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Toward Long-Term Stability: Single-Crystal Alloys of Cesium-Containing Mixed Cation and Mixed Halide Perovskite

  • Liang Chen
    Liang Chen
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
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  • Yan-Yan Tan
    Yan-Yan Tan
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
    More by Yan-Yan Tan
  • Zhi-Xin Chen
    Zhi-Xin Chen
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
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  • Tan Wang
    Tan Wang
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
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  • Shu Hu
    Shu Hu
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
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  • Zi-Ang Nan
    Zi-Ang Nan
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
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  • Li-Qiang Xie
    Li-Qiang Xie
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
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  • Yong Hui
    Yong Hui
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
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  • Jing-Xin Huang
    Jing-Xin Huang
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
  • Chao Zhan
    Chao Zhan
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
    More by Chao Zhan
  • Su-Heng Wang
    Su-Heng Wang
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
    More by Su-Heng Wang
  • Jian-Zhang Zhou
    Jian-Zhang Zhou
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
  • Jia-Wei Yan
    Jia-Wei Yan
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
    More by Jia-Wei Yan
  • Bing-Wei Mao*
    Bing-Wei Mao
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
    *[email protected]
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  • , and 
  • Zhong-Qun Tian*
    Zhong-Qun Tian
    State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, China
    *[email protected]
Cite this: J. Am. Chem. Soc. 2019, 141, 4, 1665–1671
Publication Date (Web):January 4, 2019
https://doi.org/10.1021/jacs.8b11610
Copyright © 2019 American Chemical Society

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    Abstract

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    Perovskite solar cells are strong competitors for silicon-based ones, but suffer from poor long-term stability, for which the intrinsic stability of perovskite materials is of primary concern. Herein, we prepared a series of well-defined cesium-containing mixed cation and mixed halide perovskite single-crystal alloys, which enabled systematic investigations on their structural stabilities against light, heat, water, and oxygen. Two potential phase separation processes are evidenced for the alloys as the cesium content increases to 10% and/or bromide to 15%. Eventually, a highly stable new composition, (FAPbI3)0.9(MAPbBr3)0.05(CsPbBr3)0.05, emerges with a carrier lifetime of 16 μs. It remains stable during at least 10 000 h water–oxygen and 1000 h light stability tests, which is very promising for long-term stable devices with high efficiency. The mechanism for the enhanced stability is elucidated through detailed single-crystal structure analysis. Our work provides a single-crystal-based paradigm for stability investigation, leading to the discovery of stable new perovskite materials.

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