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Well-Dispersed Ruthenium in Mesoporous Crystal TiO2 as an Advanced Electrocatalyst for Hydrogen Evolution Reaction

  • Shuying Nong
    Shuying Nong
    State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China
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    • , 
  • Wujie Dong
    Wujie Dong
    State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China
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    • , 
  • Junwen Yin
    Junwen Yin
    Beijing Computational Science Research Center, Beijing 100084, PR China
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    • , 
  • Bowei Dong
    Bowei Dong
    State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China
    More by Bowei Dong
    • , 
  • Yue Lu
    Yue Lu
    Institute of Microstructure and Properties of Advanced Materials, Beijing University of Technology, Beijing 100124, PR China
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    • , 
  • Xiaotao Yuan
    Xiaotao Yuan
    State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China
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    • , 
  • Xin Wang
    Xin Wang
    State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China
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    • , 
  • Kejun Bu
    Kejun Bu
    State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, PR China
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    • , 
  • Mingyang Chen
    Mingyang Chen
    Beijing Computational Science Research Center, Beijing 100084, PR China
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    Orcidhttp://orcid.org/0000-0002-9866-8695
    • , 
  • Shangda Jiang
    Shangda Jiang
    State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China
    More by Shangda Jiang
    Orcidhttp://orcid.org/0000-0003-0204-9601
    • , 
  • Li-Min Liu*
    Li-Min Liu
    Beijing Computational Science Research Center, Beijing 100084, PR China
    School of Physics, Beihang University, Beijing 100191, PR China
    *[email protected]
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    • , 
  • Manling Sui*
    Manling Sui
    Institute of Microstructure and Properties of Advanced Materials, Beijing University of Technology, Beijing 100124, PR China
    *[email protected]
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    • , and 
  • Fuqiang Huang*
    Fuqiang Huang
    State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China
    State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, PR China
    *[email protected]
    More by Fuqiang Huang
    Orcidhttp://orcid.org/0000-0001-7727-0488
Cite this: J. Am. Chem. Soc. 2018, 140, 17, 5719–5727
Publication Date (Web):April 12, 2018
https://doi.org/10.1021/jacs.7b13736
Copyright © 2018 American Chemical Society
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Abstract

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TiO2 mesoporous crystal has been prepared by one-step corroding process via an oriented attachment (OA) mechanism with SrTiO3 as precursor. High resolution transmission electron microscopy (HRTEM) and nitrogen adsorption–desorption isotherms confirm its mesoporous crystal structure. Well-dispersed ruthenium (Ru) in the mesoporous nanocrystal TiO2 can be attained by the same process using Ru-doped precursor SrTi1–xRuxO3. Ru is doped into lattice of TiO2, which is identified by HRTEM and super energy dispersive spectrometer (super-EDS) elemental mapping. X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance spectroscopy (EPR) suggest the pentavalent Ru but not tetravalent, while partial Ti in TiO2 accept an electron from Ru and become Ti3+, which is observed for the first time. This Ru-doped TiO2 performs high activity for electrocatalytic hydrogen evolution reaction (HER) in alkaline solution. First-principles calculations simulate the HER process and prove TiO2:Ru with Ru5+ and Ti3+ holds high HER activity with appropriate hydrogen-adsorption Gibbs free energies (ΔGH).

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.7b13736.

