logo

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2017, 139, 39, 13761-13769
RETURN TO ISSUEPREVArticleNEXT

Formation and Characterization of Hydrogen Boride Sheets Derived from MgB2 by Cation Exchange

View Author Information
†Institute of Materials Science, Graduate School of Pure and Applied Sciences, ‡Division of Physics, Faculty of Pure and Applied Sciences, §College of Engineering Sciences, ∥Technical Service Office for Pure and Applied Sciences, Faculty of Pure and Applied Sciences, and ⊥Division of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8573, Japan
# WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
∇ International Center for Young Scientists, National Institute for Materials Science, Tsukuba 305-0047, Japan
○ International Center for Materials Nanoarchitectonics, National Institute for Materials Science, Tsukuba 305-0044, Japan
◆ Department of Materials Science and Engineering, Tokyo Institute of Technology, Tokyo 152-8552, Japan
Laboratory for Materials and Structures, Tokyo Institute of Technology, Yokohama 226-8503, Japan
■ Mathematics for Advanced Materials-OIL, AIST-Tohoku University, Sendai 980-8577, Japan
▲ Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), and Center for Integrated Research in Fundamental Science and Engineering (CiRfSE), University of Tsukuba, Tsukuba 305-8571, Japan
◇ Materials Research Center for Element Strategy, Tokyo Institute of Technology, Yokohama 226-8503, Japan
*[email protected]
Cite this: J. Am. Chem. Soc. 2017, 139, 39, 13761–13769
Publication Date (Web):September 19, 2017
https://doi.org/10.1021/jacs.7b06153
Copyright © 2017 American Chemical Society
RIGHTS & PERMISSIONS
Article Views
4423
Altmetric
-
Citations
65
LEARN ABOUT THESE METRICS

Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.

Read OnlinePDF (5 MB)
Get e-Alerts
Supporting Info (1)»
SUBJECTS:

Abstract

Abstract Image

Two-dimensional (2D) materials are promising for applications in a wide range of fields because of their unique properties. Hydrogen boride sheets, a new 2D material recently predicted from theory, exhibit intriguing electronic and mechanical properties as well as hydrogen storage capacity. Here, we report the experimental realization of 2D hydrogen boride sheets with an empirical formula of H1B1, produced by exfoliation and complete ion-exchange between protons and magnesium cations in magnesium diboride (MgB2) with an average yield of 42.3% at room temperature. The sheets feature an sp2-bonded boron planar structure without any long-range order. A hexagonal boron network with bridge hydrogens is suggested as the possible local structure, where the absence of long-range order was ascribed to the presence of three different anisotropic domains originating from the 2-fold symmetry of the hydrogen positions against the 6-fold symmetry of the boron networks, based on X-ray diffraction, X-ray atomic pair distribution functions, electron diffraction, transmission electron microscopy, photo absorption, core-level binding energy data, infrared absorption, electron energy loss spectroscopy, and density functional theory calculations. The established cation-exchange method for metal diboride opens new avenues for the mass production of several types of boron-based 2D materials by countercation selection and functionalization.

Supporting Information

ARTICLE SECTIONS
Jump To

The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.7b06153.

  • Formation and separation of the byproduct B(OH)3, Figures S1–S13, Table S1, and supplementary references (PDF)

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Cited By

This article is cited by 66 publications.

