/adfm.202414120
    96. Chen-Yo Tsai, Wei-Hsuan Chang, Ming-Yen Lu, Lih-Juann Chen. Advances in the heterostructures for enhanced hydrogen production efficiency: a comprehensive review. Nanoscale 2024, 16 (35) , 16376-16403. https://doi.org/10.1039/D4NR01837K
    97. Min Zhou, Haozhi Wang, Rong Liu, Zheyang Liu, Xinyan Xiao, Weilin Li, Chao Gao, Zhou Lu, Zhifeng Jiang, Weidong Shi, Yujie Xiong. Construction of Frustrated Lewis Pairs in Poly(heptazine Imide) Nanosheets via Hydrogen Bonds for Boosting CO 2 Photoreduction. Angewandte Chemie 2024, 136 (36) https://doi.org/10.1002/ange.202407468
    98. Min Zhou, Haozhi Wang, Rong Liu, Zheyang Liu, Xinyan Xiao, Weilin Li, Chao Gao, Zhou Lu, Zhifeng Jiang, Weidong Shi, Yujie Xiong. Construction of Frustrated Lewis Pairs in Poly(heptazine Imide) Nanosheets via Hydrogen Bonds for Boosting CO 2 Photoreduction. Angewandte Chemie International Edition 2024, 63 (36) https://doi.org/10.1002/anie.202407468
    99. Haiting Lin, Anyi Chen, Tianren Liu, Wensheng Zhang, Xinyv Du, Junjie Feng, Jiajun Zeng, Yingying Fan, Dongxue Han, Li Niu. Synergistically Photocatalytic Conversion of Two Greenhouse Gases to Liquid‐Phase Oxygenates under Anaerobic Conditions. Solar RRL 2024, 8 (18) https://doi.org/10.1002/solr.202400522
    100. Jiaojiao Fang, Chengyang Zhu, Lincan Fang, Yukai Chen, Huiling Hu, Yan Wu, Qingqing Chen, Junjie Mao. Efficient charge relay steering in Pd nanoparticles coupled with the heterojunction for boosting CO2 photoreduction to C2H6. Science China Materials 2024, 67 (9) , 2949-2956. https://doi.org/10.1007/s40843-024-2995-0
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