  • Figures giving details of SEM image of SrTiO3, XRD patterns of precursors and intermediate TiO2 NPs, XRD and HER details for TiO2:Ru and R-TiO2:Ru, stability of TiO2:Ru, R-TiO2:Ru, Tafel slopes of 5% RuO2/TiO2 and Cp-TiO2:Ru (5%) (PDF)

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  3. Zhikun Peng, Jiameng Liu, Bin Hu, Yongpeng Yang, Yuqi Guo, Baojun Li, Li Li, Zhihong Zhang, Bingbing Cui, Linghao He, Miao Du. Surface Engineering on Nickel–Ruthenium Nanoalloys Attached Defective Carbon Sites as Superior Bifunctional Electrocatalysts for Overall Water Splitting. ACS Applied Materials & Interfaces 2020, 12 (12) , 13842-13851. https://doi.org/10.1021/acsami.9b21827
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  5. Jing-Qi Chi, Xin-Yu Zhang, Xue Ma, Bin Dong, Jia-Qi Zhang, Bao-Yu Guo, Min Yang, Lei Wang, Yong-Ming Chai, Chenguang Liu. Interface Charge Engineering of Ultrafine Ru/Ni2P Nanoparticles Encapsulated in N,P-Codoped Hollow Carbon Nanospheres for Efficient Hydrogen Evolution. ACS Sustainable Chemistry & Engineering 2019, 7 (21) , 17714-17722. https://doi.org/10.1021/acssuschemeng.9b04025
  6. Jie Yu, Qijiao He, Guangming Yang, Wei Zhou, Zongping Shao, Meng Ni. Recent Advances and Prospective in Ruthenium-Based Materials for Electrochemical Water Splitting. ACS Catalysis 2019, 9 (11) , 9973-10011. https://doi.org/10.1021/acscatal.9b02457
  7. Mengjiao Wang, Zhiya Dang, Mirko Prato, Urko Petralanda, Ivan Infante, Dipak V. Shinde, Luca De Trizio, Liberato Manna. Ruthenium-Decorated Cobalt Selenide Nanocrystals for Hydrogen Evolution. ACS Applied Nano Materials 2019, 2 (9) , 5695-5703. https://doi.org/10.1021/acsanm.9b01205
  8. Xiaotong Jin, Kangkang Yuan, Xinqiang Wang, Guanghui Zhang, Luyi Zhu, Dong Xu. High-Efficient Photocatalytic Performance under Visible Light of Functionalized TiO2 Nanofibers via Steam and Pressure Co-Modification. The Journal of Physical Chemistry C 2019, 123 (28) , 17306-17317. https://doi.org/10.1021/acs.jpcc.9b03528
  9. Xinhong Chen, Qing Li, Qijun Che, Yashi Chen, Ya Tan, Xi Xu. Self-Supported Ni/NiSPx Microdendrite Structure for Highly Efficient and Stable Overall Water Splitting in Simulated Industrial Environment. ACS Sustainable Chemistry & Engineering 2019, 7 (13) , 11778-11786. https://doi.org/10.1021/acssuschemeng.9b02061
  10. Shu-Wen Sun, Gao-Feng Wang, Yue Zhou, Feng-Bin Wang, Xing-Hua Xia. High-Performance [email protected] Electrocatalyst for Hydrogen Evolution Reaction in Both Acidic and Alkaline Solutions. ACS Applied Materials & Interfaces 2019, 11 (21) , 19176-19182. https://doi.org/10.1021/acsami.9b04255
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  12. Yuuki Sugawara, Keigo Kamata, Takeo Yamaguchi. Extremely Active Hydrogen Evolution Catalyst Electrochemically Generated from a Ruthenium-Based Perovskite-Type Precursor. ACS Applied Energy Materials 2019, 2 (2) , 956-960. https://doi.org/10.1021/acsaem.8b01525
