Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
Photoinduced Bending of Self-Assembled Azobenzene–Siloxane Hybrid

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2015, 137, 49, 15434-15440
    Article

    Photoinduced Bending of Self-Assembled Azobenzene–Siloxane Hybrid
    Click to copy article linkArticle link copied!

    View Author Information
    † Institute for Nanoscience & Technology, Waseda University, 513 Wasedatsurumaki-cho, Shinjuku-ku, Tokyo 162-0041, Japan
    ‡ Electronic Materials Research Division, Osaka Municipal Technical Research Institute, 1-6-50 Morinomiya, Joto-ku, Osaka 536-8553, Japan
    § Department of Chemistry and Materials Engineering, Kansai University, 3-3-35 Yamate-cho, Suita-shi, Osaka 564-8680, Japan
    ∥ Department of Chemical System Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
    # Department of Applied Chemistry, Waseda University, 3-4-1 Ohkubo, Shinjuku-ku, Tokyo 169-8555, Japan
    Kagami Memorial Research Institute for Materials Science and Technology, Waseda University, 2-8-26 Nishiwaseda, Shinjuku-ku, Tokyo 169-0051, Japan
    *[email protected]
    Other Access OptionsSupporting Information (5)

    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2015, 137, 49, 15434–15440
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jacs.5b06172
    Published November 17, 2015
    Copyright © 2015 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    A novel azobenzene–siloxane hybrid material displaying photoinduced macroscopic motions has been prepared by one-step organosilane self-assembly. Two types of alkoxysilane precursors with either pendant or bridging azobenzene groups were synthesized via thiol–ene click reactions. Hybrid films with well-ordered lamellar structures were obtained by hydrolysis and polycondensation of these precursors. The film with solely pendant azobenzene groups showed reversible and rapid d-spacing variation upon UV–vis irradiation, which was induced by the trans–cis isomerization of azobenzene moieties. The flexible, free-standing film obtained by co-condensation of two types of precursors showed reversible bending–unbending motions upon UV–vis irradiation. The partial cross-linking between the siloxane layers by bridging azobenzene groups was crucial for photoinduced distortion of the film. This film possesses high elastic modulus, good thermal stability, and shows large amplitude of photoinduced bending–unbending over a wide temperature range. This is the first report on photoinduced macroscopic motions of azobenzene-containing siloxane-based materials. These materials possess great potential for applications in smart devices and energy conversion systems.

    Copyright © 2015 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.5b06172.

    • Figures S1–S13. (PDF)

    • Movie S1. (MPG)

    • Movie S2. (MPG)

    • Movie S3. (MPG)

    • Movie S4. (MPG)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 98 publications.

