Toward Long-Term Stability: Single-Crystal Alloys of Cesium-Containing Mixed Cation and Mixed Halide Perovskite
- Liang ChenLiang ChenState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Liang Chen
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- Yan-Yan TanYan-Yan TanState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Yan-Yan Tan
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- Zhi-Xin ChenZhi-Xin ChenState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Zhi-Xin Chen
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- Tan WangTan WangState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Tan Wang
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- Shu HuShu HuState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Shu Hu
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- Zi-Ang NanZi-Ang NanState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Zi-Ang Nan
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- Li-Qiang XieLi-Qiang XieState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Li-Qiang Xie
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- Yong HuiYong HuiState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Yong Hui
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- Jing-Xin HuangJing-Xin HuangState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Jing-Xin Huang
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- Chao ZhanChao ZhanState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Chao Zhan
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- Su-Heng WangSu-Heng WangState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Su-Heng Wang
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- Jian-Zhang ZhouJian-Zhang ZhouState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Jian-Zhang Zhou
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- Jia-Wei YanJia-Wei YanState Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Jia-Wei Yan
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- Bing-Wei Mao*Bing-Wei Mao*[email protected]State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Bing-Wei Mao
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- Zhong-Qun Tian*Zhong-Qun Tian*[email protected]State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, and Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, ChinaMore by Zhong-Qun Tian
Abstract

Perovskite solar cells are strong competitors for silicon-based ones, but suffer from poor long-term stability, for which the intrinsic stability of perovskite materials is of primary concern. Herein, we prepared a series of well-defined cesium-containing mixed cation and mixed halide perovskite single-crystal alloys, which enabled systematic investigations on their structural stabilities against light, heat, water, and oxygen. Two potential phase separation processes are evidenced for the alloys as the cesium content increases to 10% and/or bromide to 15%. Eventually, a highly stable new composition, (FAPbI3)0.9(MAPbBr3)0.05(CsPbBr3)0.05, emerges with a carrier lifetime of 16 μs. It remains stable during at least 10 000 h water–oxygen and 1000 h light stability tests, which is very promising for long-term stable devices with high efficiency. The mechanism for the enhanced stability is elucidated through detailed single-crystal structure analysis. Our work provides a single-crystal-based paradigm for stability investigation, leading to the discovery of stable new perovskite materials.