  13. Lijun Zheng, Shizheng Zheng, Hongrui Wei, Lingling Du, Zhengyou Zhu, Jian Chen, Dachi Yang. Palladium/Bismuth/Copper Hierarchical Nano-Architectures for Efficient Hydrogen Evolution and Stable Hydrogen Detection. ACS Applied Materials & Interfaces 2019, 11 (6) , 6248-6256. https://doi.org/10.1021/acsami.8b19770
  14. Jian Yuan, Chao Wang, Yanyu Liu, Ping Wu, Wei Zhou. Tunable Photocatalytic HER Activity of Single-Layered TiO2 Nanosheets with Transition-Metal Doping and Biaxial Strain. The Journal of Physical Chemistry C 2019, 123 (1) , 526-533. https://doi.org/10.1021/acs.jpcc.8b09848
  15. Yao Xiao, Wengang Liu, Zhou Zhang, Jian Liu. Controllable synthesis for highly dispersed ruthenium clusters confined in nitrogen doped carbon for efficient hydrogen evolution. Journal of Colloid and Interface Science 2020, 571 , 205-212. https://doi.org/10.1016/j.jcis.2020.03.048
  16. Zitao Zhang, Song Gao, Zibin Liang, Kexin Zhang, Huichuan Guo, Yanqun Tang, Tianjie Qiu, Hassina Tabassum, Jinming Shi, Wei Meng, Ruqiang Zou. Double‐Solvent Induced Ultrafine Ruthenium Nanoparticles on Porous Carbon for Highly Efficient Hydrogen Evolution Reaction. ChemCatChem 2020, 12 (10) , 2880-2885. https://doi.org/10.1002/cctc.202000067
  17. Yan Liu, Juanjuan Huo, Jiaojiao Guo, Li Lu, Ziyan Shen, Weihua Chen, Chuntai Liu, Hao Liu. Hierarchical Porous Molybdenum Carbide Based Nanomaterials for Electrocatalytic Hydrogen Production. Frontiers in Chemistry 2020, 8 https://doi.org/10.3389/fchem.2020.00426
  18. Tanglue Feng, Guangtao Yu, Songyuan Tao, Shoujun Zhu, Ruiqi Ku, Ran Zhang, Qingsen Zeng, Mingxi Yang, Yixin Chen, Weihua Chen, Wei Chen, Bai Yang. A highly efficient overall water splitting ruthenium-cobalt alloy electrocatalyst across a wide pH range via electronic coupling with carbon dots. Journal of Materials Chemistry A 2020, 8 (19) , 9638-9645. https://doi.org/10.1039/D0TA02496A
  19. Guoxin Zhuang, Yawen Chen, Zanyong Zhuang, Yan Yu, Jiaguo Yu. Oxygen vacancies in metal oxides: recent progress towards advanced catalyst design. Science China Materials 2020, 133 https://doi.org/10.1007/s40843-020-1305-6
  20. Baolin Yan, Dapeng Liu, Xilan Feng, Mingzhe Shao, Yu Zhang. Ru Nanoparticles Supported on Co-Embedded N-Doped Carbon Nanotubes as Efficient Electrocatalysts for Hydrogen Evolution in Basic Media. Chemical Research in Chinese Universities 2020, 27 https://doi.org/10.1007/s40242-020-0104-4
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  23. Yuanyuan Zhou, Zhenyang Xie, Jinxia Jiang, Jian Wang, Xiaoyun Song, Qian He, Wei Ding, Zidong Wei. Lattice-confined Ru clusters with high CO tolerance and activity for the hydrogen oxidation reaction. Nature Catalysis 2020, 3 (5) , 454-462. https://doi.org/10.1038/s41929-020-0446-9
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  31. Wenquan Wang, Yalong Shao, Zhikai Wang, Zijing Yang, Zhen Zhen, Zhonghua Zhang, Changming Mao, Xiaosong Guo, Guicun Li. Synthesis of Ru doped VN by a soft‐urea pathway as an Efficient Catalyst for hydrogen evolution. ChemElectroChem 2020, https://doi.org/10.1002/celc.202000072