    1. Yasutaka Nagaoka, Jeremy Schneider, Na Jin, Tong Cai, Yuzi Liu, Zhongwu Wang, Ruipeng Li, Kyung-Suk Kim, Ou Chen. Dynamic Transformation of High-Architectural Nanocrystal Superlattices upon Solvent Molecule Exposure. Journal of the American Chemical Society 2024, 146 (19) , 13093-13104. https://doi.org/10.1021/jacs.3c14603
    2. Jing-Ru Zhang, Yi Mo, Wei Fang, Ya-Xian Yuan, Jian-Lin Yao, Ji Hong Wu. Insight into Multiphase Interlayer Molecular Packing and Stepwise Phase Transition in 4-(Phenylazo)benzoate Anion-Intercalated Layered Zinc Hydroxide. Inorganic Chemistry 2024, 63 (8) , 3692-3701. https://doi.org/10.1021/acs.inorgchem.3c03650
    3. Misaki Kitagawa, Yuma Nakagawa, Takato Ii, Ryo Nishimura, Masakazu Morimoto, Satoshi Yokojima, Shinichiro Nakamura, Kingo Uchida. Photoinduced Multistep Bending of 7-Acetoxy-4-methylcoumarin Crystal. Crystal Growth & Design 2024, 24 (3) , 913-922. https://doi.org/10.1021/acs.cgd.3c00738
    4. Sheng Zheng, Yu-Liang Lin, Chun-Chi Chang, Min-Jie Lee, Yi-Fan Chen, Lin-Ruei Lee, Ming-Hsuan Chang, Jiun-Tai Chen. Boosting Ion Conductivities: Light-Modulated Azobenzene-Based Ionic Liquids in Vertical Nanochannels. ACS Applied Materials & Interfaces 2023, 15 (38) , 45418-45425. https://doi.org/10.1021/acsami.3c08792
    5. Chi-Hsien Wang, Hong-Kai Chang, Kai-Jen Chen, Dao-Hong Huang, Chiung-Ju Chang, Kuan-Hung Huang, Yao-De Chiu, Masaki Horie. Facile Photoresponsive Actuators Based on Ferrocene-Doped Poly(butyl methacrylate). ACS Applied Materials & Interfaces 2023, 15 (32) , 38846-38856. https://doi.org/10.1021/acsami.3c07788
    6. Aya Edagawa, Satoru Matsuda, Hirofumi Kawakubo, Hiroaki Imai, Yuya Oaki. Coatable 2D Conjugated Polymers Containing Bulky Macromolecular Guests for Thermal Imaging. ACS Applied Materials & Interfaces 2022, 14 (38) , 43792-43801. https://doi.org/10.1021/acsami.2c12909
    7. Zhiwei Li, Qingsong Fan, Yadong Yin. Colloidal Self-Assembly Approaches to Smart Nanostructured Materials. Chemical Reviews 2022, 122 (5) , 4976-5067. https://doi.org/10.1021/acs.chemrev.1c00482
    8. Tingting Xu, Sufang Guo, Miaomiao Li, Zhen Zhang, Baobao Pang, Yingmo Hu. Multiphotoinduced Bending of Azobenzene-Modified Graphene Oxide/Poly(vinyl alcohol) Composite Films for Smart Devices. ACS Applied Nano Materials 2021, 4 (10) , 10209-10217. https://doi.org/10.1021/acsanm.1c01671
    9. Zili Li, Zhiqun Lin. Self-Assembly of Bolaamphiphiles into 2D Nanosheets via Synergistic and Meticulous Tailoring of Multiple Noncovalent Interactions. ACS Nano 2021, 15 (2) , 3152-3160. https://doi.org/10.1021/acsnano.0c09693
    10. Junhong Pang, Ziqi Deng, Shanshan Sun, Guanheng Huang, Guohui Zhang, Amjad Islam, Li Dang, David Lee Phillips, Ming-De Li. Unprecedentedly Ultrafast Dynamics of Excited States of C═C Photoswitching Molecules in Nanocrystals and Microcrystals. The Journal of Physical Chemistry Letters 2021, 12 (1) , 41-48. https://doi.org/10.1021/acs.jpclett.0c03232
    11. Shao-Chi Cheng, Chi-Hsien Wang, Yi-Chia Lin, Yoshitaka Tsuchido, Yuji Suzaki, Yoshihisa Sei, Ting-Shen Kuo, Masaki Horie. Photoinduced Mechanical Motions of Pseudorotaxane Crystals Composed of Azobenzene and Ferrocenyl Groups on an Axle and a Crown Ether Ring. ACS Applied Materials & Interfaces 2020, 12 (44) , 50002-50010. https://doi.org/10.1021/acsami.0c15171
    12. Jing Zhang, Benzhao He, Wenjie Wu, Parvej Alam, Han Zhang, Junyi Gong, Fengyan Song, Zaiyu Wang, Herman H. Y. Sung, Ian D. Williams, Zhiming Wang, Jacky W. Y. Lam, Ben Zhong Tang. Molecular Motions in AIEgen Crystals: Turning on Photoluminescence by Force-Induced Filament Sliding. Journal of the American Chemical Society 2020, 142 (34) , 14608-14618. https://doi.org/10.1021/jacs.0c06305
    13. Damien Dattler, Gad Fuks, Joakim Heiser, Emilie Moulin, Alexis Perrot, Xuyang Yao, Nicolas Giuseppone. Design of Collective Motions from Synthetic Molecular Switches, Rotors, and Motors. Chemical Reviews 2020, 120 (1) , 310-433. https://doi.org/10.1021/acs.chemrev.9b00288