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- Ruiqing Li, Haidong Jiang, Yunpeng Yao, Huang Ye, Xitao Liu, Shuang Chen, Junhua Luo. Bulk Single Crystals of a Narrow Band Gap Three-Dimensional Hybrid Perovskitoid Enabling Ultrastable Photodetection. Chemistry of Materials 2022, 34 (23) , 10382-10389. https://doi.org/10.1021/acs.chemmater.2c02109
- Rui Wang, Xiyue Dong, Qin Ling, Qiang Fu, Ziyang Hu, Zhiyuan Xu, Hao Zhang, Qiaohui Li, Yongsheng Liu. Spacer Engineering for 2D Ruddlesden–Popper Perovskites with an Ultralong Carrier Lifetime of Over 18 μs Enable Efficient Solar Cells. ACS Energy Letters 2022, 7 (10) , 3656-3665. https://doi.org/10.1021/acsenergylett.2c01800
- Wen-Han Zhang, Liang Chen, Ze-Ping Zou, Zi-Ang Nan, Jue-Li Shi, Qing-Peng Luo, Yong Hui, Kai-Xuan Li, Yan-Jie Wang, Jian-Zhang Zhou, Jia-Wei Yan, Bing-Wei Mao. Defect Passivation by a Multifunctional Phosphate Additive toward Improvements of Efficiency and Stability of Perovskite Solar Cells. ACS Applied Materials & Interfaces 2022, 14 (28) , 31911-31919. https://doi.org/10.1021/acsami.2c05956
- Ananthan Alagumalai, Muthukumar Venu Rajendran, Saraswathi Ganesan, Vidya Sudhakaran Menon, Rohith Kumar Raman, Sai Manohar Chelli, Sai Muthukumar Vijayasayee, Senthil A. Gurusamy Thangavelu, Ananthanarayanan Krishnamoorthy. Interface Modification with Holistically Designed Push–Pull D–π–A Organic Small Molecule Facilitates Band Alignment Engineering, Efficient Defect Passivation, and Enhanced Hydrophobicity in Mixed Cation Planar Perovskite Solar Cells. ACS Applied Energy Materials 2022, 5 (6) , 6783-6796. https://doi.org/10.1021/acsaem.2c00400
- Wenchi Kong, Chen Zhao, Tao Huang, Xiuyun Li, Jun Xing, Zhi Yu, Peng Yang, Wei Li, Weili Yu. Accurate Adjusting the Lattice Strain of Triple-Cation and Mixed-Halide Perovskites for High-Performance Photodetector. ACS Applied Materials & Interfaces 2022, 14 (24) , 28154-28162. https://doi.org/10.1021/acsami.2c02427
- Zhengwei Pan, Long Wu, Jizhong Jiang, Liang Shen, Kai Yao. Searching for High-Quality Halide Perovskite Single Crystals toward X-ray Detection. The Journal of Physical Chemistry Letters 2022, 13 (13) , 2851-2861. https://doi.org/10.1021/acs.jpclett.2c00450
- Tingting Niu, Lingfeng Chao, Xue Dong, Li Fu, Yonghua Chen. Phase-Pure α-FAPbI3 for Perovskite Solar Cells. The Journal of Physical Chemistry Letters 2022, 13 (7) , 1845-1854. https://doi.org/10.1021/acs.jpclett.1c04241
- Kaiyu Wang, Qing Yao, Jie Zhang, Lin Jing, Xiaohua Cheng, Chenyu Shang, Changqian Li, Feitong Chen, Tianliang Zhou, Huiling Zhu, Tingxi Li, Huiping Li, Zhongwei Wang, Jianxu Ding. How Ternary Cations and Binary Halogens Stabilize Trigonal FA1–x–yMAxCsyPbI3–zBrz Perovskites: From a Single Crystal Perspective. Chemistry of Materials 2022, 34 (3) , 1179-1190. https://doi.org/10.1021/acs.chemmater.1c03710
- Zihan Fang, Luyao Wang, Xijiao Mu, Bin Chen, Qiu Xiong, Wei David Wang, Jiaxin Ding, Peng Gao, Yiying Wu, Jing Cao. Grain Boundary Engineering with Self-Assembled Porphyrin Supramolecules for Highly Efficient Large-Area Perovskite Photovoltaics. Journal of the American Chemical Society 2021, 143 (45) , 18989-18996. https://doi.org/10.1021/jacs.1c07518
- Kaiyu Wang, Qing Yao, Jie Zhang, Chenyu Shang, Changqian Li, Feitong Chen, Tianliang Zhou, Haiqing Sun, Weiwei Zhang, Huiling Zhu, Jianxu Ding. Short-Range Migration of A-Site Cations Inhibit Photoinduced Phase Segregation in FAxMAyCs1–x–yPbI3–zBrz Single Crystals. The Journal of Physical Chemistry C 2021, 125 (42) , 23050-23057. https://doi.org/10.1021/acs.jpcc.1c08346