  32. Rong Ding, Qian Chen, Qian Luo, Lingxi Zhou, Yi Wang, Yun Zhang, Guangyin Fan. Salt template-assisted in situ construction of Ru nanoclusters and porous carbon: excellent catalysts toward hydrogen evolution, ammonia-borane hydrolysis, and 4-nitrophenol reduction. Green Chemistry 2020, 22 (3) , 835-842. https://doi.org/10.1039/C9GC03986D
  33. Muhammad Sohail Riaz, Siwei Zhao, Chenlong Dong, Shuying Nong, Yantao Zhao, Muhammad Javed Iqbal, Fuqiang Huang. ZnO‐Templated Selenized and Phosphorized Cobalt‐Nickel Oxide Microcubes as Rapid Alkaline Water Oxidation Electrocatalysts. Chemistry – A European Journal 2020, 26 (6) , 1306-1313. https://doi.org/10.1002/chem.201903508
  34. Yuan Liu, Xue Li, Qinghua Zhang, Weidong Li, Yu Xie, Hanyu Liu, Lu Shang, Zhongyi Liu, Zhimin Chen, Lin Gu, Zhiyong Tang, Tierui Zhang, Siyu Lu. A General Route to Prepare Low‐Ruthenium‐Content Bimetallic Electrocatalysts for pH‐Universal Hydrogen Evolution Reaction by Using Carbon Quantum Dots. Angewandte Chemie 2020, 132 (4) , 1735-1743. https://doi.org/10.1002/ange.201913910
  35. Yuan Liu, Xue Li, Qinghua Zhang, Weidong Li, Yu Xie, Hanyu Liu, Lu Shang, Zhongyi Liu, Zhimin Chen, Lin Gu, Zhiyong Tang, Tierui Zhang, Siyu Lu. A General Route to Prepare Low‐Ruthenium‐Content Bimetallic Electrocatalysts for pH‐Universal Hydrogen Evolution Reaction by Using Carbon Quantum Dots. Angewandte Chemie International Edition 2020, 59 (4) , 1718-1726. https://doi.org/10.1002/anie.201913910
  36. Ligang Wang, Xinxuan Duan, Xijun Liu, Jing Gu, Rui Si, Yi Qiu, Yaming Qiu, Dier Shi, Fanhong Chen, Xiaoming Sun, Jianhua Lin, Junliang Sun. Atomically Dispersed Mo Supported on Metallic Co 9 S 8 Nanoflakes as an Advanced Noble‐Metal‐Free Bifunctional Water Splitting Catalyst Working in Universal pH Conditions. Advanced Energy Materials 2020, 10 (4) , 1903137. https://doi.org/10.1002/aenm.201903137
  37. Xiaoguang Wang, Minghui Sun, Muthu Murugananthan, Yanrong Zhang, Lizhi Zhang. Electrochemically self-doped WO3/TiO2 nanotubes for photocatalytic degradation of volatile organic compounds. Applied Catalysis B: Environmental 2020, 260 , 118205. https://doi.org/10.1016/j.apcatb.2019.118205
  38. Haifeng Gao, Chunyang Zhai, Chen Yuan, Zhao-Qing Liu, Mingshan Zhu. Snowflake-like Cu2S as visible-light-carrier for boosting Pd electrocatalytic ethylene glycol oxidation under visible light irradiation. Electrochimica Acta 2020, 330 , 135214. https://doi.org/10.1016/j.electacta.2019.135214
  39. Francisco Alcaide, Radostina V. Genova, Garbiñe Álvarez, Hans-Jürgen Grande, Óscar Miguel, Pere L. Cabot. Platinum-catalyzed Nb–doped TiO2 and Nb-doped TiO2 nanotubes for hydrogen generation in proton exchange membrane water electrolyzers. International Journal of Hydrogen Energy 2020, https://doi.org/10.1016/j.ijhydene.2020.01.057
  40. Zuohua Liu, Liang Wang, Li Li, Facheng Qiu, Xia Xiong, Changyuan Tao, Jun Du. Surfactant effect on controllable phase transformation and UV-shielding performance of titanium dioxide. Materials Chemistry and Physics 2020, 240 , 122079. https://doi.org/10.1016/j.matchemphys.2019.122079