    14. Ryota Kajiya, Seiya Sakakibara, Hanako Ikawa, Kenji Higashiguchi, Kenji Matsuda, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima. Inorganic–Organic Hybrid Photomechanical Crystals Consisting of Diarylethenes and Cage Siloxanes. Chemistry of Materials 2019, 31 (22) , 9372-9378. https://doi.org/10.1021/acs.chemmater.9b02941
    15. Wanli Tian, Tingting Lin, Hua Chen, Weizhi Wang. Configuration-Controllable E/Z Isomers Based on Tetraphenylethene: Synthesis, Characterization, and Applications. ACS Applied Materials & Interfaces 2019, 11 (6) , 6302-6314. https://doi.org/10.1021/acsami.8b19672
    16. Daniel Moldenhauer, Juan Pablo Fuenzalida Werner, Cristian A. Strassert, Franziska Gröhn. Light-Responsive Size of Self-Assembled Spiropyran–Lysozyme Nanoparticles with Enzymatic Function. Biomacromolecules 2019, 20 (2) , 979-991. https://doi.org/10.1021/acs.biomac.8b01605
    17. Sudha Devi, Mayank Saraswat, Surbhi Grewal, Sugumar Venkataramani. Evaluation of Substituent Effect in Z-Isomer Stability of Arylazo-1H-3,5-dimethylpyrazoles: Interplay of Steric, Electronic Effects and Hydrogen Bonding. The Journal of Organic Chemistry 2018, 83 (8) , 4307-4322. https://doi.org/10.1021/acs.joc.7b02604
    18. Xiao-Dong Yang, Rui Zhu, Li Sun, Rui-Yun Guo, Jie Zhang. Phototriggered Mechanical Movement in A Bipyridinium-based Coordination Polymer Powered by Electron Transfer. Inorganic Chemistry 2018, 57 (5) , 2724-2729. https://doi.org/10.1021/acs.inorgchem.7b03108
    19. Shao-Chi Cheng, Kai-Jen Chen, Yuji Suzaki, Yoshitaka Tsuchido, Ting-Shen Kuo, Kohtaro Osakada, and Masaki Horie . Reversible Laser-Induced Bending of Pseudorotaxane Crystals. Journal of the American Chemical Society 2018, 140 (1) , 90-93. https://doi.org/10.1021/jacs.7b10998
    20. Zheng Wu, Rongrong Xue, Mengqi Xie, Xuejiao Wang, Zihao Liu, Markus Drechsler, Jianbin Huang, and Yun Yan . Self-Assembly-Triggered Cis-to-Trans Conversion of Azobenzene Compounds. The Journal of Physical Chemistry Letters 2018, 9 (1) , 163-169. https://doi.org/10.1021/acs.jpclett.7b03060
    21. Tetsuo Yamaguchi, Ayan Maity, Vivek Polshettiwar, and Makoto Ogawa . Photochromism of a Spiropyran in the Presence of a Dendritic Fibrous Nanosilica; Simultaneous Photochemical Reaction and Adsorption. The Journal of Physical Chemistry A 2017, 121 (42) , 8080-8085. https://doi.org/10.1021/acs.jpca.7b08466
    22. Zili Li, Miao Tang, Jingwen Dai, Taisheng Wang, Zhisheng Wang, Wei Bai, and Ruke Bai . Preparation of Covalent Pseudo-Two-Dimensional Polymers in Water by Free Radical Polymerization. Macromolecules 2017, 50 (11) , 4292-4299. https://doi.org/10.1021/acs.macromol.7b00668
    23. Yantong Chen, Chao Li, Xiuru Xu, Ming Liu, Yaowu He, Imran Murtaza, Dongwei Zhang, Chao Yao, Yongfeng Wang, and Hong Meng . Thermal and Optical Modulation of the Carrier Mobility in OTFTs Based on an Azo-anthracene Liquid Crystal Organic Semiconductor. ACS Applied Materials & Interfaces 2017, 9 (8) , 7305-7314. https://doi.org/10.1021/acsami.6b13500
    24. Mineo Hashizume, Soichiro Fukagawa, Shoko Mishima, Takumi Osuga, and Kazutoshi Iijima . Hot-Press-Assisted Adhesions between Polyimide Films and Titanium Plates Utilizing Coating Layers of Silane Coupling Agents. Langmuir 2016, 32 (47) , 12344-12351. https://doi.org/10.1021/acs.langmuir.6b01657
    25. Lin Ai, Yanchun Li, Zhennan Wu, Jiale Liu, Yu Gao, Yi Liu, Zhongyuan Lu, Hao Zhang, and Bai Yang . Photoinduced Conversion of Cu Nanoclusters Self-Assembly Architectures from Ribbons to Spheres. The Journal of Physical Chemistry C 2016, 120 (42) , 24427-24436. https://doi.org/10.1021/acs.jpcc.6b06600
    26. Durga Prasad Karothu, James Weston, Israel Tilahun Desta, and Panče Naumov . Shape-Memory and Self-Healing Effects in Mechanosalient Molecular Crystals. Journal of the American Chemical Society 2016, 138 (40) , 13298-13306. https://doi.org/10.1021/jacs.6b07406
