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A Carbon Nitride/Fe Quaterpyridine Catalytic System for Photostimulated CO2-to-CO Conversion with Visible Light

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    Communication

    A Carbon Nitride/Fe Quaterpyridine Catalytic System for Photostimulated CO2-to-CO Conversion with Visible Light
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    • Claudio Cometto
      Claudio Cometto
      Université Paris Diderot, Sorbonne Paris Cité, Laboratoire d’Electrochimie Moléculaire, UMR 7591 CNRS, 15 rue Jean-Antoine de Baïf, F-75205 Paris, Cedex 13, France
      More by Claudio Cometto
    • Ryo Kuriki
      Ryo Kuriki
      Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1-NE-1 Okayama, Meguro-ku, Tokyo 152-8550, Japan
      Japan Society for the Promotion of Science, Kojimachi Business Center Building, 5-3-1 Kojimachi, Chiyoda-ku, Tokyo 102-0083, Japan
      More by Ryo Kuriki
    • Lingjing Chen
      Lingjing Chen
      School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan, Guangdong 523808, P. R. China
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    • Kazuhiko Maeda*
      Kazuhiko Maeda
      Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1-NE-1 Okayama, Meguro-ku, Tokyo 152-8550, Japan
      *E-mail: [email protected]
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      Orcidhttp://orcid.org/0000-0001-7245-8318
    • Tai-Chu Lau*
      Tai-Chu Lau
      Department of Chemistry and Institute of Molecular Functional Materials, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, P. R. China
      *E-mail: [email protected]
      More by Tai-Chu Lau
      Orcidhttp://orcid.org/0000-0002-0867-9746
    • Osamu Ishitani*
      Osamu Ishitani
      Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1-NE-1 Okayama, Meguro-ku, Tokyo 152-8550, Japan
      *E-mail: [email protected]
      More by Osamu Ishitani
      Orcidhttp://orcid.org/0000-0001-9557-7854
    • Marc Robert*
      Marc Robert
      Université Paris Diderot, Sorbonne Paris Cité, Laboratoire d’Electrochimie Moléculaire, UMR 7591 CNRS, 15 rue Jean-Antoine de Baïf, F-75205 Paris, Cedex 13, France
      *E-mail: [email protected]
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      Orcidhttp://orcid.org/0000-0001-7042-4106
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2018, 140, 24, 7437–7440
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    https://doi.org/10.1021/jacs.8b04007
    Published June 11, 2018
    Copyright © 2018 American Chemical Society
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    Abstract

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    Efficient and selective photostimulated CO2-to-CO reduction by a photocatalytic system consisting of an iron-complex catalyst and a mesoporous graphitic carbon nitride (mpg-C3N4) redox photosensitizer is reported for the first time. Irradiation in the visible region (λ ≥ 400 nm) of an CH3CN/triethanolamine (4:1, v/v) solution containing [Fe(qpy)(H2O)2]2+ (qpy = 2,2′:6′,2′′:6′′,2′′-quaterpyridine) and mpg-C3N4 resulted in CO evolution with 97% selectivity, a turnover number of 155, and an apparent quantum yield of ca. 4.2%. This hybrid catalytic system, comprising only earth abundant elements, opens new perspectives for solar fuels production using CO2 as a renewable feedstock.

    Copyright © 2018 American Chemical Society

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    This article is cited by 170 publications.

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