  1. Rameshwar L. Kumawat, Milan Kumar Jena, Biswarup Pathak. Individual Identification of Amino Acids on an Atomically Thin Hydrogen Boride System Using Electronic Transport Calculations. The Journal of Physical Chemistry C 2020, 124 (49) , 27194-27202. https://doi.org/10.1021/acs.jpcc.0c08545
  2. Y.-S. Liu, K. G. Ray, M. Jørgensen, T. M. Mattox, D. F. Cowgill, H. V. Eshelman, A. M. Sawvel, J. L. Snider, W. York, P. Wijeratne, A. L. Pham, H. Gunda, S. Li, T. W. Heo, S. Kang, T. R. Jensen, V. Stavila, B. C. Wood, L. E. Klebanoff. Nanoscale Mg–B via Surfactant Ball Milling of MgB2: Morphology, Composition, and Improved Hydrogen Storage Properties. The Journal of Physical Chemistry C 2020, 124 (39) , 21761-21771. https://doi.org/10.1021/acs.jpcc.0c05142
  3. Qiyuan Zhou, Hongfeng Zhan, Bo Chen, Hai Li, Zhendong Huang, Yanwen Ma, Hua Zhang, Shaozhou Li, Xiao Huang, Wei Huang. Imparting Boron Nanosheets with Ambient Stability through Methyl Group Functionalization for Mechanistic Investigation of Their Lithiation Process. ACS Applied Materials & Interfaces 2020, 12 (20) , 23370-23377. https://doi.org/10.1021/acsami.0c05236
  4. Rick W. Dorn, Matthew J. Ryan, Tae-Hoon Kim, Tian Wei Goh, Amrit Venkatesh, Patrick M. Heintz, Lin Zhou, Wenyu Huang, Aaron J. Rossini. Identifying the Molecular Edge Termination of Exfoliated Hexagonal Boron Nitride Nanosheets with Solid-State NMR Spectroscopy and Plane-Wave DFT Calculations. Chemistry of Materials 2020, 32 (7) , 3109-3121. https://doi.org/10.1021/acs.chemmater.0c00104
  5. Zen Maeno, Shunsaku Yasumura, Xiaopeng Wu, Mengwen Huang, Chong Liu, Takashi Toyao, Ken-ichi Shimizu. Isolated Indium Hydrides in CHA Zeolites: Speciation and Catalysis for Nonoxidative Dehydrogenation of Ethane. Journal of the American Chemical Society 2020, 142 (10) , 4820-4832. https://doi.org/10.1021/jacs.9b13865
  6. Asahi Fujino, Shin-ichi Ito, Taiga Goto, Ryota Ishibiki, Junko N. Kondo, Tadahiro Fujitani, Junji Nakamura, Hideo Hosono, Takahiro Kondo. Hydrogenated Borophene Shows Catalytic Activity as Solid Acid. ACS Omega 2019, 4 (9) , 14100-14104. https://doi.org/10.1021/acsomega.9b02020
  7. Priyanka Ganguly, Moussab Harb, Zhen Cao, Luigi Cavallo, Ailish Breen, Saoirse Dervin, Dionysios D. Dionysiou, Suresh C. Pillai. 2D Nanomaterials for Photocatalytic Hydrogen Production. ACS Energy Letters 2019, 4 (7) , 1687-1709. https://doi.org/10.1021/acsenergylett.9b00940
  8. Pan Xiang, Xianfei Chen, Beibei Xiao, Zhiming M. Wang. Highly Flexible Hydrogen Boride Monolayers as Potassium-Ion Battery Anodes for Wearable Electronics. ACS Applied Materials & Interfaces 2019, 11 (8) , 8115-8125. https://doi.org/10.1021/acsami.8b22214
  9. Saroj Kumar Das, Kabeer Jasuja. Chemical Exfoliation of Layered Magnesium Diboride To Yield Functionalized Nanosheets and Nanoaccordions for Potential Flame Retardant Applications. ACS Applied Nano Materials 2018, 1 (4) , 1612-1622. https://doi.org/10.1021/acsanm.8b00101
