ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Cyclic Penta-Twinned Rhodium Nanobranches as Superior Catalysts for Ethanol Electro-oxidation

  • Jiawei Zhang
    Jiawei Zhang
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
    More by Jiawei Zhang
  • Jinyu Ye
    Jinyu Ye
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
    More by Jinyu Ye
  • Qiyuan Fan
    Qiyuan Fan
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
    More by Qiyuan Fan
  • Yating Jiang
    Yating Jiang
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
    More by Yating Jiang
  • Yifan Zhu
    Yifan Zhu
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
    More by Yifan Zhu
  • Huiqi Li
    Huiqi Li
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
    More by Huiqi Li
  • Zhenming Cao
    Zhenming Cao
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
    More by Zhenming Cao
  • Qin Kuang*
    Qin Kuang
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
    *[email protected]
    More by Qin Kuang
  • Jun Cheng
    Jun Cheng
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
    More by Jun Cheng
  • Jun Zheng
    Jun Zheng
    Institute of Physical Science and Information Technology, Anhui University, Hefei 230601, P. R. China
    More by Jun Zheng
  • , and 
  • Zhaoxiong Xie*
    Zhaoxiong Xie
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
    Pen-Tung Sah Institute of Micro-Nano Science and Technology, Xiamen University, Xiamen 361005, P. R. China
    *[email protected]
Cite this: J. Am. Chem. Soc. 2018, 140, 36, 11232–11240
Publication Date (Web):August 17, 2018
https://doi.org/10.1021/jacs.8b03080
Copyright © 2018 American Chemical Society

    Article Views

    5642

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options
    Supporting Info (1)»

    Abstract

    Abstract Image

    Developing active and durable electro-catalysts toward ethanol oxidation reaction (EOR) with high selectivity toward the C–C bond cleavage is an important issue for the commercialization of direct ethanol fuel cell. Unfortunately, current ethanol oxidation electro-catalysts (e.g., Pt, Pd) still suffer from poor selectivity for direct oxidation of ethanol to CO2, and rapid activity degradation. Here we report a facile route to the synthesis of a new kind of cyclic penta-twinned (CPT) Rh nanostructures that are self-supported nanobranches (NBs) built with 1-dimension CPT nanorods as subunits. Structurally, the as-prepared Rh NBs possess high percentage of open {100} facets with significant CPT-induced lattice strains. With these unique structural characteristics, the as-prepared CPT Rh NBs exhibit outstanding electrocatalytic performance toward EOR in alkaline solution. Most strikingly, the selectivity of complete conversion ethanol to CO2 on the CPT Rh NBs is measured to be as high as 14.5 ± 1.1% at −0.15 V, far exceeding that for single-crystal tetrahedral nanocrystals, icosahedral nanocrystals, and commercial Rh black, as well as majority of reported values for Pt or Pd-based electro-catalysts. By combining with density functional theory calculation, the effects of different structural features of Rh on EOR are definitively elucidated. It was found that the large amount of open Rh (100) facets dominantly contribute to the outstanding activity and exceptionally high selectivity, while the additional tensile strain on (100) planes can further boost the catalytic activity by enhancing the adsorption strength and lowering the reaction barrier of dehydrogenation process of ethanol. As a proof of concept, the present work shows that rationally optimizing surface and electronic structure of electro-catalysts by simultaneously engineering their surface and bulk structures is a promising strategy to promote the performance of electro-catalysts.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.8b03080.

    • Theoretical discussion and DFT results, TEM analysis of Rh NCs obtained using different precursors, different solvents, and in the absence of PVP. DRIFTS, XPS of the CPT Rh NBs, and tetrahedral Rh NCs. TEM and photograph of products obtained at 25 min using n-octanol and n-octylamine, respectively. CO-stripping curves for the Rh NBs and commercial Rh black. TEM images and CV curves of catalysts for EOR. TEM images of the CPT Rh NBs after thermal stability. Scheme of in situ FTIRS cell, and calculation procedure for CO2 selectivity. DFT results (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 132 publications.

