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Self-Assembly of Nanometer-Sized Boroxine Cages from Diboronic Acids
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    Self-Assembly of Nanometer-Sized Boroxine Cages from Diboronic Acids
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    † § Department of Chemistry, Department of Chemistry and Materials Science, Tokyo Institute of Technology and §JST-CREST, O-okayama, Meguro-ku, Tokyo 152-8551, Japan
    Japan Synchrotron Radiation Research Institute/SPring-8, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2015, 137, 22, 7015–7018
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    https://doi.org/10.1021/jacs.5b02716
    Published May 18, 2015
    Copyright © 2015 American Chemical Society

    Abstract

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    By use of the reversible trimerization of boronic acids, the series of boroxine cages 3-mer, 6-mer, and 12-mer were constructed from rationally designed diboronic acids whose bond angles between two C–B bonds are 60°, 84°, and 117°, respectively. Boroxine cages 6-mer and 12-mer have 1.5 and 2.5 nm sized cavities, respectively.

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    Additional experimental details, characterization data for new compounds, and crystallographic data (CIF). The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.5b02716.

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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2015, 137, 22, 7015–7018
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    https://doi.org/10.1021/jacs.5b02716
    Published May 18, 2015
    Copyright © 2015 American Chemical Society

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