  10. Yaser Bahari, Bohayra Mortazavi, Ali Rajabpour, Xiaoying Zhuang, Timon Rabczuk. Application of two-dimensional materials as anodes for rechargeable metal-ion batteries: A comprehensive perspective from density functional theory simulations. Energy Storage Materials 2021, 35 , 203-282. https://doi.org/10.1016/j.ensm.2020.11.004
  11. Josep M. Oliva-Enrich, Ibon Alkorta, José Elguero, Maxime Ferrer, José I. Burgos. On the 3D → 2D Isomerization of Hexaborane(12). Chemistry 2021, 3 (1) , 28-38. https://doi.org/10.3390/chemistry3010003
  12. Nontawat Ploysongsri, Viwat Vchirawongkwin, Vithaya Ruangpornvisuti. Hydrogen boride nanotubes and their C, N, O decoration and doping derivatives as materials for hydrogen-containing gases storage and sensing: A SCC–DFTB study. Vacuum 2021, 125 , 110140. https://doi.org/10.1016/j.vacuum.2021.110140
  13. Takahiro Kondo, Iwao Matsuda. Chemically Modified Borophene. 2021,,, 89-119. https://doi.org/10.1007/978-3-030-49999-0_5
  14. , . 2D Boron: Boraphene, Borophene, Boronene. 2021,,https://doi.org/10.1007/978-3-030-49999-0
  15. Asahi Fujino, Shin-ichi Ito, Taiga Goto, Ryota Ishibiki, Ryota Osuga, Junko N. Kondo, Tadahiro Fujitani, Junji Nakamura, Hideo Hosono, Takahiro Kondo. Ethanol–ethylene conversion mechanism on hydrogen boride sheets probed by in situ infrared absorption spectroscopy. Physical Chemistry Chemical Physics 2021, 119 https://doi.org/10.1039/D0CP03079A
  16. Volodymyr Gvozdetskyi, Yang Sun, Xin Zhao, Gourab Bhaskar, Scott L. Carnahan, Colin P. Harmer, Feng Zhang, Raquel A. Ribeiro, Paul C. Canfield, Aaron J. Rossini, Cai-Zhuang Wang, Kai-Ming Ho, Julia V. Zaikina. Lithium nickel borides: evolution of [NiB] layers driven by Li pressure. Inorganic Chemistry Frontiers 2021, 63 https://doi.org/10.1039/D0QI01150A
  17. Chuang Hou, Guo’an Tai, Bo Liu, Zenghui Wu, Yonghe Yin. Borophene-graphene heterostructure: Preparation and ultrasensitive humidity sensing. Nano Research 2020, 5 https://doi.org/10.1007/s12274-020-3232-8
  18. Akihiko Hirata. Local structure analysis of amorphous materials by angstrom-beam electron diffraction. Microscopy 2020, 199 https://doi.org/10.1093/jmicro/dfaa075
  19. Rishabh Patidar, Harini Gunda, Akash K. Varma, Ramchandra Gawas, Saroj Kumar Das, Kabeer Jasuja. Co-solvent exfoliation of layered titanium diboride into few-layer-thick nanosheets. Ceramics International 2020, 46 (18) , 28324-28331. https://doi.org/10.1016/j.ceramint.2020.07.336
  20. Josep M. Oliva‐Enrich, Takahiro Kondo, Ibon Alkorta, José Elguero, Douglas J. Klein. Diborane Concatenation Leads to New Planar Boron Chemistry. ChemPhysChem 2020, 21 (21) , 2460-2467. https://doi.org/10.1002/cphc.202000554
  21. Josep M. Oliva-Enrich, Ibon Alkorta, José Elguero. Hybrid Boron-Carbon Chemistry. Molecules 2020, 25 (21) , 5026. https://doi.org/10.3390/molecules25215026
  22. Reiya Kawamura, Akira Yamaguchi, Chika Shimada, Ryota Ishibiki, Takeshi Fujita, Takahiro Kondo, Masahiro Miyauchi. Acid Assisted Synthesis of HB Sheets through Exfoliation of MgB 2 Bulk in Organic Media. Chemistry Letters 2020, 49 (10) , 1194-1196. https://doi.org/10.1246/cl.200203