    1. Likang Yang, Ze Li, Chen Chen, Jiasheng Wang, Qizhi Yin, Yuxiang Zhang, Peizhi Guo. Assembly of Alloyed PdM (Ag, Cu, and Sn) Nanosheets and Their Electrocatalytic Oxidation of Ethanol and Methanol. Inorganic Chemistry 2023, 62 (37) , 15320-15328. https://doi.org/10.1021/acs.inorgchem.3c02558
    2. Xuchun Wang, Yu Liu, Xing-Yu Ma, Lo-Yueh Chang, Qixuan Zhong, Qi Pan, Zhiqiang Wang, Xiaolei Yuan, Muhan Cao, Fenglei Lyu, Yaoyue Yang, Jinxing Chen, Tsun-Kong Sham, Qiao Zhang. The Role of Bismuth in Suppressing the CO Poisoning in Alkaline Methanol Electrooxidation: Switching the Reaction from the CO to Formate Pathway. Nano Letters 2023, 23 (2) , 685-693. https://doi.org/10.1021/acs.nanolett.2c04568
    3. Ruitao Wu, Lichang Wang. Activity Enhancement of PtIr Catalysts for Complete Ethanol Oxidation Reaction by Tuning C–O Coupling Abilities. The Journal of Physical Chemistry C 2022, 126 (51) , 21650-21666. https://doi.org/10.1021/acs.jpcc.2c07874
    4. Feng Cao, Hongyu Zhang, Xiao Duan, Xiaoke Li, Rui Ding, Kang Hua, Zhiyan Rui, Yongkang Wu, Mengchen Yuan, Jiankang Wang, Jia Li, Min Han, Jianguo Liu. Coating Porous TiO2 Films on Carbon Nanotubes to Enhance the Durability of Ultrafine PtCo/CNT Nanocatalysts for the Oxygen Reduction Reaction. ACS Applied Materials & Interfaces 2022, 14 (46) , 51975-51982. https://doi.org/10.1021/acsami.2c15517
    5. Yue Liu, Qiong-Lan Wang, Yao-Yue Yang. CO2 and Formate Pathway of Methanol Electrooxidation at Rhodium Electrodes in Alkaline Media: An In Situ Electrochemical Attenuated Total Refection Surface-Enhanced Infrared Absorption Spectroscopy and Infrared Reflection Absorption Spectroscopy Investigation. Langmuir 2022, 38 (41) , 12510-12520. https://doi.org/10.1021/acs.langmuir.2c01917
    6. Qiuxia Wang, Tong Li, Suxia Yan, Wenjie Zhang, Guoai Lv, Hui Xu, Huaming Li, Yong Wang, Junfeng Liu. Boosting Hydrogen Production by Selective Anodic Electrooxidation of Ethanol over Trimetallic PdSbBi Nanoparticles: Composition Matters. Inorganic Chemistry 2022, 61 (40) , 16211-16219. https://doi.org/10.1021/acs.inorgchem.2c02888
    7. Ke Guo, Yang Meng, Ruonan Guo, Hongyou Guo, Shuqin Qiu, Dongping Fan, Dongdong Xu, Yafei Li. Facet-Controlled PdP Nanosheets for Ethanol Electrooxidation. ACS Applied Energy Materials 2022, 5 (9) , 10758-10766. https://doi.org/10.1021/acsaem.2c01480
    8. Weicong Wang, Xiatong Shi, Tianou He, Zhaorui Zhang, Xiaolong Yang, Yan-Jun Guo, Ben Chong, Wen-Min Zhang, Mingshang Jin. Tailoring Amorphous PdCu Nanostructures for Efficient C–C Cleavage in Ethanol Electrooxidation. Nano Letters 2022, 22 (17) , 7028-7033. https://doi.org/10.1021/acs.nanolett.2c01870
    9. Tong Sun, Jianyu Chen, Xianzhuo Lao, Xingxue Zhang, Aiping Fu, Wei Wang, Peizhi Guo. Unveiling the Synergistic Effects of Monodisperse Sea Urchin-like PdPb Alloy Nanodendrites as Stable Electrocatalysts for Ethylene Glycol and Glycerol Oxidation Reactions. Inorganic Chemistry 2022, 61 (26) , 10220-10227. https://doi.org/10.1021/acs.inorgchem.2c01566
    10. Xianzhuo Lao, Tong Sun, Xingxue Zhang, Mingyuan Pang, Aiping Fu, Peizhi Guo. Controllable Lattice Expansion of Monodisperse Face-Centered Cubic Pd–Ag Nanoparticles for C1 and C2 Alcohol Oxidation: The Role of Core–Sheath Lattice Mismatch. ACS Sustainable Chemistry & Engineering 2022, 10 (20) , 6843-6852. https://doi.org/10.1021/acssuschemeng.2c01592
    11. Qiuxia Wang, Junfeng Liu, Wei Zhang, Tong Li, Yong Wang, Huaming Li, Andreu Cabot. Branch-Regulated Palladium–Antimony Nanoparticles Boost Ethanol Electro-oxidation to Acetate. Inorganic Chemistry 2022, 61 (16) , 6337-6346. https://doi.org/10.1021/acs.inorgchem.2c00820
    12. Mingyuan Pang, Min Yang, Jie Yan, Ben Zhang, Lei Zang, Aiping Fu, Peizhi Guo. Assembly of Alloyed PdCu Nanosheets and Their Electrocatalytic Oxidation of Ethanol. Langmuir 2022, 38 (14) , 4287-4294. https://doi.org/10.1021/acs.langmuir.1c03466
    13. Xianzhuo Lao, Min Yang, Xiaoli Sheng, Jing Sun, Yiqian Wang, Derui Zheng, Mingyuan Pang, Aiping Fu, Hongliang Li, Peizhi Guo. Monodisperse PdBi Nanoparticles with a Face-Centered Cubic Structure for Highly Efficient Ethanol Oxidation. ACS Applied Energy Materials 2022, 5 (1) , 1282-1290. https://doi.org/10.1021/acsaem.1c03703
