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Physical Organic Approach to Persistent, Cyclable, Low-Potential Electrolytes for Flow Battery Applications

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† Joint Center for Energy Storage Research, 9700 S. Cass Avenue, Argonne, Illinois 60439, United States
‡ Department of Chemistry, University of Michigan, 930 N. University Avenue, Ann Arbor, Michigan 48109, United States
§ Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United States
*[email protected]
*[email protected]
*[email protected]
Cite this: J. Am. Chem. Soc. 2017, 139, 8, 2924–2927
Publication Date (Web):February 21, 2017
https://doi.org/10.1021/jacs.7b00147
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Abstract

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The deployment of nonaqueous redox flow batteries for grid-scale energy storage has been impeded by a lack of electrolytes that undergo redox events at as low (anolyte) or high (catholyte) potentials as possible while exhibiting the stability and cycling lifetimes necessary for a battery device. Herein, we report a new approach to electrolyte design that uses physical organic tools for the predictive targeting of electrolytes that possess this combination of properties. We apply this approach to the identification of a new pyridinium-based anolyte that undergoes 1e– electrochemical charge–discharge cycling at low potential (−1.21 V vs Fc/Fc+) to a 95% state-of-charge without detectable capacity loss after 200 cycles.

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