  23. Saisai Gao, Yang Zhang, Jinglei Bi, Bin Wang, Chao Li, Jiamei Liu, Chuncai Kong, Sen Yang, Shengchun Yang. 2D hydrogenated boride as a reductant and stabilizer for in situ synthesis of ultrafine and surfactant-free carbon supported noble metal electrocatalysts with enhanced activity and stability. Journal of Materials Chemistry A 2020, 8 (36) , 18856-18862. https://doi.org/10.1039/D0TA06542K
  24. Tingting Wang, Huide Wang, Zongkui Kou, Weiyuan Liang, Xiaoling Luo, Francis Verpoort, Yu‐Jia Zeng, Han Zhang. Xenes as an Emerging 2D Monoelemental Family: Fundamental Electrochemistry and Energy Applications. Advanced Functional Materials 2020, 30 (36) , 2002885. https://doi.org/10.1002/adfm.202002885
  25. Saju K. John, Aji A. Anappara. Facile synthesis of aqueous-dispersed luminescent nanosheets from non-layered lanthanum hexaboride. RSC Advances 2020, 10 (53) , 31788-31793. https://doi.org/10.1039/D0RA05611A
  26. Xiao Tang, Jinxing Gu, Jing Shang, Zhongfang Chen, Liangzhi Kou. Double‐sided surface functionalization: An effective approach to stabilize and modulate the electronic structure of graphene‐like borophene. InfoMat 2020, https://doi.org/10.1002/inf2.12126
  27. Takahiro KONDO, Masahiro MIYAUCHI. Hydrogen Generation Induced by Ultraviolet Light Irradiation on Hydrogen Boride Sheets. Vacuum and Surface Science 2020, 63 (7) , 352-357. https://doi.org/10.1380/vss.63.352
  28. Shin-ichi Ito, Toru Hirabayashi, Ryota Ishibiki, Reiya Kawamura, Taiga Goto, Takeshi Fujita, Akira Yamaguchi, Hideo Hosono, Masahiro Miyauchi, Takahiro Kondo. Hydrogen Boride Sheets as Reductants and the Formation of Nanocomposites with Metal Nanoparticles. Chemistry Letters 2020, 49 (7) , 789-793. https://doi.org/10.1246/cl.200206
  29. Chuang Hou, Guoan Tai, Jinqian Hao, Lihang Sheng, Bo Liu, Zitong Wu. Ultrastable Crystalline Semiconducting Hydrogenated Borophene. Angewandte Chemie 2020, 132 (27) , 10911-10917. https://doi.org/10.1002/ange.202001045
  30. Chuang Hou, Guoan Tai, Jinqian Hao, Lihang Sheng, Bo Liu, Zitong Wu. Ultrastable Crystalline Semiconducting Hydrogenated Borophene. Angewandte Chemie International Edition 2020, 59 (27) , 10819-10825. https://doi.org/10.1002/anie.202001045
  31. Y.-M. Chang, H.-W. Lin, L.-J. Li, H.-Y. Chen. Two-dimensional materials as anodes for sodium-ion batteries. Materials Today Advances 2020, 6 , 100054. https://doi.org/10.1016/j.mtadv.2020.100054
  32. N. T. Cuong, I. Tateishi, M. Cameau, M. Niibe, N. Umezawa, B. Slater, K. Yubuta, T. Kondo, M. Ogata, S. Okada, I. Matsuda. Topological Dirac nodal loops in nonsymmorphic hydrogenated monolayer boron. Physical Review B 2020, 101 (19) https://doi.org/10.1103/PhysRevB.101.195412
  33. Liumei Su, Xing Fan, Cong Wang, Qiong Wu, Yu Li, Han Zhang, Heping Xie. Advances in photonics of recently developed Xenes. Nanophotonics 2020, 9 (7) , 1621-1649. https://doi.org/10.1515/nanoph-2019-0561
  34. Fan Bai, Liang Xu, Xiaoying Zhai, Xu Chen, Wensheng Yang. Vacancy in Ultrathin 2D Nanomaterials toward Sustainable Energy Application. Advanced Energy Materials 2020, 10 (11) , 1902107. https://doi.org/10.1002/aenm.201902107