- Mohammad Adil Afroz, Clara A. Aranda, Naveen Kumar Tailor, Yukta, Pankaj Yadav, Mohammad Mahdi Tavakoli, Michael Saliba, Soumitra Satapathi. Impedance Spectroscopy for Metal Halide Perovskite Single Crystals: Recent Advances, Challenges, and Solutions. ACS Energy Letters 2021, 6 (9) , 3275-3286. https://doi.org/10.1021/acsenergylett.1c01099
- Naveen Kumar Tailor, Partha Maity, Soumitra Satapathi. Observation of Negative Photoconductivity in Lead-Free Cs3Bi2Br9Perovskite Single Crystal. ACS Photonics 2021, 8 (8) , 2473-2480. https://doi.org/10.1021/acsphotonics.1c00702
- Xingtao Wang, Yuetian Chen, Taiyang Zhang, Xiaoyu Wang, Yong Wang, Miao Kan, Yanfeng Miao, Haoran Chen, Xiaomin Liu, Xinjiang Wang, Jielin Shi, Lijun Zhang, Yixin Zhao. Stable Cesium-Rich Formamidinium/Cesium Pure-Iodide Perovskites for Efficient Photovoltaics. ACS Energy Letters 2021, 6 (8) , 2735-2741. https://doi.org/10.1021/acsenergylett.1c01013
- Yuanyuan Zhang, Qiao Chen, Hyun-Seock Yang, Danbi Kim, Insoo Shin, Bo Ram Lee, Joo Hyun Kim, Doo Kyung Moon, Kwang Ho Kim, Sung Heum Park. Water-Repellent Perovskites Induced by a Blend of Organic Halide Salts for Efficient and Stable Solar Cells. ACS Applied Materials & Interfaces 2021, 13 (28) , 33172-33181. https://doi.org/10.1021/acsami.1c09093
- Naveen Kumar Tailor, Shaoni Kar, Pranjal Mishra, Albert These, Christian Kupfer, Hanlin Hu, Muhammad Awais, Makhsud Saidaminov, M. Ibrahim Dar, Christoph Brabec, Soumitra Satapathi. Advances in Lead-Free Perovskite Single Crystals: Fundamentals and Applications. ACS Materials Letters 2021, 3 (7) , 1025-1080. https://doi.org/10.1021/acsmaterialslett.1c00242
- Hongwei Zhu, Yameng Ren, Linfeng Pan, Olivier Ouellette, Felix T. Eickemeyer, Yinghui Wu, Xianggao Li, Shirong Wang, Hongli Liu, Xiaofei Dong, Shaik M. Zakeeruddin, Yuhang Liu, Anders Hagfeldt, Michael Grätzel. Synergistic Effect of Fluorinated Passivator and Hole Transport Dopant Enables Stable Perovskite Solar Cells with an Efficiency Near 24%. Journal of the American Chemical Society 2021, 143 (8) , 3231-3237. https://doi.org/10.1021/jacs.0c12802
- Suverna Trivedi, Daniel Prochowicz, Nishi Parikh, Apurba Mahapatra, Manoj Kumar Pandey, Abul Kalam, Mohammad Mahdi Tavakoli, Pankaj Yadav. Recent Progress in Growth of Single-Crystal Perovskites for Photovoltaic Applications. ACS Omega 2021, 6 (2) , 1030-1042. https://doi.org/10.1021/acsomega.0c04593
- Lu Zhang, Yucheng Liu, Xilai He, Haochen Ye, Jing Leng, Xiaodong Ren, Shengye Jin, Shengzhong Liu. Cd-Doped Triple-Cation Perovskite Thin Films with a 20 μs Carrier Lifetime. The Journal of Physical Chemistry C 2020, 124 (40) , 22011-22018. https://doi.org/10.1021/acs.jpcc.0c07423
- Eve M. Mozur, Michael A. Hope, Julia C. Trowbridge, David M. Halat, Luke L. Daemen, Annalise E. Maughan, Timothy R. Prisk, Clare P. Grey, James R. Neilson. Cesium Substitution Disrupts Concerted Cation Dynamics in Formamidinium Hybrid Perovskites. Chemistry of Materials 2020, 32 (14) , 6266-6277. https://doi.org/10.1021/acs.chemmater.0c01862
- Haotong Wei, Shangshang Chen, Jingjing Zhao, Zhenhua Yu, Jinsong Huang. Is Formamidinium Always More Stable than Methylammonium?. Chemistry of Materials 2020, 32 (6) , 2501-2507. https://doi.org/10.1021/acs.chemmater.9b05101
- Jan Jancik, Anna Jancik Prochazkova, Markus Clark Scharber, Alexander Kovalenko, Jiří Másilko, Niyazi Serdar Sariciftci, Martin Weiter, Jozef Krajcovic. Microwave-Assisted Preparation of Organo-Lead Halide Perovskite Single Crystals. Crystal Growth & Design 2020, 20 (3) , 1388-1393. https://doi.org/10.1021/acs.cgd.9b01670