    14. Jing Sun, Xianzhuo Lao, Min Yang, Aiping Fu, Jianyu Chen, Mingyuan Pang, Fahui Gao, Peizhi Guo. Alloyed Palladium–Lead Nanosheet Assemblies for Electrocatalytic Ethanol Oxidation. Langmuir 2021, 37 (51) , 14930-14940. https://doi.org/10.1021/acs.langmuir.1c02816
    15. Yan Fang, Dongjie Cao, Yan Shi, Shiyu Guo, Qi Wang, Genlei Zhang, Peng Cui, Sheng Cheng. Highly Porous Pt2Ir Alloy Nanocrystals as a Superior Catalyst with High-Efficiency C–C Bond Cleavage for Ethanol Electrooxidation. The Journal of Physical Chemistry Letters 2021, 12 (29) , 6773-6780. https://doi.org/10.1021/acs.jpclett.1c01796
    16. Minghang Jiang, Yi Hu, Wenjun Zhang, Lei Wang, Songyuan Yang, Junchuan Liang, Zewen Zhang, Xiaoli Zhang, Zhong Jin. Regulating the Alloying Degree and Electronic Structure of Pt–Au Nanoparticles for High-Efficiency Direct C2+ Alcohol Fuel Cells. Chemistry of Materials 2021, 33 (10) , 3767-3778. https://doi.org/10.1021/acs.chemmater.1c00886
    17. Ming Zhao, Zitao Chen, Yifeng Shi, Zachary D. Hood, Zhiheng Lyu, Minghao Xie, Miaofang Chi, Younan Xia. Kinetically Controlled Synthesis of Rhodium Nanocrystals with Different Shapes and a Comparison Study of Their Thermal and Catalytic Properties. Journal of the American Chemical Society 2021, 143 (16) , 6293-6302. https://doi.org/10.1021/jacs.1c02734
    18. Yaping Quan, Yanying Zhao. Density Functional Theoretical Study on the Electronic Structure of Rh2O7+ with Low Oxidation States. ACS Omega 2020, 5 (31) , 19422-19428. https://doi.org/10.1021/acsomega.0c01321
    19. Wei Wang, Xue Zhang, Yuhui Zhang, Xiaowei Chen, Jinyu Ye, Jiayu Chen, Zixi Lyu, Xuejiao Chen, Qin Kuang, Shuifen Xie, Zhaoxiong Xie. Edge Enrichment of Ultrathin 2D PdPtCu Trimetallic Nanostructures Effectuates Top-Ranked Ethanol Electrooxidation. Nano Letters 2020, 20 (7) , 5458-5464. https://doi.org/10.1021/acs.nanolett.0c01908
    20. Yiming Zhu, Lingzheng Bu, Qi Shao, Xiaoqing Huang. Structurally Ordered Pt3Sn Nanofibers with Highlighted Antipoisoning Property as Efficient Ethanol Oxidation Electrocatalysts. ACS Catalysis 2020, 10 (5) , 3455-3461. https://doi.org/10.1021/acscatal.9b04313
    21. Liang Yu, Lingling Zhang, Xiaojing Zhang, Gaofeng Dai, Jinyu Zhang, Xuebin Wang, Hongjun You. Hollow AuAg Alloy Nanourchins: Twin Plane and Surface Treatment for Enhanced Methanol Electrooxidation Performance. ACS Applied Energy Materials 2020, 3 (1) , 723-732. https://doi.org/10.1021/acsaem.9b01912
    22. Bowei Zhang, Chongqin Zhu, Zishan Wu, Eli Stavitski, Yu Hui Lui, Tae-Hoon Kim, Huan Liu, Ling Huang, Xuechen Luan, Lin Zhou, Kun Jiang, Wenyu Huang, Shan Hu, Hailiang Wang, Joseph S. Francisco. Integrating Rh Species with NiFe-Layered Double Hydroxide for Overall Water Splitting. Nano Letters 2020, 20 (1) , 136-144. https://doi.org/10.1021/acs.nanolett.9b03460
    23. Honglei Yang, Shuwen Li, Fan Feng, Shiyong Ou, Feng Li, Ming Yang, Kailong Qian, Jun Jin, Jiantai Ma. Palladium Nanoparticles with Surface Enrichment of Palladium Oxide Species Immobilized on the Aniline-Functionalized Graphene As an Advanced Electrocatalyst of Ethanol Oxidation. ACS Sustainable Chemistry & Engineering 2019, 7 (17) , 14621-14628. https://doi.org/10.1021/acssuschemeng.9b02397
    24. Da Huo, Myung Jun Kim, Zhiheng Lyu, Yifeng Shi, Benjamin J. Wiley, Younan Xia. One-Dimensional Metal Nanostructures: From Colloidal Syntheses to Applications. Chemical Reviews 2019, 119 (15) , 8972-9073. https://doi.org/10.1021/acs.chemrev.8b00745
    25. Yiming Zhu, Lingzheng Bu, Qi Shao, Xiaoqing Huang. Subnanometer PtRh Nanowire with Alleviated Poisoning Effect and Enhanced C–C Bond Cleavage for Ethanol Oxidation Electrocatalysis. ACS Catalysis 2019, 9 (8) , 6607-6612. https://doi.org/10.1021/acscatal.9b01375
    26. Honglei Yang, Shuwen Li, Sihao Shen, Zeming Jin, Jun Jin, Jiantai Ma. Unraveling the Cooperative Synergy of Palladium/Tin Oxide/Aniline-Functionalized Carbon Nanotubes Enabled by Layer-by-Layer Synthetic Strategy for Ethanol Electrooxidation. ACS Sustainable Chemistry & Engineering 2019, 7 (11) , 10008-10015. https://doi.org/10.1021/acssuschemeng.9b01197
    27. Chan Zhu, Bin Lan, Rui-Lin Wei, Chao-Nan Wang, Yao-Yue Yang. Potential-Dependent Selectivity of Ethanol Complete Oxidation on Rh Electrode in Alkaline Media: A Synergistic Study of Electrochemical ATR-SEIRAS and IRAS. ACS Catalysis 2019, 9 (5) , 4046-4053. https://doi.org/10.1021/acscatal.9b00138