    27. Xiaofeng Fang, Yu-Mo Zhang, Kaiwen Chang, Zhihe Liu, Xing Su, Haobin Chen, Sean Xiao-An Zhang, Yifei Liu, and Changfeng Wu . Facile Synthesis, Macroscopic Separation, E/Z Isomerization, and Distinct AIE properties of Pure Stereoisomers of an Oxetane-Substituted Tetraphenylethene Luminogen. Chemistry of Materials 2016, 28 (18) , 6628-6636. https://doi.org/10.1021/acs.chemmater.6b02746
    28. Chisato Izutani, Daisuke Fukagawa, Makoto Miyasita, Masaki Ito, Natsuhiko Sugimura, Reiko Aoyama, Takahiro Gotoh, Toshimichi Shibue, Yoko Igarashi, and Hiroshi Oshio . The Materials Characterization Central Laboratory: An Open-Ended Laboratory Program for Fourth-Year Undergraduate and Graduate Students. Journal of Chemical Education 2016, 93 (9) , 1667-1670. https://doi.org/10.1021/acs.jchemed.6b00161
    29. Yuya OAKI. Recent Advances in Two-Dimensional Polymer Materials. POLYMERS 2024, 73 (10) , 521-525. https://doi.org/10.1295/kobunshi.73.10_521
    30. Bratati Das, Nano Shioda, Shunsuke Yagi, Yuya Oaki, Kaori Sugihara. Nanoscopic Force Sensitivity of Polydiacetylene 2D Layered Composites with Guest Molecules. Advanced Materials Interfaces 2023, 378 https://doi.org/10.1002/admi.202300745
    31. Kazuma Hamaguchi, Huanjun Lu, Shota Okamura, Satoshi Kajiyama, Junya Uchida, Shunsuke Sato, Go Watanabe, Yoshiki Ishii, Hitoshi Washizu, Goran Ungar, Takashi Kato. Reentrant 2D Nanostructured Liquid Crystals by Competition between Molecular Packing and Conformation: Potential Design for Multistep Switching of Ionic Conductivity. ChemPhysChem 2023, 24 (8) https://doi.org/10.1002/cphc.202200927
    32. Tetsuo Yamaguchi, Makoto Ogawa. Photoinduced movement: how photoirradiation induced the movements of matter. Science and Technology of Advanced Materials 2022, 23 (1) , 796-844. https://doi.org/10.1080/14686996.2022.2142955
    33. Takehiro Harigaya, Ryota Kajiya, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima. Photomechanical organosiloxane films derived from azobenzene-modified di- and tri-alkoxysilanes. Journal of Sol-Gel Science and Technology 2022, 104 (3) , 659-665. https://doi.org/10.1007/s10971-022-05825-w
    34. Lin Ai, Huimin Liu, Rui Liu, Haoqiang Song, Ziqi Song, Mingjun Nie, Geoffrey I. N. Waterhouse, Siyu Lu. Dual sensitivity of spiropyran-functionalized carbon dots for full color conversions. Science China Chemistry 2022, 65 (11) , 2274-2282. https://doi.org/10.1007/s11426-022-1346-6
    35. Dowon Moon, Min‐Gyu Lee, Jeong‐Yun Sun, Kwang Hoon Song, Junsang Doh. Jammed Microgel‐Based Inks for 3D Printing of Complex Structures Transformable via pH/Temperature Variations. Macromolecular Rapid Communications 2022, 43 (19) https://doi.org/10.1002/marc.202200271
    36. Koichi Kajihara, Kazuyoshi Kanamori, Atsushi Shimojima. Current status of sol–gel processing of glasses, ceramics, and organic–inorganic hybrids: a brief review. Journal of the Ceramic Society of Japan 2022, 130 (8) , 575-583. https://doi.org/10.2109/jcersj2.22078
    37. Aleksei I. Ryzhkov, Fedor V. Drozdov, Georgij V. Cherkaev, Mihail I. Buzin, Evgeniya A. Svidchenko, Aziz M. Muzafarov. Synthesis and properties of new siloxane with terminal azodyes functions based on eugenol. Journal of Applied Polymer Science 2022, 139 (24) https://doi.org/10.1002/app.52340
    38. Shujin Zhou, Kai Sheng, Na Zhang, Han Zhang, Hongguang Li, Panpan Sun, Xia Xin. Light-triggered reversible supramolecular self-assembly of azo groups-functionalized copper nanoclusters. Journal of Molecular Liquids 2021, 343 , 117698. https://doi.org/10.1016/j.molliq.2021.117698
    39. Jing Zhang, Benzhao He, Yubing Hu, Parvej Alam, Haoke Zhang, Jacky W. Y. Lam, Ben Zhong Tang. Stimuli‐Responsive AIEgens. Advanced Materials 2021, 33 (32) https://doi.org/10.1002/adma.202008071