  41. Xiaojun Zeng, Myeong Je Jang, Sung Mook Choi, Hyun-Seok Cho, Chang-Hee Kim, Nosang Vincent Myung, Yadong Yin. Single-crystalline CoFe nanoparticles encapsulated in N-doped carbon nanotubes as a bifunctional catalyst for water splitting. Materials Chemistry Frontiers 2020, 6 https://doi.org/10.1039/D0QM00126K
  42. Ke Chen, Shaofeng Deng, Yun Lu, Mingxing Gong, Yezhou Hu, Tonghui Zhao, Tao Shen, Deli Wang. . Chinese Chemical Letters 2020,,https://doi.org/10.1016/j.cclet.2020.05.030
  43. Kunfeng Zhang, Yuxi Liu, Jiguang Deng, Lin Jing, Wenbo Pei, Zhuo Han, Xing Zhang, Hongxing Dai. Ru Nanoparticles Supported on Oxygen‐Deficient 3DOM BiVO 4 : High‐Performance Catalysts for the Visible‐Light‐Driven Selective Oxidation of Benzyl Alcohol. ChemCatChem 2019, 11 (24) , 6398-6407. https://doi.org/10.1002/cctc.201901540
  44. Tao Zhao, Pengpeng Qiu, Yuchi Fan, Jianping Yang, Wan Jiang, Lianjun Wang, Yonghui Deng, Wei Luo. Hierarchical Branched Mesoporous TiO 2 –SnO 2 Nanocomposites with Well‐Defined n–n Heterojunctions for Highly Efficient Ethanol Sensing. Advanced Science 2019, 6 (24) , 1902008. https://doi.org/10.1002/advs.201902008
  45. Jing Gao, Liu Yang, Di Wang, Dapeng Cao. Hollow Nanotube Ru/Cu 2+1 O Supported on Copper Foam as a Bifunctional Catalyst for Overall Water Splitting. Chemistry – A European Journal 2019, 44 https://doi.org/10.1002/chem.201904337
  46. Yachao Jin, Fuyi Chen, Jiali Wang, Roy L. Johnston. Tuning electronic and composition effects in ruthenium-copper alloy nanoparticles anchored on carbon nanofibers for rechargeable Li-CO2 batteries. Chemical Engineering Journal 2019, 375 , 121978. https://doi.org/10.1016/j.cej.2019.121978
  47. Zhigang Hu, Julien Mahin, Laura Torrente-Murciano. A MOF-templated approach for designing ruthenium–cesium catalysts for hydrogen generation from ammonia. International Journal of Hydrogen Energy 2019, 44 (57) , 30108-30118. https://doi.org/10.1016/j.ijhydene.2019.09.174
  48. Shuang Liu, Fei Ji, Xiaoyu Li, Xiaoli Pan, Shuyuan Chen, Xuefei Wang, Yanhua Zhang, Yong Men. Stick-like mesoporous titania loaded Pd as highly active and cost effective catalysts for hydrodebenzylation of hexabenzylhexaazaisowurtzitane (HBIW). Molecular Catalysis 2019, 477 , 110556. https://doi.org/10.1016/j.mcat.2019.110556
  49. Ying Wu, Zengxi Wei, Rui Xu, Yue Gong, Lin Gu, Jianmin Ma, Yan Yu. Boosting the rate capability of multichannel porous TiO2 nanofibers with well-dispersed Cu nanodots and Cu2+-doping derived oxygen vacancies for sodium-ion batteries. Nano Research 2019, 12 (9) , 2211-2217. https://doi.org/10.1007/s12274-018-2248-9
  50. Di Zu, Haiyang Wang, Sen Lin, Gang Ou, Hehe Wei, Shuqing Sun, Hui Wu. Oxygen-deficient metal oxides: Synthesis routes and applications in energy and environment. Nano Research 2019, 12 (9) , 2150-2163. https://doi.org/10.1007/s12274-019-2377-9