    28. Rui-Lin Wei, Yue Liu, Yao-Yue Yang. Electrocatalytic ethanol-to-CO2 selectivity on the Ir electrode: A quasi-quantitative electrochemical infrared absorption spectroscopic investigation. Applied Catalysis B: Environmental 2024, 344 , 123638. https://doi.org/10.1016/j.apcatb.2023.123638
    29. Liping Wang, Zhiyong Yu, Wei Yan, Liangbin Liu, Mengjun Wang, Qingyu Kong, Zhiwei Hu, Hongbo Geng, Xiaoqing Huang, Yunhua Li. Palladium chalcogenide nanosheets with p-d orbital hybridization for enhanced alcohol electro-oxidation performance. Applied Catalysis B: Environmental 2024, 343 , 123564. https://doi.org/10.1016/j.apcatb.2023.123564
    30. Zhe Zhang, Hui Fu, Cun Chen, Zhen Huang, Liheng Guan, Hanjun Li, Nan Zhang, Tianxi Liu. Defect-rich Pt-Ru metallic aerogels for highly efficient ethanol oxidation reaction. Applied Surface Science 2024, 652 , 159277. https://doi.org/10.1016/j.apsusc.2023.159277
    31. Yufeng Zhang, Wei Zhu, Jinjie Fang, Zhiyuan Xu, Yanrong Xue, Jiajing Pei, Rui Sui, Xingdong Wang, Xuejiang Zhang, Zhongbin Zhuang. Electrochemical converting ethanol to hydrogen and acetic acid for large scale green hydrogen production. Nano Research 2024, 17 (3) , 1542-1551. https://doi.org/10.1007/s12274-023-6023-1
    32. Fu‐Min Li, Chenfeng Xia, Wensheng Fang, Yu Chen, Bao Yu Xia. RhCuBi Trimetallenes with Composition Segregation Coupled Crystalline‐Amorphous Heterostructure Toward Ethanol Electrooxidation. Advanced Energy Materials 2024, 19 https://doi.org/10.1002/aenm.202400112
    33. Liang Ji, Xiaoyue Zhang, Ningkang Qian, Junjie Li, Sudan Shen, Xingqiao Wu, Xin Tan, Hui Zhang, Deren Yang. A universal synthesis strategy of Pd-based trimetallic nanowires for efficient alcohol electrooxidation. Nanoscale 2024, 16 (7) , 3685-3692. https://doi.org/10.1039/D3NR06200G
    34. Chenjia Liang, Ruiyao Zhao, Teng Chen, Yi Luo, Jianqiang Hu, Ping Qi, Weiping Ding. Recent Approaches for Cleaving the C─C Bond During Ethanol Electro‐Oxidation Reaction. Advanced Science 2024, 595 https://doi.org/10.1002/advs.202308958
    35. Hehe Qian, Yuetan Su, Ji Mi, Yongsheng Guo, Kun Yang, Wenjun Fang, Xiaole Weng. Trimetallic PdRhPt Porous Nanooctahedra as Highly Active and Cost‐Effective Electrocatalysts for Ethanol Electrooxidation. ChemCatChem 2024, 16 (3) https://doi.org/10.1002/cctc.202301145
    36. Yipin Lv, Shaohan Yang, Yuchen Qin, Jianyu Ren, Angang Song, Shuna Li, Daowei Gao. Tuning intrinsic strain in PtCuCr nanoframes boosts electro-oxidation of liquid fuels. Chemical Engineering Science 2024, 284 , 119486. https://doi.org/10.1016/j.ces.2023.119486
    37. Tianchun Cheng, Jinshu Tian, Jiafeng Du, Zhi Wang, Jinyu Ye, Aihua Liu, Qiaoli Chen, Yihan Zhu. Self‐Interface in Rh Nanosheets‐Supported Tetrahedral Rh Nanocrystals for Promoting Electrocatalytic Oxidation of Ethanol. Small 2024, 20 (7) https://doi.org/10.1002/smll.202306221
    38. Bei Liu, Haosen Yang, Pengfei Hu, Guang-Sheng Wang, Yongqiang Guo, Hewei Zhao. Dimension Engineering in Noble-Metal-Based Nanocatalysts. Catalysts 2024, 14 (1) , 9. https://doi.org/10.3390/catal14010009
    39. Na Ye, Wenchao Sheng, Riguang Zhang, Binhang Yan, Zhao Jiang, Tao Fang. Interfacial Electron Engineering of PdSn‐NbN/C for Highly Efficient Cleavage of the C–C Bonds in Alkaline Ethanol Electrooxidation. Small 2024, 20 (3) https://doi.org/10.1002/smll.202304990
    40. Bin Sun, Wei Zhong, Xuan Ai, Chong Zhang, Fu-Min Li, Yu Chen. Engineering low-coordination atoms on RhPt bimetallene for 12-electron ethanol electrooxidation. Energy & Environmental Science 2024, 16 https://doi.org/10.1039/D3EE04023B
    41. Chenjie Han, Yeqing Lyu, Shaona Wang, Biao Liu, Yi Zhang, Jan J. Weigand, Hao Du, Jun Lu. Highly Utilized Active Sites on Pt@Cu/C for Ethanol Electrocatalytic Oxidation in Alkali Metal Hydroxide Solutions. Advanced Functional Materials 2023, 33 (46) https://doi.org/10.1002/adfm.202305436
    42. Ruilin Wei, Yue Liu, Huazhong Ma, Xingyu Ma, Yaoyue Yang. Effective ethanol-to-CO2 electrocatalysis at iridium-bismuth oxide featuring the impressive negative shifting of the working potential. Journal of Energy Chemistry 2023, 86 , 23-31. https://doi.org/10.1016/j.jechem.2023.07.013
