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Electrocatalytic CO2 Reduction by Imidazolium-Functionalized Molecular Catalysts

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† Department of Chemistry, Texas A&M University, 3255 TAMU, College Station, Texas 77843, United States
‡ School of Chemistry and Biochemistry, Thapar University, Patiala, Punjab 147004, India
§ Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, Cerdanyola del Vallès, 08193 Barcelona, Catalonia, Spain
*[email protected]
Cite this: J. Am. Chem. Soc. 2017, 139, 40, 13993–13996
Publication Date (Web):September 18, 2017
https://doi.org/10.1021/jacs.7b07709
Copyright © 2017 American Chemical Society
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Abstract

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We present the first examples of CO2 electro-reduction catalysts that feature charged imidazolium groups in the secondary coordination sphere. The functionalized Lehn-type catalysts display significant differences in their redox properties and improved catalytic activities as compared to the conventional reference catalyst. Our results suggest that the incorporated imidazolium moieties do not solely function as a charged tag but also alter mechanistic aspects of catalysis.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.7b07709.

  • Experimental and computational details, including Figures S1–S51 and Tables S1–S4 (PDF)

  • X-ray crystallographic data for 1PF6 (CIF)

  • X-ray crystallographic data for 2PF6 (CIF)

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