  51. Yongfei Wang, Hong Guo, Xudong Luo, Xin Liu, Zhizhi Hu, Lu Han, Zhiqiang Zhang. Nonsiliceous Mesoporous Materials: Design and Applications in Energy Conversion and Storage. Small 2019, 15 (32) , 1805277. https://doi.org/10.1002/smll.201805277
  52. Yajing Wang, Jiankang Wang, Taiping Xie, Qiuyin Zhu, Dan Zeng, Rong Li, Xiaodong Zhang, Songli Liu. Ru doping in Ni(OH)2 to accelerate water reduction kinetics for efficient hydrogen evolution reaction. Applied Surface Science 2019, 485 , 506-512. https://doi.org/10.1016/j.apsusc.2019.04.240
  53. Aizhu Wang, Lei Shen, Mingwen Zhao, Junru Wang, Weijia Zhou, Weifeng Li, Yuanping Feng, Hong Liu. Tungsten boride: a 2D multiple Dirac semimetal for the hydrogen evolution reaction. Journal of Materials Chemistry C 2019, 7 (29) , 8868-8873. https://doi.org/10.1039/C9TC01862J
  54. Jiawei Xia, Kapil Dhaka, Michael Volokh, Guiming Peng, Zhen Wu, Yongsheng Fu, Maytal Caspary Toroker, Xin Wang, Menny Shalom. Nickel phosphide decorated with trace amount of platinum as an efficient electrocatalyst for the alkaline hydrogen evolution reaction. Sustainable Energy & Fuels 2019, 3 (8) , 2006-2014. https://doi.org/10.1039/C9SE00221A
  55. Rajaram Narasimman, Manmohansingh Waldiya, Esakki Karthik, Indrajit Mukhopadhyay, Abhijit Ray. Transition Metal Dichalcogenide Anchored in 3D Nickel Framework with Graphene Support for Efficient Electrocatalytic Hydrogen Evolution. Advanced Sustainable Systems 2019, 3 (7) , 1800168. https://doi.org/10.1002/adsu.201800168
  56. Di Wang, Liu Yang, Huibing Liu, Dapeng Cao. Polyaniline-coated Ru/Ni(OH)2 nanosheets for hydrogen evolution reaction over a wide pH range. Journal of Catalysis 2019, 375 , 249-256. https://doi.org/10.1016/j.jcat.2019.06.008
  57. Rohit D. Chavan, Pankaj Yadav, Ajaysing Nimbalkar, Sangram P. Bhoite, Popatrao N. Bhosale, Chang Kook Hong. Ruthenium doped mesoporous titanium dioxide for highly efficient, hysteresis-free and stable perovskite solar cells. Solar Energy 2019, 186 , 156-165. https://doi.org/10.1016/j.solener.2019.04.098
  58. Min Cheng, Hongbo Geng, Yang Yang, Yufei Zhang, Cheng Chao Li. Optimization of the Hydrogen‐Adsorption Free Energy of Ru‐Based Catalysts towards High‐Efficiency Hydrogen Evolution Reaction at all pH. Chemistry – A European Journal 2019, 25 (36) , 8579-8584. https://doi.org/10.1002/chem.201900790
  59. Jiawei Xia, Michael Volokh, Guiming Peng, Yongsheng Fu, Xin Wang, Menny Shalom. Low‐Cost Porous Ruthenium Layer Deposited on Nickel Foam as a Highly Active Universal‐pH Electrocatalyst for the Hydrogen Evolution Reaction. ChemSusChem 2019, 12 (12) , 2780-2787. https://doi.org/10.1002/cssc.201900472
  60. X. Zeng, Y. Bai, S.M. Choi, L. Tong, R.M. Aleisa, Z. Li, X. Liu, R. Yu, N.V. Myung, Y. Yin. Mesoporous TiO2 nanospheres loaded with highly dispersed Pd nanoparticles for pH-universal hydrogen evolution reaction. Materials Today Nano 2019, 6 , 100038. https://doi.org/10.1016/j.mtnano.2019.100038