    43. Minsu Han, Kenya Kani, Jongbeom Na, Jeonghun Kim, Yoshio Bando, Tansir Ahamad, Saad M. Alshehri, Yusuke Yamauchi. Retrospect and Prospect: Nanoarchitectonics of Platinum‐Group‐Metal‐Based Materials. Advanced Functional Materials 2023, 33 (44) https://doi.org/10.1002/adfm.202301831
    44. Tao Shen, Sijing Chen, Shuang Wang, Xiao Huang, Min Song, Xu Zhao, Jingping Hu, Deli Wang. Optimizing dual-intermediates adsorption on Rh-based intermetallics for formic acid electrooxidation. Applied Catalysis B: Environmental 2023, 333 , 122766. https://doi.org/10.1016/j.apcatb.2023.122766
    45. Zhenming Cao, Huiqi Li, Qiyuan Fan, Zhantao Liu, Zitao Chen, Yunchao Sun, Jinyu Ye, Maofeng Cao, Cong Shen, Yaqi Jiang, Miaofang Chi, Jun Cheng, Hailong Chen, Zhaoxiong Xie, Younan Xia. Interstitial carbon atoms enhance both selectivity and activity of rhodium catalysts toward C-C cleavage in direct ethanol fuel cells. Nano Energy 2023, 113 , 108597. https://doi.org/10.1016/j.nanoen.2023.108597
    46. Liang Ji, Haiyun Che, Ningkang Qian, Junjie Li, Sai Luo, Xiao Li, Xingqiao Wu, Qun Xu, Xuzhong Gong, Xinwei Cui, Hui Zhang, Deren Yang. Unconventional s-p-d hybridization in modulating frontier orbitals of carbonaceous radicals on PdBi nanosheets for efficient ethanol electrooxidation. Applied Catalysis B: Environmental 2023, 328 , 122521. https://doi.org/10.1016/j.apcatb.2023.122521
    47. Di Liu, Zhejiaji Zhu, Jiani Li, Li-Wei Chen, Hui-Zi Huang, Xiao-Ting Jing, An-Xiang Yin. Rh–Cu alloy nano-dendrites with enhanced electrocatalytic ethanol oxidation activity. Journal of Energy Chemistry 2023, 82 , 343-349. https://doi.org/10.1016/j.jechem.2023.03.038
    48. Xin Zhang, Tao Wang, Cui Wang, René Hübner, Alexander Eychmüller, Jinhua Zhan, Bin Cai. Bimetallic Pt‐Hg Aerogels for Electrocatalytic Upgrading of Ethanol to Acetate. Small 2023, 19 (24) https://doi.org/10.1002/smll.202207557
    49. Wengui Xiao, Susu Li, Jiaxin Liu, Jiahe Fan, Liang Ma, Weiwei Cai. Lead as an effective facilitator for ethanol electrooxidation on Rh catalyst in alkaline media: RhPb/C vs RhRu/C. Journal of Electroanalytical Chemistry 2023, 936 , 117386. https://doi.org/10.1016/j.jelechem.2023.117386
    50. Krishnan Veeramani, Gnanaprakasam Janani, Joonyoung Kim, Subramani Surendran, Jaehyoung Lim, Sebastian Cyril Jesudass, Shivraj Mahadik, Hyunjung lee, Tae-Hoon Kim, Jung Kyu Kim, Uk Sim. Hydrogen and value-added products yield from hybrid water electrolysis: A critical review on recent developments. Renewable and Sustainable Energy Reviews 2023, 177 , 113227. https://doi.org/10.1016/j.rser.2023.113227
    51. Ke Guo, Dongdong Xu, Lin Xu, Yafei Li, Yawen Tang. Noble metal nanodendrites: growth mechanisms, synthesis strategies and applications. Materials Horizons 2023, 10 (4) , 1234-1263. https://doi.org/10.1039/D2MH01408D
    52. Bei Fu, Likang Yang, Luyao Xu, Qingqing Yang, Yaying Zheng, Tianrong Zhan, Peizhi Guo. Synthesis of PdSn Nanoparticles with a Face‐Centered Cubic Structure for Electrocatalytic Ethanol Oxidation. ChemCatChem 2023, 15 (5) https://doi.org/10.1002/cctc.202201357
    53. Qian Wang, Runxi Zhu, Peilin Deng, Jing Li, Wei Huang, Qi Chen, Ya-Qiong Su, Chunman Jia, Zhongxin Liu, Zhenye Kang, Yijun Shen, Xinlong Tian. Rhodium decorated stable platinum nickel nanowires for effective ethanol oxidation reaction. Science China Materials 2023, 66 (2) , 679-685. https://doi.org/10.1007/s40843-022-2150-y
    54. Dian Tri Lestarini, Jong Wook Hong. Intermetallic Pd3Pb nanobranches with low-coordinated surface atoms for highly efficient ethanol oxidation reaction. Applied Surface Science 2023, 610 , 155311. https://doi.org/10.1016/j.apsusc.2022.155311
    55. Xiaomeng Liu, Junxuan Xu, Haoyue Zhang, Yitian Zhong, Haosheng Feng, Yanxi Zhao, Qin Li, Xianghong Li, Tao Huang. Microwave-assisted synthesis of octahedral Rh nanocrystals and their performance for electrocatalytic oxidation of formic acid. RSC Advances 2023, 13 (3) , 1751-1756. https://doi.org/10.1039/D2RA07445A
    56. Yan Guo, Xiaobo Yang, Xingchen Liu, Xili Tong, Nianjun Yang. Coupling Methanol Oxidation with Hydrogen Evolution on Bifunctional Co‐Doped Rh Electrocatalyst for Efficient Hydrogen Generation. Advanced Functional Materials 2023, 33 (2) https://doi.org/10.1002/adfm.202209134