- Wu-Qiang Wu, Peter N. Rudd, Zhenyi Ni, Charles Henry Van Brackle, Haotong Wei, Qi Wang, Benjamin R. Ecker, Yongli Gao, Jinsong Huang. Reducing Surface Halide Deficiency for Efficient and Stable Iodide-Based Perovskite Solar Cells. Journal of the American Chemical Society 2020, 142 (8) , 3989-3996. https://doi.org/10.1021/jacs.9b13418
- Liqiang Xie, Kebin Lin, Jianxun Lu, Wenjing Feng, Peiquan Song, Chuanzhong Yan, Kaikai Liu, Lina Shen, Chengbo Tian, Zhanhua Wei. Efficient and Stable Low-Bandgap Perovskite Solar Cells Enabled by a CsPbBr3-Cluster Assisted Bottom-up Crystallization Approach. Journal of the American Chemical Society 2019, 141 (51) , 20537-20546. https://doi.org/10.1021/jacs.9b11546
- Rana Nakar, F. Javier Ramos, Clément Dalinot, Pablo Simon Marques, Clément Cabanetos, Philippe Leriche, Lionel Sanguinet, Marwan Kobeissi, Philippe Blanchard, Jérôme Faure-Vincent, François Tran-Van, Nicolas Berton, Jean Rousset, Bruno Schmaltz. Cyclopentadithiophene and Fluorene Spiro-Core-Based Hole-Transporting Materials for Perovskite Solar Cells. The Journal of Physical Chemistry C 2019, 123 (37) , 22767-22774. https://doi.org/10.1021/acs.jpcc.9b05931
- Yipeng Huang, Feiming Li, Linghang Qiu, Fangyuan Lin, Zhiwei Lai, Shuya Wang, Longhui Lin, Yimeng Zhu, Yiru Wang, Yaqi Jiang, Xi Chen. Enhancing the Stability of CH3NH3PbBr3 Nanoparticles Using Double Hydrophobic Shells of SiO2 and Poly(vinylidene fluoride). ACS Applied Materials & Interfaces 2019, 11 (29) , 26384-26391. https://doi.org/10.1021/acsami.9b07841
- Jianxu Ding, Songjie Du, Tianliang Zhou, Ye Yuan, Xiaohua Cheng, Lin Jing, Qing Yao, Jie Zhang, Qingkun He, Hongzhi Cui, Xiaoyuan Zhan, Haiqing Sun. Cesium Decreases Defect Density and Enhances Optoelectronic Properties of Mixed MA1–xCsxPbBr3 Single Crystal. The Journal of Physical Chemistry C 2019, 123 (24) , 14969-14975. https://doi.org/10.1021/acs.jpcc.9b03987
- Huamin Wang, Haodi Wu, Yeming Xian, Guangda Niu, Weinan Yuan, Huanyong Li, Hang Yin, Peng Liu, Yi Long, Wenzhe Li, Jiandong Fan. Controllable CsxFA1–xPbI3 Single-Crystal Morphology via Rationally Regulating the Diffusion and Collision of Micelles toward High-Performance Photon Detectors. ACS Applied Materials & Interfaces 2019, 11 (14) , 13812-13821. https://doi.org/10.1021/acsami.9b02840
- Zemin Zhang, Wooyeon Kim, Min Jae Ko, Yuelong Li. Perovskite single-crystal thin films: preparation, surface engineering, and application. Nano Convergence 2023, 10 (1) https://doi.org/10.1186/s40580-023-00373-7
- Wenjun Wang, Molang Cai, Xuepeng Liu, Kangyu Ji, Xuechao Yu, Songyuan Dai. Metal halide perovskite single crystal growth and application for X-ray detectors. Journal of Materials Chemistry C 2023, 11 (36) , 12105-12127. https://doi.org/10.1039/D3TC01283B
- Denice Navat Feria, Jia-Wen Su, Guo-Hong Wu, Yi-Tsz Zeng, Jan-Tian Lian, Tai-Yuan Lin. Revealing the Enhanced Crystalline Quality Mechanism of Perovskites produced by Microwave-assisted Synthesis: toward the fabrications in a fully ambient air environment. Materials Today Sustainability 2023, 58 , 100532. https://doi.org/10.1016/j.mtsust.2023.100532
- Anastasia Soultati, Marinos Tountas, Konstantina K. Armadorou, Abd. Rashid bin Mohd Yusoff, Maria Vasilopoulou, Mohammad Khaja Nazeeruddin. Synthetic approaches for perovskite thin films and single-crystals. Energy Advances 2023, 2 (8) , 1075-1115. https://doi.org/10.1039/D3YA00098B