    40. Taichi Kato, Masayuki Gon, Kazuo Tanaka, Yoshiki Chujo. Modulation of stimuli‐responsiveness toward acid vapor between real‐time and write‐erase responses based on conjugated polymers containing azobenzene and Schiff base moieties. Journal of Polymer Science 2021, 59 (14) , 1596-1602. https://doi.org/10.1002/pol.20210329
    41. Supreet Kaur, Nazma Begum, Golam Mohiuddin, Santanu Kumar Pal. Photo‐Responsive Behavior of Azobenzene Based Polar Hockey‐Stick‐Shaped Liquid Crystals. ChemPhysChem 2021, 22 (13) , 1361-1370. https://doi.org/10.1002/cphc.202100215
    42. Hirotoshi Sakaino, Brigitte A. G. Lamers, Stefan C. J. Meskers, E. W. Meijer, Ghislaine Vantomme. Photo‐controlled alignment and helical organization in main‐chain liquid crystalline alternating polymers. Journal of Polymer Science 2021, 59 (12) , 1131-1141. https://doi.org/10.1002/pol.20210057
    43. Ye Shang, Linlin Sun, Huiqin Wang, Songtian Li, Kesheng Cao, Pengwei Huo. Azobenzene-modified Ag/Ag 2 O/CN photocatalysts with photoresponsive performance for controllable photodegradation of tetracyclines. New Journal of Chemistry 2021, 45 (21) , 9677-9690. https://doi.org/10.1039/D1NJ00933H
    44. Nai–hsuan Hu, Joseph Coy Furgal. Photoreversible Loading and Unloading of Q–Silsesquioxane Dynamic Network Sponges. Advanced Functional Materials 2021, 31 (13) https://doi.org/10.1002/adfm.202010114
    45. A. S. Soldatenko, N. F. Lazareva. Cyclic hybrid compounds based on 1,3- and 1,5-dichlorosiloxanes and 2,2′-dihydroxyazobenzene. Russian Chemical Bulletin 2021, 70 (1) , 158-163. https://doi.org/10.1007/s11172-021-3071-0
    46. Majeed Irfan, Rong Deng, Idrees Sumra, Xiao-Feng Zhu, Tingting Liu, Zhuo Zeng. Stereoselective synthesis of E, E / E, Z isomers based on 1-(4- iodophenyl)-2,5-divinyl-1H-pyrrole core skeleton: A configuration-controlled fluorescence characteristics and highly selective anti-cancer activity. Dyes and Pigments 2021, 184 , 108733. https://doi.org/10.1016/j.dyepig.2020.108733
    47. Yuya Oaki. Intercalation and flexibility chemistries of soft layered materials. Chemical Communications 2020, 56 (86) , 13069-13081. https://doi.org/10.1039/D0CC05931E
    48. Jinhua Wang, Airui Jiang, Jingyang Wang, Bin Song, Yao He. Dual-emission fluorescent silicon nanoparticle-based nanothermometer for ratiometric detection of intracellular temperature in living cells. Faraday Discussions 2020, 222 , 122-134. https://doi.org/10.1039/C9FD00088G
    49. Lei Gao, Yunhui Hao, Xiunan Zhang, Xin Huang, Ting Wang, Hongxun Hao. Polymorph induced diversity of photomechanical motions of molecular crystals. CrystEngComm 2020, 22 (19) , 3279-3286. https://doi.org/10.1039/D0CE00311E
    50. Ye Yuan, Bo Wu, Liang Jiang, Zhimeng Liu, Yi Wang, Xiaowei Fu, Weibo Kong, Jingxin Lei. Nonconstant enthalpy of thermosetting solid-solid phase change materials controlled by light. Energy and Buildings 2020, 214 , 109894. https://doi.org/10.1016/j.enbuild.2020.109894
    51. Nai-hsuan Hu, Joseph C. Furgal. R-Silsesquioxane-Based Network Polymers by Fluoride Catalyzed Synthesis: An Investigation of Cross-Linker Structure and Its Influence on Porosity. Materials 2020, 13 (8) , 1849. https://doi.org/10.3390/ma13081849
    52. Ryota Kajiya, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima. Inorganic–Organic Hybrid Photomechanical Crystals of Azobenzene-modified Polyhedral Oligomeric Silsesquioxane (POSS). Chemistry Letters 2020, 49 (3) , 327-329. https://doi.org/10.1246/cl.190926
    53. Meng Gao, Jie Zeng, Kang Liang, Dongyuan Zhao, Biao Kong. Interfacial Assembly of Mesoporous Silica‐Based Optical Heterostructures for Sensing Applications. Advanced Functional Materials 2020, 30 (9) https://doi.org/10.1002/adfm.201906950
    54. Sufang Guo, Atsushi Shimojima. Organic–Inorganic Hybrid Materials with Photomechanical Functions. 2020, 257-275. https://doi.org/10.1002/9783527822201.ch10
    55. Ejaz Ahmed, Durga Prasad Karothu, Mark Warren, Panče Naumov. Shape-memory effects in molecular crystals. Nature Communications 2019, 10 (1) https://doi.org/10.1038/s41467-019-11612-z
    56. Jiyeon Lee, Wonsik Lee, Dongjun Kim, Myungjun Kim, Jiwon Kim. Independent Multi-states of Photo-responsive Polymer/Quantum Dot Nanocomposite Induced via Different Wavelengths of Light. Scientific Reports 2019, 9 (1) https://doi.org/10.1038/s41598-019-48834-6
    57. Jin-jian Liu, Jing Li. Photochromism of stable crystalline 3D Cd-viologen coordination polymers. Dyes and Pigments 2019, 170 , 107565. https://doi.org/10.1016/j.dyepig.2019.107565
    58. Masaki Horie, Chi-Hsien Wang. Stimuli-responsive dynamic pseudorotaxane crystals. Materials Chemistry Frontiers 2019, 3 (11) , 2258-2269. https://doi.org/10.1039/C9QM00483A
    59. Shohei Saito, Naoto Sato, Masashi Yoshikawa, Atsushi Shimojima, Kazuyuki Kuroda. Siloxane‐Based Building Blocks for Molecular Technology. 2019, 119-161. https://doi.org/10.1002/9783527823987.vol4_c6
    60. María J. Galante, Ileana A. Zucchi, Patricia A. Oyanguren, Luciana M. Sáiz. Light-induced healing in azobenzene bridged silsesquioxanes. European Polymer Journal 2019, 117 , 382-390. https://doi.org/10.1016/j.eurpolymj.2019.05.025
    61. Yihan Wang, Lizhi Hu, Qiang Yin, Kai Du, Taoran Zhang, Qinjian Yin. Multi-responsive hollow nanospheres self-assembly by amphiphilic random copolymer and azobenzene. Polymer 2019, 175 , 235-242. https://doi.org/10.1016/j.polymer.2019.04.071
    62. Xiaoyang Zhu, Yanfang Geng, Xuefeng Zhu, Pengfei Duan, Feng Li, Qingdao Zeng, Junjie Qi. Dependence of the photo-response behavior of self-assembled 2D Azo-derivatives on the functional groups on a solid surface. New Journal of Chemistry 2019, 43 (16) , 6262-6266. https://doi.org/10.1039/C9NJ00291J
    63. Bin Wang, Haoran Qian. Different behaviors of self-assembled nanostructure with three-types of azopyridine hydrochloride salts. Materials Research Express 2019, 6 (4) , 045104. https://doi.org/10.1088/2053-1591/aafe56
    64. Lingling Wang, Yingchuan Zhang, Chenhao Zhan, Yong You, Hongxing Zhang, Jinyi Ma, Zhiyuan Xiong, Xiaobo Liu, Renbo Wei. Synthesis and Photoinduced Anisotropy of Polymers Containing Nunchaku-Like Unit with an Azobenzene and a Mesogen. Polymers 2019, 11 (4) , 600. https://doi.org/10.3390/polym11040600
    65. Sudha Devi, Indu Bala, Santosh Prasad Gupta, Pravesh Kumar, Santanu Kumar Pal, Sugumar Venkataramani. Reversibly photoswitchable alkoxy azobenzenes connected benzenetricarboxamide discotic liquid crystals with perpetual long range columnar assembly. Organic & Biomolecular Chemistry 2019, 17 (7) , 1947-1954. https://doi.org/10.1039/C8OB01579A
    66. Yunhui Hao, Shuai Huang, Yanmei Guo, Lina Zhou, Hongxun Hao, Christopher J. Barrett, Haifeng Yu. Photoinduced multi-directional deformation of azobenzene molecular crystals. Journal of Materials Chemistry C 2019, 7 (3) , 503-508. https://doi.org/10.1039/C8TC04631J
    67. Sufang Guo, Kazuyuki Kuroda, Atsushi Shimojima. Design of Element Blocks for Photoresponsive Organosiloxane-Based Materials. 2019, 243-252. https://doi.org/10.1007/978-981-13-2889-3_14
    68. Mineo Hashizume. Nanoarchitectonics With Hybrid Materials. 2019, 255-275. https://doi.org/10.1016/B978-0-12-813341-5.00011-5
    69. Gagandeep Singh, Pushap Raj, Harupjit Singh, Narinder Singh. Colorimetric detection and ratiometric quantification of mercury( ii ) using azophenol dye: ‘dip & read’ based handheld prototype device development. Journal of Materials Chemistry C 2018, 6 (46) , 12728-12738. https://doi.org/10.1039/C8TC04720K
    70. Xia Yu, Hui Chen, Xiang Shi, Pierre-Antoine Albouy, Jia Guo, Jun Hu, Min-Hui Li. Liquid crystal gelators with photo-responsive and AIE properties. Materials Chemistry Frontiers 2018, 2 (12) , 2245-2253. https://doi.org/10.1039/C8QM00340H
    71. Nuo‐Hua Xie, Chong Li, Ying Chen, Tao Chen, Zhitian Liu, Ming‐Qiang Zhu. Photoswitchable Self‐Assembly/Disassembly of Near‐Infrared Fluorophores. Chemistry – A European Journal 2018, 24 (61) , 16251-16256. https://doi.org/10.1002/chem.201803896