    57. Ze Li, Xianzhuo Lao, Likang Yang, Aiping Fu, Peizhi Guo. Assembly of trimetallic palladium-silver-copper nanosheets for efficient C2 alcohol electrooxidation. Science China Materials 2023, 66 (1) , 150-159. https://doi.org/10.1007/s40843-022-2104-4
    58. Lusi Zhao, Guangtao Yu, Mingyue Lv, Xuri Huang, Hu Zhu, Wei Chen. 2D RhTe Monolayer: A highly efficient electrocatalyst for oxygen reduction reaction. Journal of Colloid and Interface Science 2023, 629 , 971-980. https://doi.org/10.1016/j.jcis.2022.09.023
    59. Juan Xiong, Hongdong Li, Yue Pan, Jiao Liu, Yan Zhang, Jixiang Xu, Bin Li, Jianping Lai, Lei Wang. Multiple strategies of porous tetrametallene for efficient ethanol electrooxidation. Journal of Materials Chemistry A 2022, 10 (43) , 23015-23022. https://doi.org/10.1039/D2TA05109E
    60. Yue Liu, Bing Lan, Yaoyue Yang. Boosting ethanol electrooxidation at RhBi alloy and Bi 2 O 3 composite surfaces in alkaline media. Journal of Materials Chemistry A 2022, 10 (39) , 20946-20952. https://doi.org/10.1039/D2TA06062K
    61. Hao Tian, Runxi Zhu, Peilin Deng, Jing Li, Wei Huang, Qi Chen, Ya‐Qiong Su, Chunman Jia, Zhongxin Liu, Yijun Shen, Xinlong Tian. Ultrathin Pd 3 Pt 1 Rh 0.1 Nanorings with Strong C−C Bond Breaking Ability for the Ethanol Oxidation Reaction. Small 2022, 18 (40) https://doi.org/10.1002/smll.202203506
    62. Zhengshuai Cao, Xianzhuo Lao, Fahui Gao, Min Yang, Jing Sun, Xuehua Liu, Rui Su, Jianyu Chen, Peizhi Guo. Improvement of electrocatalytic alcohol oxidation by tuning the phase structure of atomically ordered intermetallic Pd-Sn nanowire networks. Science China Materials 2022, 65 (10) , 2694-2703. https://doi.org/10.1007/s40843-022-2069-8
    63. Na Ye, Pengcheng Zhao, Xiaoying Qi, Wenchao Sheng, Zhao Jiang, Tao Fang. Ethanol electro-oxidation on the PdSn-TaN/C catalyst in alkaline media: Making TaN capable of splitting C C bond. Applied Catalysis B: Environmental 2022, 314 , 121473. https://doi.org/10.1016/j.apcatb.2022.121473
    64. Yue Pan, Hongdong Li, Jiajun Min, Juan Xiong, Yingnan Qin, Zuochao Wang, Zhanchao Wu, Shouhua Feng, Jianping Lai, Lei Wang. High C1 selectivity in alkaline ethanol oxidation reaction over stable Lewis pairs of Pd-MxC@CNT (M = W, Mo and Cr). Chemical Engineering Journal 2022, 446 , 137178. https://doi.org/10.1016/j.cej.2022.137178
    65. Min Huang, Bing Lan, Xiao-Le Jiang, Yao-Yue Yang, Wei-Shang Jia. Interfacial engineering Pb skin-layer at Rh surface to promote ethanol electrooxidation into CO2 in alkaline media. International Journal of Hydrogen Energy 2022, 47 (82) , 34932-34942. https://doi.org/10.1016/j.ijhydene.2022.08.088
    66. Junkai Zhao, Liang Li, Liuqiang Li, Siru Zhang, Shiqi Chen, Zheng Yuan, Ling Wang. Simple and efficient: performance of palladium-loaded sepiolite for electrocatalytic ethanol oxidation. Clay Minerals 2022, 57 (3-4) , 211-222. https://doi.org/10.1180/clm.2022.40
    67. Kai Deng, Wenxin Wang, Qiqi Mao, Hongjie Yu, Ziqiang Wang, You Xu, Xiaonian Li, Hongjing Wang, Liang Wang. Boron‐Intercalation‐Induced Phase Evolution of Rh Metallene for Energy‐Saving H 2 Production by H 2 O 2 Oxidation Coupled with Water Electrolysis. Small 2022, 18 (32) https://doi.org/10.1002/smll.202203020
    68. Amir Mahmoud Makin, Madeha Ishag Adam, Zehai Xu, Jia Kang Wan, Guoliang Zhang. Pd-Ru anchored on CaO derived from waste-eggshells for ethanol oxidation electrocatalysis. Molecular Catalysis 2022, 528 , 112437. https://doi.org/10.1016/j.mcat.2022.112437
    69. Hao Lv, Lizhi Sun, Yanzhi Wang, Shaohua Liu, Ben Liu. Highly Curved, Quasi‐Single‐Crystalline Mesoporous Metal Nanoplates Promote CC Bond Cleavage in Ethanol Oxidation Electrocatalysis. Advanced Materials 2022, 34 (30) https://doi.org/10.1002/adma.202203612
    70. Ling Li, Mingyu Chu, Ruru Song, Shangheng Liu, Guomian Ren, Yong Xu, Lu Wang, Qingfeng Xu, Qi Shao, Jianmei Lu, Xiaoqing Huang. CO spillover on ultrathin bimetallic Rh/Rh-M nanosheets. Chem Catalysis 2022, 2 (7) , 1709-1719. https://doi.org/10.1016/j.checat.2022.04.013
    71. Zhiwei Hu, Linjuan Zhang. Catalytic activity of bimetallic Rh/Rh-M nanosheets governed by CO spillover. Chem Catalysis 2022, 2 (7) , 1512-1514. https://doi.org/10.1016/j.checat.2022.05.008