- Shien-Ping Feng, Yuanhang Cheng, Hin-Lap Yip, Yufei Zhong, Patrick W K Fong, Gang Li, Annie Ng, Cong Chen, Luigi Angelo Castriotta, Fabio Matteocci, Luigi Vesce, Danila Saranin, Aldo Di Carlo, Puqun Wang, Jian Wei Ho, Yi Hou, Fen Lin, Armin G Aberle, Zhaoning Song, Yanfa Yan, Xu Chen, Yang (Michael) Yang, Ali Asgher Syed, Ishaq Ahmad, Tiklun Leung, Yantao Wang, JingYang Lin, Alan Man Ching Ng, Yin Li, Firouzeh Ebadi, Wolfgang Tress, Giles Richardson, Chuangye Ge, Hanlin Hu, Masoud Karimipour, Fanny Baumann, Kenedy Tabah, Carlos Pereyra, Sonia R Raga, Haibing Xie, Monica Lira-Cantu, Mark V Khenkin, Iris Visoly-Fisher, Eugene A Katz, Yana Vaynzof, Rosario Vidal, Guicheng Yu, Haoran Lin, Shuchen Weng, Shifeng Wang, Aleksandra B Djurišić. Roadmap on commercialization of metal halide perovskite photovoltaics. Journal of Physics: Materials 2023, 6 (3) , 032501. https://doi.org/10.1088/2515-7639/acc893
- Xueping Liu, Deying Luo, Zheng-Hong Lu, Jae Sung Yun, Michael Saliba, Sang Il Seok, Wei Zhang. Stabilization of photoactive phases for perovskite photovoltaics. Nature Reviews Chemistry 2023, 7 (7) , 462-479. https://doi.org/10.1038/s41570-023-00492-z
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- Haodi Wu, Xu Chen, Zihao Song, Ao Zhang, Xinyuan Du, Xin He, Hanqi Wang, Ling Xu, Zhiping Zheng, Guangda Niu, Jiang Tang. Mechanochemical Synthesis of High‐Entropy Perovskite toward Highly Sensitive and Stable X‐ray Flat‐Panel Detectors. Advanced Materials 2023, 35 (29) https://doi.org/10.1002/adma.202301406
- Huayang Li, Nan Shen, Shi Chen, Fei Guo, Baomin Xu. Recent Progress on Synthesis, Intrinsic Properties and Optoelectronic Applications of Perovskite Single Crystals. Advanced Functional Materials 2023, 33 (24) https://doi.org/10.1002/adfm.202214339
- Oscar Telschow, Niels Scheffczyk, Alexander Hinderhofer, Lena Merten, Ekaterina Kneschaurek, Florian Bertram, Qi Zhou, Markus Löffler, Frank Schreiber, Fabian Paulus, Yana Vaynzof. Elucidating Structure Formation in Highly Oriented Triple Cation Perovskite Films. Advanced Science 2023, 10 (17) https://doi.org/10.1002/advs.202206325
- Wenjun Zou, Leting Shan, Weichen Cao, Jun Chen, Xin Liu, Jiangsheng Yu, Liang Shen, Kai Yao. Precrystallized‐Heterojunction Strategy on Precursor Solution Enables High‐Performance Semitransparent Perovskite Solar Cells. Advanced Optical Materials 2023, 11 (12) https://doi.org/10.1002/adom.202202982
- Malik Muhammad Wasim Iqbal, Qihao Xie, Mengqiu Cai, Xuming Zou, Qinglin Zhang, Ruosheng Zeng, Bingsuo Zou, Lei Liao, Qiang Wan. Surface steered aligned gradient inorganic lead halide perovskite CsPbBr I nanowires for use in photodetectors. Applied Surface Science 2023, 617 , 156458. https://doi.org/10.1016/j.apsusc.2023.156458
- Merlys Borges-Martínez, Mario Saavedra-Torres, Eduardo Schott, Ximena Zarate. Computational design and properties elucidation of new (FAPbI3)1−x-y(MAPbBr3)y(CsPbBr3)x photoactive systems for their application in perovskite solar cells. Materials Today Communications 2023, 34 , 105324. https://doi.org/10.1016/j.mtcomm.2023.105324
- Donghoon Shin, Minliang Lai, Yongjin Shin, Jingshan S. Du, Liban Jibril, James M. Rondinelli, Chad A. Mirkin. From Heterostructures to Solid‐Solutions: Structural Tunability in Mixed Halide Perovskites. Advanced Materials 2023, 35 (11) https://doi.org/10.1002/adma.202205923
- N. Rajeev Kumar, Sankar Ganesh Ramaraj, P.C. Karthika, Nishitha P. Mathew, R. Radhakrishnan. First-principles study on the role of anion in the physical properties of lead-free halide double perovskites. Computational Materials Science 2023, 218 , 111975. https://doi.org/10.1016/j.commatsci.2022.111975
- Yao Lu, Dong Wei, Wu Liu, Juan Meng, Xiaomin Huo, Yu Zhang, Zhiqin Liang, Bo Qiao, Suling Zhao, Dandan Song, Zheng Xu. Predicting the device performance of the perovskite solar cells from the experimental parameters through machine learning of existing experimental results. Journal of Energy Chemistry 2023, 77 , 200-208. https://doi.org/10.1016/j.jechem.2022.10.024
