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Tunable Heterogeneous Catalysis: N-Heterocyclic Carbenes as Ligands for Supported Heterogeneous Ru/K-Al2O3 Catalysts To Tune Reactivity and Selectivity

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Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149 Münster, Germany
‡ § ∥ Department of Chemistry, Graduate School of Science, §Research Center for Materials Science (RCMS), and Integrated Research Consortium on Chemical Sciences (IRCCS), Nagoya University, Furo-cho, Chikusa, Nagoya, Aichi 464-8602, Japan
Cite this: J. Am. Chem. Soc. 2016, 138, 34, 10718–10721
Publication Date (Web):August 8, 2016
https://doi.org/10.1021/jacs.6b03821
Copyright © 2016 American Chemical Society

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    Abstract

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    Here we report, for the first time, an extensive characterization of an N-heterocyclic carbene (NHC)-modified supported heterogeneous catalyst. The existence of the metal-carbene bond could be proven by 13C-SS-NMR experiments. Furthermore, it could be shown that the modification with NHCs does not structurally change the catalyst itself. The effect of the nature and the loading of the NHC on the activity and selectivity of the heterogeneous catalyst is presented by a hydrogenation study, finally leading to an NHC-enabled tunable heterogeneous catalyst for chemoselective hydrogenation.

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