    72. Jing-Xiao Tang, Na Tian, Liang-Ping Xiao, Qing-Song Chen, Qiong Wang, Zhi-You Zhou, Shi-Gang Sun. Helical PdPtAu nanowires bounded with high-index facets selectively switch the pathway of ethanol electrooxidation. Journal of Materials Chemistry A 2022, 10 (20) , 10902-10908. https://doi.org/10.1039/D2TA01011A
    73. Peiwen Xu, Shafei Zhao, Tingting Wang, Weijie Ji, Zhaoxu Chen, Chak-Tong Au. A Pt/SnO 2 /rGO interface more capable of converting ethanol to CO 2 in ethanol electro-oxidation: a detailed experimental/DFT study. Journal of Materials Chemistry A 2022, 10 (18) , 10150-10161. https://doi.org/10.1039/D2TA00178K
    74. Zhenyu Li, Jiefei Li, Zexuan Zheng, Kunhong Jiang, Tianrun Zheng, Dongmin Wang, Hang Wei, Zhiming Shi, Xiaotian Li, Haibin Chu. Roles of hydroxyl and oxygen vacancy of CeO2·xH2O in Pd-catalyzed ethanol electro-oxidation. Science China Chemistry 2022, 65 (5) , 877-884. https://doi.org/10.1007/s11426-021-1220-2
    75. Mingyu Chu, Jialu Huang, Jin Gong, Yi Qu, Guoling Chen, Hu Yang, Xuchun Wang, Qixuan Zhong, Chengwei Deng, Muhan Cao, Jinxing Chen, Xiaolei Yuan, Qiao Zhang. Synergistic combination of Pd nanosheets and porous Bi(OH)3 boosts activity and durability for ethanol oxidation reaction. Nano Research 2022, 15 (5) , 3920-3926. https://doi.org/10.1007/s12274-021-4049-9
    76. Yan Fang, Shiyu Guo, Dongjie Cao, Genlei Zhang, Qi Wang, Yazhong Chen, Peng Cui, Sheng Cheng, Wansheng Zuo. Five-fold twinned Ir-alloyed Pt nanorods with high C1 pathway selectivity for ethanol electrooxidation. Nano Research 2022, 15 (5) , 3933-3939. https://doi.org/10.1007/s12274-021-4062-z
    77. Xiao Duan, Feng Cao, Rui Ding, Xiaoke Li, Qingbing Li, Ruziguli Aisha, Shiqiao Zhang, Kang Hua, Zhiyan Rui, Yongkang Wu, Jia Li, Aidong Li, Jianguo Liu. Cobalt‐Doping Stabilized Active and Durable Sub‐2 nm Pt Nanoclusters for Low‐Pt‐Loading PEMFC Cathode. Advanced Energy Materials 2022, 12 (13) https://doi.org/10.1002/aenm.202103144
    78. Zi‐Xin Ge, Tian‐Jiao Wang, Yu Ding, Shi‐Bin Yin, Fu‐Min Li, Pei Chen, Yu Chen. Interfacial Engineering Enhances the Electroactivity of Frame‐Like Concave RhCu Bimetallic Nanocubes for Nitrate Reduction. Advanced Energy Materials 2022, 12 (15) https://doi.org/10.1002/aenm.202103916
    79. Dawei Du, Qinghong Geng, Lian Ma, Siyu Ren, Jun-Xuan Li, Weikang Dong, Qingfeng Hua, Longlong Fan, Ruiwen Shao, Xiaoming Wang, Cuiling Li, Yusuke Yamauchi. Mesoporous PdBi nanocages for enhanced electrocatalytic performances by all-direction accessibility and steric site activation. Chemical Science 2022, 13 (13) , 3819-3825. https://doi.org/10.1039/D1SC06314F
    80. Jun-Xuan Li, Hong-Xing Yin, Qinghong Geng, Dawei Du, Lian Ma, Longlong Fan, Qingfeng Hua, Cuiling Li. Nanoporous trimetallic PdCuAg alloys as efficient electrocatalysts by all-direction accessibility and synergetic effects. Journal of Materials Chemistry A 2022, 10 (12) , 6569-6575. https://doi.org/10.1039/D1TA10558B
    81. Xiaoyang Fu, Chengzhang Wan, Yu Huang, Xiangfeng Duan. Noble Metal Based Electrocatalysts for Alcohol Oxidation Reactions in Alkaline Media. Advanced Functional Materials 2022, 32 (11) https://doi.org/10.1002/adfm.202106401
    82. Xiaobo Yang, Yingyong Wang, Xili Tong, Nianjun Yang. Strain Engineering in Electrocatalysts: Fundamentals, Progress, and Perspectives. Advanced Energy Materials 2022, 12 (5) https://doi.org/10.1002/aenm.202102261
    83. Junlin Cai, Xinyan Liao, Pingting Li, Qiuxiang Wang, Hongpu Huang, Zixi Lyu, Jing Lin, Shuifen Xie. Penta-Twinned Rh@Pt Core-Shell nanobranches with engineered shell thickness for reversible and active hydrogen redox electrocatalysis. Chemical Engineering Journal 2022, 429 , 132414. https://doi.org/10.1016/j.cej.2021.132414
    84. Chen Li, Ke Wang, Dong Xie. A review of approaches for the design of high-performance electrocatalysts for ethanol electrooxidation. Surfaces and Interfaces 2022, 28 , 101594. https://doi.org/10.1016/j.surfin.2021.101594
    85. Cong Shen, Hanming Chen, Mingye Qiu, Yuqiang Shi, Wei Yan, Qiaorong Jiang, Yaqi Jiang, Zhaoxiong Xie. Introducing oxophilic metal and interstitial hydrogen into the Pd lattice to boost electrochemical performance for alkaline ethanol oxidation. Journal of Materials Chemistry A 2022, 10 (4) , 1735-1741. https://doi.org/10.1039/D1TA08924B