  35. Xinyuan Li, Muwei Ji, Hongbo Li, Hongzhi Wang, Meng Xu, Hongpan Rong, Jing Wei, Jia Liu, Jiajia Liu, Wenxing Chen, Caizhen Zhu, Jin Wang, Jiatao Zhang. Cation/Anion Exchange Reactions toward the Syntheses of Upgraded Nanostructures: Principles and Applications. Matter 2020, 2 (3) , 554-586. https://doi.org/10.1016/j.matt.2019.12.024
  36. Shao-Gang Xu, Zhong-Jia Chen, Yu-Jun Zhao, Xiuwen Zhang, Hu Xu, Xiao-Bao Yang. Realizing graphene-like Dirac cones in triangular boron sheets by chemical functionalization. Journal of Materials Chemistry C 2020, 8 (8) , 2798-2805. https://doi.org/10.1039/C9TC06464H
  37. Dengfeng Li, Junfeng Gao, Peng Cheng, Jia He, Yan Yin, Yanxiao Hu, Lan Chen, Yuan Cheng, Jijun Zhao. 2D Boron Sheets: Structure, Growth, and Electronic and Thermal Transport Properties. Advanced Functional Materials 2020, 30 (8) , 1904349. https://doi.org/10.1002/adfm.201904349
  38. Satoshi Tominaka, Ryota Ishibiki, Asahi Fujino, Kohsaku Kawakami, Koji Ohara, Takuya Masuda, Iwao Matsuda, Hideo Hosono, Takahiro Kondo. Geometrical Frustration of B-H Bonds in Layered Hydrogen Borides Accessible by Soft Chemistry. Chem 2020, 6 (2) , 406-418. https://doi.org/10.1016/j.chempr.2019.11.006
  39. Xi-Meng Chen, Xuenian Chen. Chemical Syntheses of Two-Dimensional Boron Materials. Chem 2020, 6 (2) , 324-326. https://doi.org/10.1016/j.chempr.2020.01.001
  40. Junjie Wang, Tian-Nan Ye, Yutong Gong, Jiazhen Wu, Nanxi Miao, Tomofumi Tada, Hideo Hosono. Discovery of hexagonal ternary phase Ti2InB2 and its evolution to layered boride TiB. Nature Communications 2019, 10 (1) https://doi.org/10.1038/s41467-019-10297-8
  41. Reiya Kawamura, Nguyen Thanh Cuong, Takeshi Fujita, Ryota Ishibiki, Toru Hirabayashi, Akira Yamaguchi, Iwao Matsuda, Susumu Okada, Takahiro Kondo, Masahiro Miyauchi. Photoinduced hydrogen release from hydrogen boride sheets. Nature Communications 2019, 10 (1) https://doi.org/10.1038/s41467-019-12903-1
  42. Jia He, Dengfeng Li, Yan Ying, Chunbao Feng, Junjie He, Chengyong Zhong, Hangbo Zhou, Ping Zhou, Gang Zhang. Orbitally driven giant thermal conductance associated with abnormal strain dependence in hydrogenated graphene-like borophene. npj Computational Materials 2019, 5 (1) https://doi.org/10.1038/s41524-019-0183-2
  43. Volodymyr Gvozdetskyi, Gourab Bhaskar, Maria Batuk, Xin Zhao, Renhai Wang, Scott L. Carnahan, Michael P. Hanrahan, Raquel A. Ribeiro, Paul C. Canfield, Aaron J. Rossini, Cai‐Zhuang Wang, Kai‐Ming Ho, Joke Hadermann, Julia V. Zaikina. Computationally Driven Discovery of a Family of Layered LiNiB Polymorphs. Angewandte Chemie 2019, 131 (44) , 16002-16009. https://doi.org/10.1002/ange.201907499
  44. Volodymyr Gvozdetskyi, Gourab Bhaskar, Maria Batuk, Xin Zhao, Renhai Wang, Scott L. Carnahan, Michael P. Hanrahan, Raquel A. Ribeiro, Paul C. Canfield, Aaron J. Rossini, Cai‐Zhuang Wang, Kai‐Ming Ho, Joke Hadermann, Julia V. Zaikina. Computationally Driven Discovery of a Family of Layered LiNiB Polymorphs. Angewandte Chemie International Edition 2019, 58 (44) , 15855-15862. https://doi.org/10.1002/anie.201907499
  45. Naoki Uemura, Koun Shirai, Jens Kunstmann, Evgeny A Ekimov, Yuliya B Lebed. Hydrogenation, dehydrogenation of α -tetragonal boron and its transition to δ -orthorhombic boron. Journal of Physics: Materials 2019, 2 (4) , 045004. https://doi.org/10.1088/2515-7639/ab2c8d
  46. Pratap Vishnoi, K. Pramoda, C. N. R. Rao. 2D Elemental Nanomaterials Beyond Graphene. ChemNanoMat 2019, 5 (9) , 1062-1091. https://doi.org/10.1002/cnma.201900176
  47. Mingjian Fan, Yanyuan Wen, Dien Ye, Zhaokui Jin, Penghe Zhao, Danyang Chen, Xifeng Lu, Qianjun He. Acid‐Responsive H 2 ‐Releasing 2D MgB 2 Nanosheet for Therapeutic Synergy and Side Effect Attenuation of Gastric Cancer Chemotherapy. Advanced Healthcare Materials 2019, 8 (13) , 1900157. https://doi.org/10.1002/adhm.201900157
  48. Saju K. John, Aji A. Anappara. Aqueous dispersions of highly luminescent boron-rich nanosheets by the exfoliation of polycrystalline titanium diboride. New Journal of Chemistry 2019, 43 (25) , 9953-9960. https://doi.org/10.1039/C9NJ01502G
  49. Yipeng An, Yusheng Hou, Hui Wang, Jie Li, Ruqian Wu, Tianxing Wang, Haixia Da, Jutao Jiao. Unveiling the Electric-Current-Limiting and Photodetection Effect in Two-Dimensional Hydrogenated Borophene. Physical Review Applied 2019, 11 (6) https://doi.org/10.1103/PhysRevApplied.11.064031
  50. Bao Lei, Yu-Yang Zhang, Shi-Xuan Du. Band engineering of B 2 H 2 nanoribbons. Chinese Physics B 2019, 28 (4) , 046803. https://doi.org/10.1088/1674-1056/28/4/046803
  51. I. Tateishi, N. T. Cuong, C. A. S. Moura, M. Cameau, R. Ishibiki, A. Fujino, S. Okada, A. Yamamoto, M. Araki, S. Ito, S. Yamamoto, M. Niibe, T. Tokushima, D. E. Weibel, T. Kondo, M. Ogata, I. Matsuda. Semimetallicity of free-standing hydrogenated monolayer boron from MgB 2 . Physical Review Materials 2019, 3 (2) https://doi.org/10.1103/PhysRevMaterials.3.024004
  52. Chengyong Zhong, Weikang Wu, Junjie He, Guangqian Ding, Yi Liu, Dengfeng Li, Shengyuan A. Yang, Gang Zhang. Two-dimensional honeycomb borophene oxide: strong anisotropy and nodal loop transformation. Nanoscale 2019, 11 (5) , 2468-2475. https://doi.org/10.1039/C8NR08729F
  53. Masoud Shahrokhi. Can fluorine and chlorine functionalization stabilize the graphene like borophene?. Computational Materials Science 2019, 156 , 56-66. https://doi.org/10.1016/j.commatsci.2018.09.045
  54. Satoshi Tominaka, Ryota Ishibiki, Asahi Fujino, Kohsaku Kawakami, Koji Ohara, Iwao Matsuda, Hideo Hosono, Takahiro Kondo. Electrical Conduction in Curved Hexagonal Borophane. SSRN Electronic Journal 2019, https://doi.org/10.2139/ssrn.3327224
  55. Long Chen, Xianfei Chen, Chao Duan, Yi Huang, Qian Zhang, Beibei Xiao. Reversible hydrogen storage in pristine and Li decorated 2D boron hydride. Physical Chemistry Chemical Physics 2018, 20 (48) , 30304-30311. https://doi.org/10.1039/C8CP05846F