    72. Machi Takeuchi, Karthikeyan Gnanasekaran, Heiner Friedrich, Hiroaki Imai, Nico A. J. M. Sommerdijk, Yuya Oaki. Tunable Stimuli‐Responsive Color‐Change Properties of Layered Organic Composites. Advanced Functional Materials 2018, 28 (45) https://doi.org/10.1002/adfm.201804906
    73. Xin Peng, Huiliang Wang. Shape changing hydrogels and their applications as soft actuators. Journal of Polymer Science Part B: Polymer Physics 2018, 56 (19) , 1314-1324. https://doi.org/10.1002/polb.24724
    74. Fedor V. Drozdov, Georgij V. Cherkaev, Mihail I. Buzin, Aziz M. Muzafarov. Facile methods of siloxanes derivatives modification by azodyes based on eugenol. Journal of Organometallic Chemistry 2018, 871 , 135-139. https://doi.org/10.1016/j.jorganchem.2018.07.018
    75. Hideto Terada, Hiroaki Imai, Yuya Oaki. Visualization and Quantitative Detection of Friction Force by Self‐Organized Organic Layered Composites. Advanced Materials 2018, 30 (27) https://doi.org/10.1002/adma.201801121
    76. Zili Li, Miao Tang, Chen Jiang, Ruke Bai, Wei Bai. Photoinduced Reversible Morphological Transformation of Azobenzene‐Containing Pseudo‐2D Polymers. Macromolecular Rapid Communications 2018, 39 (11) https://doi.org/10.1002/marc.201700880
    77. R. Helen Zha, Ghislaine Vantomme, José Augusto Berrocal, Ronald Gosens, Bas de Waal, Stefan Meskers, E. W. Meijer. Photoswitchable Nanomaterials Based on Hierarchically Organized Siloxane Oligomers. Advanced Functional Materials 2018, 28 (1) https://doi.org/10.1002/adfm.201703952
    78. Hee-Soo So, Takaya Minami, Takumi Jindo, Shinya Matsumoto. Thermosalient effect of two polymorphs of a diketopyrrolopyrrole dye with different crystal systems and molecular arrangements. CrystEngComm 2018, 20 (36) , 5317-5320. https://doi.org/10.1039/C8CE00940F
    79. Yukiko Ishijima, Hiroaki Imai, Yuya Oaki. Tunable Mechano-responsive Color-Change Properties of Organic Layered Material by Intercalation. Chem 2017, 3 (3) , 509-521. https://doi.org/10.1016/j.chempr.2017.05.013
    80. Lijie Li, Lipeng He, Xiaoning Liu, Haomin Liu, Linlin Hu, Pingxia Guo, Weifeng Bu. E / Z isomerization effects on aggregation-enhanced emission of tetraphenylethene derivatives assisted by host–guest recognition. RSC Advances 2017, 7 (61) , 38581-38585. https://doi.org/10.1039/C7RA06475F
    81. Sufang Guo, Jun Sasaki, Shiho Tsujiuchi, Shintaro Hara, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima. Role of Cubic Siloxane Cages in Mesostructure Formation and Photoisomerization of Azobenzene–Siloxane Hybrid. Chemistry Letters 2017, 46 (8) , 1237-1239. https://doi.org/10.1246/cl.170468
    82. Wei Li, Tairong Kuang, Xiaoping Jiang, Jintao Yang, Ping Fan, Zhengping Zhao, Zhengdong Fei, Mingqiang Zhong, Lingqian Chang, Feng Chen. Photoresponsive polyelectrolyte/mesoporous silica hybrid materials with remote-controllable ionic transportation. Chemical Engineering Journal 2017, 322 , 445-453. https://doi.org/10.1016/j.cej.2017.04.048
    83. Qiang Matthew Zhang, Michael J. Serpe. Stimuli‐Responsive Polymers for Actuation. ChemPhysChem 2017, 18 (11) , 1451-1465. https://doi.org/10.1002/cphc.201601187
    84. Dae‐Yoon Kim, Suyong Shin, Won‐Jin Yoon, Yu‐Jin Choi, Joo‐Kyoung Hwang, Jin‐Soo Kim, Cheul‐Ro Lee, Tae‐Lim Choi, Kwang‐Un Jeong. From Smart Denpols to Remote‐Controllable Actuators: Hierarchical Superstructures of Azobenzene‐Based Polynorbornenes. Advanced Functional Materials 2017, 27 (18) https://doi.org/10.1002/adfm.201606294
    85. Lingli Ni, Mei Wu, Feng Chen, Irena Deroche, Abraham Chemtob. Ordering minimalist bridged polysilsesquioxane films under visible LED light irradiation. Soft Materials 2017, 15 (2) , 196-204. https://doi.org/10.1080/1539445X.2017.1308380
    86. Rong Tang, Wei Sang, Yeping Wu, Chunhua Zhu, Jian Liu. Multi-Wavelength Light Drivable Oscillatory Actuator on Graphene-Based Bilayer Film. Macromolecular Materials and Engineering 2017, 302 (2) , 1600384. https://doi.org/10.1002/mame.201600384
    87. Caixia Liu, Zhiqiang Li, Yige Wang. Novel fluorescent terphenyl bridged crystalline silsesquioxane through self-directed assembly. Journal of Sol-Gel Science and Technology 2017, 81 (2) , 593-599. https://doi.org/10.1007/s10971-016-4219-5
    88. Tomohiko Okada, Nozomi Nozaki, Jangwon Seo, Ji Eon Kwon, Soo Young Park, Hideo Hashizume, Takayoshi Sasaki, Makoto Ogawa. Photoinduced structural changes of cationic azo dyes confined in a two dimensional nanospace by two different mechanisms. RSC Advances 2017, 7 (13) , 8077-8081. https://doi.org/10.1039/C6RA27749G
    89. Kai Feng, Shusheng Li, Linglong Feng, Shengyu Feng. Synthesis of thermo- and photo-responsive polysiloxanes with tunable phase separation via aza-Michael addition. New Journal of Chemistry 2017, 41 (23) , 14498-14504. https://doi.org/10.1039/C7NJ03177G
    90. Irene Vassalini, Ivano Alessandri. “The phactalysts”: carbon nanotube/TiO 2 composites as phototropic actuators for wireless remote triggering of chemical reactions and catalysis. Nanoscale 2017, 9 (32) , 11446-11451. https://doi.org/10.1039/C7NR05104B
    91. K. Nickmans, Ph. Leclère, J. Lub, D. J. Broer, A. P. H. J. Schenning. Reactive oligo(dimethylsiloxane) mesogens and their nanostructured thin films. Soft Matter 2017, 13 (24) , 4357-4362. https://doi.org/10.1039/C7SM00673J
    92. Ihor M. Tkachenko, Yaroslav L. Kobzar, Olha G. Purikova, Alexander L. Tolstov, Oleg V. Shekera, Valery V. Shevchenko. Design, synthesis and photoisomerization behavior of novel azobenzene-based dyes containing different alkyl chains and isolation groups. Tetrahedron Letters 2016, 57 (49) , 5505-5510. https://doi.org/10.1016/j.tetlet.2016.10.101
    93. Dong‐Dong Han, Yong‐Lai Zhang, Jia‐Nan Ma, Yu‐Qing Liu, Bing Han, Hong‐Bo Sun. Light‐Mediated Manufacture and Manipulation of Actuators. Advanced Materials 2016, 28 (38) , 8328-8343. https://doi.org/10.1002/adma.201602211
    94. Zhongjie Ren, Shouke Yan. Polysiloxanes for optoelectronic applications. Progress in Materials Science 2016, 83 , 383-416. https://doi.org/10.1016/j.pmatsci.2016.07.004
    95. Sufang Guo, Tatsuya Okubo, Kazuyuki Kuroda, Atsushi Shimojima. A photoresponsive azobenzene-bridged cubic silsesquioxane network. Journal of Sol-Gel Science and Technology 2016, 79 (2) , 262-269. https://doi.org/10.1007/s10971-016-4074-4
    96. Bin Ni, He-Lou Xie, Jun Tang, Hai-Liang Zhang, Er-Qiang Chen. A self-healing photoinduced-deformable material fabricated by liquid crystalline elastomers using multivalent hydrogen bonds as cross-linkers. Chemical Communications 2016, 52 (67) , 10257-10260. https://doi.org/10.1039/C6CC04199J
    97. Jonas G. Croissant, Xavier Cattoën, Jean-Olivier Durand, Michel Wong Chi Man, Niveen M. Khashab. Organosilica hybrid nanomaterials with a high organic content: syntheses and applications of silsesquioxanes. Nanoscale 2016, 8 (48) , 19945-19972. https://doi.org/10.1039/C6NR06862F
    98. Mohamed Gamal Mohamed, Jia-Huei Tu, Shih-Hung Huang, Yeo-Wan Chiang, Shiao-Wei Kuo. Hydrogen bonding interactions affect the hierarchical self-assembly and secondary structures of comb-like polypeptide supramolecular complexes displaying photoresponsive behavior. RSC Advances 2016, 6 (56) , 51456-51469. https://doi.org/10.1039/C6RA07907E
    Download PDF
    Go to Journal of the American Chemical Society
    Get e-Alerts
    Get e-Alerts

    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2015, 137, 49, 15434–15440
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jacs.5b06172
    Published November 17, 2015
    Copyright © 2015 American Chemical Society
    Request reuse permissions

    Article Views

    7440

    Altmetric

    -

    Citations

    98
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.