    86. Bing Lan, Qiong-Lan Wang, Zhao-Xia Ma, Ya-Juan Wu, Xiao-Le Jiang, Wei-Shang Jia, Cai-Xia Zhou, Yao-Yue Yang. Efficient electrochemical ethanol-to-CO2 conversion at rhodium and bismuth hydroxide interfaces. Applied Catalysis B: Environmental 2022, 300 , 120728. https://doi.org/10.1016/j.apcatb.2021.120728
    87. Yangping Zhang, Fei Gao, Huaming You, Zhuolin Li, Bin Zou, Yukou Du. Recent advances in one-dimensional noble-metal-based catalysts with multiple structures for efficient fuel-cell electrocatalysis. Coordination Chemistry Reviews 2022, 450 , 214244. https://doi.org/10.1016/j.ccr.2021.214244
    88. Yanxin Bai, Xiang Gong, Na Ye, Xiaoying Qi, Zhao Jiang, Tao Fang. Design the PdCu/Ni2P electrocatalyst with high efficiency for ethanol oxidation reaction in alkaline media. International Journal of Hydrogen Energy 2022, 47 (3) , 1543-1555. https://doi.org/10.1016/j.ijhydene.2021.10.016
    89. Yue Liu, Bing Lan, Wei-Shang Jia, Yao-Yue Yang. Ethanol Selective Electrooxidation Following the C2 Pathway with Superior Activity and Stability at Rhbi Alloy Surface in Alkaline Media. SSRN Electronic Journal 2022, 109 https://doi.org/10.2139/ssrn.4097385
    90. Ben Zhang, Xingxue Zhang, Jie Yan, Zhengshuai Cao, Mingyuan Pang, Jianyu Chen, Lei Zang, Peizhi Guo. Synthesis of Free‐Standing Alloyed PdSn Nanoparticles with Enhanced Catalytic Performance for Ethanol Electrooxidation. ChemElectroChem 2021, 8 (23) , 4509-4514. https://doi.org/10.1002/celc.202101242
    91. Yajun Qiu, Jian Zhang, Jing Jin, Jiaqiang Sun, Haolin Tang, Qingqing Chen, Zedong Zhang, Wenming Sun, Ge Meng, Qi Xu, Youqi Zhu, Aijuan Han, Lin Gu, Dingsheng Wang, Yadong Li. Construction of Pd-Zn dual sites to enhance the performance for ethanol electro-oxidation reaction. Nature Communications 2021, 12 (1) https://doi.org/10.1038/s41467-021-25600-9
    92. Jianyu Chen, Min Yang, Mingyuan Pang, Fahui Gao, Peizhi Guo. Bimetallic PdAg nanoparticles for enhanced electrocatalysis of ethanol oxidation reaction. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2021, 629 , 127404. https://doi.org/10.1016/j.colsurfa.2021.127404
    93. Ying Zhang, Gen Li, Zhonglong Zhao, Lili Han, Yonggang Feng, Shangheng Liu, Bingyan Xu, Honggang Liao, Gang Lu, Huolin L. Xin, Xiaoqing Huang. Atomically Isolated Rh Sites within Highly Branched Rh 2 Sb Nanostructures Enhance Bifunctional Hydrogen Electrocatalysis. Advanced Materials 2021, 33 (43) https://doi.org/10.1002/adma.202105049
    94. Guangxing Yang, Qiao Zhang, Hao Yu, Feng Peng. Platinum-based ternary catalysts for the electrooxidation of ethanol. Particuology 2021, 58 , 169-186. https://doi.org/10.1016/j.partic.2021.01.007
    95. Yuheng Zhou, Zhiqiang Wang, Bin Ye, Xubo Huang, Hui Deng. Ligand effect over gold nanocatalysts towards enhanced gas-phase oxidation of alcohols. Journal of Catalysis 2021, 400 , 274-282. https://doi.org/10.1016/j.jcat.2021.05.032
    96. Liangping Xiao, Guang Li, Zhou Yang, Kai Chen, Rusen Zhou, Honggang Liao, Qingchi Xu, Jun Xu. Engineering of Amorphous PtO x Interface on Pt/WO 3 Nanosheets for Ethanol Oxidation Electrocatalysis. Advanced Functional Materials 2021, 31 (28) https://doi.org/10.1002/adfm.202100982
    97. Siyu Ren, Dawei Du, Lian Ma, Cuiling Li. Mesoporous PdBi film as efficient electrocatalyst for ethanol oxidation reaction. Journal of Physics: Materials 2021, 4 (3) , 034001. https://doi.org/10.1088/2515-7639/abf1aa
    98. Fan Lv, Weiyu Zhang, Mingzi Sun, Fangxu Lin, Tong Wu, Peng Zhou, Wenxiu Yang, Peng Gao, Bolong Huang, Shaojun Guo. Au Clusters on Pd Nanosheets Selectively Switch the Pathway of Ethanol Electrooxidation: Amorphous/Crystalline Interface Matters. Advanced Energy Materials 2021, 11 (19) https://doi.org/10.1002/aenm.202100187
    99. Shuiping Luo, Long Zhang, Yujia Liao, Lanxi Li, Qi Yang, Xiaotong Wu, Xiaoyu Wu, Dongsheng He, Chunyong He, Wen Chen, Qilong Wu, Mingrui Li, Emiel J. M. Hensen, Zewei Quan. A Tensile‐Strained Pt–Rh Single‐Atom Alloy Remarkably Boosts Ethanol Oxidation. Advanced Materials 2021, 33 (17) https://doi.org/10.1002/adma.202008508
    100. Meng Li, Zhijuan Li, Gengtao Fu, Yawen Tang. Recent Advances in Amino‐Based Molecules Assisted Control of Noble‐Metal Electrocatalysts. Small 2021, 17 (17) https://doi.org/10.1002/smll.202007179
    Load all citations

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect