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Photocatalytic Hydrogen-Evolution Cross-Couplings: Benzene C–H Amination and Hydroxylation

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    Photocatalytic Hydrogen-Evolution Cross-Couplings: Benzene C–H Amination and Hydroxylation
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    † Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, P.R. China
    ‡ Key Laboratory of Colloid and Interface Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P.R. China
    *[email protected]
    *[email protected]
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    Cite this: J. Am. Chem. Soc. 2016, 138, 32, 10080–10083
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    https://doi.org/10.1021/jacs.6b05498
    Published July 28, 2016
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    Abstract

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    We present a blueprint for aromatic C–H functionalization via a combination of photocatalysis and cobalt catalysis and describe the utility of this strategy for benzene amination and hydroxylation. Without any sacrificial oxidant, we could use the dual catalyst system to produce aniline directly from benzene and ammonia, and phenol from benzene and water, both with evolution of hydrogen gas under unusually mild conditions in excellent yields and selectivities.

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    Cite this: J. Am. Chem. Soc. 2016, 138, 32, 10080–10083
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