  56. Asha Liza James, Shikha Khandelwal, Arnab Dutta, Kabeer Jasuja. Boron based nanosheets as reducing templates in aqueous solutions: towards novel nanohybrids with gold nanoparticles and graphene. Nanoscale 2018, 10 (44) , 20514-20518. https://doi.org/10.1039/C8NR06283H
  57. Azhar Alowasheeir, Satoshi Tominaka, Yusuke Ide, Yusuke Yamauchi, Yoshitaka Matsushita. Two-dimensional cyano-bridged coordination polymer of Mn(H 2 O) 2 [Ni(CN) 4 ]: structural analysis and proton conductivity measurements upon dehydration and rehydration. CrystEngComm 2018, 20 (42) , 6713-6720. https://doi.org/10.1039/C8CE01400K
  58. Bing Ni, Yuang Shi, Xun Wang. The Sub-Nanometer Scale as a New Focus in Nanoscience. Advanced Materials 2018, 30 (43) , 1802031. https://doi.org/10.1002/adma.201802031
  59. Geoffrey Ozin, Todd Siler. Catalyst: New Materials Discovery: Machine-Enhanced Human Creativity. Chem 2018, 4 (6) , 1183-1189. https://doi.org/10.1016/j.chempr.2018.05.011
  60. Meysam Makaremi, Bohayra Mortazavi, Chandra Veer Singh. 2D Hydrogenated graphene-like borophene as a high capacity anode material for improved Li/Na ion batteries: A first principles study. Materials Today Energy 2018, 8 , 22-28. https://doi.org/10.1016/j.mtener.2018.02.003
  61. Chi-Cheng Lee, Baojie Feng, Marie D'angelo, Ryu Yukawa, Ro-Ya Liu, Takahiro Kondo, Hiroshi Kumigashira, Iwao Matsuda, Taisuke Ozaki. Peculiar bonding associated with atomic doping and hidden honeycombs in borophene. Physical Review B 2018, 97 (7) https://doi.org/10.1103/PhysRevB.97.075430
  62. Bohayra Mortazavi, Meysam Makaremi, Masoud Shahrokhi, Mostafa Raeisi, Chandra Veer Singh, Timon Rabczuk, Luiz Felipe C. Pereira. Borophene hydride: a stiff 2D material with high thermal conductivity and attractive optical and electronic properties. Nanoscale 2018, 10 (8) , 3759-3768. https://doi.org/10.1039/C7NR08725J
  63. A. Mogulkoc, Y. Mogulkoc, D. Kecik, E. Durgun. The effect of strain and functionalization on the optical properties of borophene. Physical Chemistry Chemical Physics 2018, 20 (32) , 21043-21050. https://doi.org/10.1039/C8CP03594F
  64. Vivekanand Shukla, Rafael B. Araujo, Naresh K. Jena, Rajeev Ahuja. Borophene's tryst with stability: exploring 2D hydrogen boride as an electrode for rechargeable batteries. Physical Chemistry Chemical Physics 2018, 20 (34) , 22008-22016. https://doi.org/10.1039/C8CP03686A
  65. Vivekanand Shukla, Anton Grigoriev, Naresh K. Jena, Rajeev Ahuja. Strain controlled electronic and transport anisotropies in two-dimensional borophene sheets. Physical Chemistry Chemical Physics 2018, 20 (35) , 22952-22960. https://doi.org/10.1039/C8CP03815E
  66. Takahiro Kondo. Recent progress in boron nanomaterials. Science and Technology of Advanced Materials 2017, 18 (1) , 780-804. https://doi.org/10.1080/14686996.2017.1379856

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

OOPS

You have to login with your ACS ID befor you can login with your Mendeley account.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect

This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy.

CONTINUE