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A Metallo-molecular Cage That Can Close the Apertures with Coordination Bonds

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† Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan
‡ Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan
*[email protected]
*[email protected]
Cite this: J. Am. Chem. Soc. 2017, 139, 13, 4631–4634
Publication Date (Web):March 14, 2017
https://doi.org/10.1021/jacs.7b00840
Copyright © 2017 American Chemical Society
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Abstract

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We designed a novel tricobalt(III) metallo-molecular cage in which its apertures can be closed with bifunctional ligands via coordination bonds. A closed-cage complex was easily formed by ligand exchange of its open-cage analogue. Guest uptake/release by the open-cage complex was sufficiently fast to quickly reach guest-binding equilibrium, while that by the closed-cage complex was extremely slow and took about 1 week to reach equilibrium. The guest uptake was retarded by at least 2000 times by introduction of the bifunctional ligands at the cage apertures.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.7b00840.

  • Synthetic procedure and characterization data, complexation studies, and crystallographic analysis of [LCo3(hda)3](TFPB)3, including Figures S1–S21 and Table S1 (PDF)

  • X-ray crystallographic data for [LCo3(hda)3](TFPB)3 (CIF)

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