  61. Xiaofei Liu, Tian Leo Jin, Zachary D. Hood, Chengcheng Tian, Yanglong Guo, Wangcheng Zhan. Mechanochemically Assisted Synthesis of Ruthenium Clusters Embedded in Mesoporous Carbon for an Efficient Hydrogen Evolution Reaction. ChemElectroChem 2019, 6 (10) , 2719-2725. https://doi.org/10.1002/celc.201900618
  62. Jiadong Chen, Haiyan Wang, Yutong Gong, Yong Wang. Directly immobilizing a Ru–tannic acid linkage coordination complex on carbon cloth: an efficient and ultrastable catalyst for the hydrogen evolution reaction. Journal of Materials Chemistry A 2019, 7 (18) , 11038-11043. https://doi.org/10.1039/C9TA02680K
  63. Wenjing Yuan, Fuhua Zhang, Yaoyao Wu, Xiaotao Chen, Chihhsiang Fang, Chuanhao Li. Point-Defect-Rich Carbon Sheets as the High-Activity Catalyst Toward Oxygen Reduction and Hydrogen Evolution. Catalysts 2019, 9 (4) , 386. https://doi.org/10.3390/catal9040386
  64. Xiaofei Liu, Yanglong Guo, Wangcheng Zhan, Tian Jin. Ball Milling-Assisted Synthesis of Ultrasmall Ruthenium Phosphide for Efficient Hydrogen Evolution Reaction. Catalysts 2019, 9 (3) , 240. https://doi.org/10.3390/catal9030240
  65. Haiqing Wang, Huiling Liu, Yanchen Ji, Ruiqi Yang, Zengfu Zhang, Xun Wang, Hong Liu. Hybrid nanostructures of pit-rich TiO 2 nanocrystals with Ru loading and N doping for enhanced solar water splitting. Chemical Communications 2019, 55 (19) , 2781-2784. https://doi.org/10.1039/C8CC10093D
  66. Jinzhu Wu, Lixin Du, Yanbin Shao, Xiaohong Wu. Silicon quantum dots-assistant synthesis of mesoporous MoS2 3D frameworks (SiQDs-MoS2) with 1T and 2H phases for hydrogen evolution reaction. Materials Letters 2019, 236 , 124-127. https://doi.org/10.1016/j.matlet.2018.10.095
  67. Qiuju Li, Xu Zou, Xuan Ai, Hui Chen, Lei Sun, Xiaoxin Zou. Revealing Activity Trends of Metal Diborides Toward pH‐Universal Hydrogen Evolution Electrocatalysts with Pt‐Like Activity. Advanced Energy Materials 2018, 130 , 1803369. https://doi.org/10.1002/aenm.201803369
  68. Lei Zhang, Zhi-Jian Zhao, Mohammad Norouzi Banis, Lulu Li, Yang Zhao, Zhongxin Song, Zhiqiang Wang, Tsun-Kong Sham, Ruying Li, Matthew Zheng, Jinlong Gong, Xueliang Sun. Selective atomic layer deposition of RuO x catalysts on shape-controlled Pd nanocrystals with significantly enhanced hydrogen evolution activity. Journal of Materials Chemistry A 2018, 6 (47) , 24397-24406. https://doi.org/10.1039/C8TA08931K
  69. Kefeng Wang, Qi Chen, Yingyan Hu, Wei Wei, Songzhu Wang, Qi Shen, Peng Qu. Crystalline Ru 0.33 Se Nanoparticles-Decorated TiO 2 Nanotube Arrays for Enhanced Hydrogen Evolution Reaction. Small 2018, 14 (37) , 1802132. https://doi.org/10.1002/smll.201802132
  70. Yuan-Yuan Ma, Zhong-Ling Lang, Li-Kai Yan, Yong-Hui Wang, Hua-Qiao Tan, Kun Feng, Yu-Jian Xia, Jun Zhong, Yang Liu, Zhen-Hui Kang, Yang-Guang Li. Highly efficient hydrogen evolution triggered by a multi-interfacial Ni/WC hybrid electrocatalyst. Energy & Environmental Science 2018, 11 (8) , 2114-2123. https://doi.org/10.1039/C8EE01129J

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