- Qianwen Wei, Mehri Ghasemi, Rongfei Wang, Chong Wang, Juan Wang, Weijie Zhou, Baohua Jia, Yu Yang, Xiaoming Wen. Metal Halide Perovskite Alloy: Fundamental, Optoelectronic Properties and Applications. Advanced Photonics Research 2023, 4 (2) https://doi.org/10.1002/adpr.202200236
- Yunxia Zhang, Yucheng Liu, Shengzhong (Frank) Liu. Composition Engineering of Perovskite Single Crystals for High‐Performance Optoelectronics. Advanced Functional Materials 2023, 33 (9) https://doi.org/10.1002/adfm.202210335
- Rong Lu, Zhangchuan Wen, Mei Zhao, Jun Li, Lijie Zhang, Yun Yang, Huile Jin, Yihuang Chen, Shun Wang, Shuang Pan. Spacer Cation Alloying Enables Markedly Improved Chiroptical Properties of Two‐Dimensional Chiral Hybrid Perovskite Nanosheets. Advanced Optical Materials 2023, 11 (4) https://doi.org/10.1002/adom.202202290
- Yunjie Lou, Shasha Zhang, Zhenkun Gu, Na Wang, Shiheng Wang, Yiqiang Zhang, Yanlin Song. Perovskite single crystals: Dimensional control, optoelectronic properties, and applications. Materials Today 2023, 62 , 225-250. https://doi.org/10.1016/j.mattod.2022.11.009
- Feng Li. Single-Crystal Halide Perovskites for Transistor Applications. 2023, 265-296. https://doi.org/10.1007/978-3-031-26892-2_13
- Kaiyu Wang, Feitong Chen, Qing Yao, Jie Zhang, Huiling Zhu, Weiwei Zhang, Xiaoyuan Zhan, Shenglai Wang, Jianxu Ding. Synergistic enhancement of the optoelectronic performance and stability of MA and Cs in FA x MA y Cs 1− x − y PbI z Br 3− z single crystals. Journal of Materials Chemistry C 2023, 131 https://doi.org/10.1039/D3TC01380D
- Anshebo Getachew Alemu, Teketel Alemu. Recent Development of Lead-Free Perovskite Solar Cells. 2022https://doi.org/10.5772/intechopen.105046
- Liang Chen, Jin Wook Yoo, Manman Hu, Seung‐Un Lee, Sang Il Seok. Intrinsic Phase Stability and Inherent Bandgap of Formamidinium Lead Triiodide Perovskite Single Crystals. Angewandte Chemie International Edition 2022, 61 (50) https://doi.org/10.1002/anie.202212700
- Liang Chen, Jin Wook Yoo, Manman Hu, Seung‐Un Lee, Sang Il Seok. Intrinsic Phase Stability and Inherent Bandgap of Formamidinium Lead Triiodide Perovskite Single Crystals. Angewandte Chemie 2022, 134 (50) https://doi.org/10.1002/ange.202212700
- Huan Zhang, Juan Xing, Zhujiang Dai, Daorong Wang, Dong Tang. Exosomes: the key of sophisticated cell–cell communication and targeted metastasis in pancreatic cancer. Cell Communication and Signaling 2022, 20 (1) https://doi.org/10.1186/s12964-021-00808-w
- Haiyan Wang, Yu Sun, Jin Chen, Fengchao Wang, Ruiyi Han, Canyun Zhang, Jinfang Kong, Lan Li, Jing Yang. A Review of Perovskite-Based Photodetectors and Their Applications. Nanomaterials 2022, 12 (24) , 4390. https://doi.org/10.3390/nano12244390
- Wen-Cheng Qiao, Jia-Qi Liang, Wei Dong, Kaiyang Ma, Xue Lu Wang, Ye-Feng Yao. Formamidinium lead triiodide perovskites with improved structural stabilities and photovoltaic properties obtained by ultratrace dimethylamine substitution. NPG Asia Materials 2022, 14 (1) https://doi.org/10.1038/s41427-022-00395-3
- Tao Zuo, Fangfang Qi, ChiYung Yam, Lingyi Meng. Lead-free all-inorganic halide double perovskite materials for optoelectronic applications: progress, performance and design. Physical Chemistry Chemical Physics 2022, 24 (44) , 26948-26961. https://doi.org/10.1039/D2CP03463H
- Fernando B. Minussi, Eduardo M. Bertoletti, José A. Eiras, Eudes B. Araújo. Intrinsic aging in mixed-cation lead halide perovskites. Sustainable Energy & Fuels 2022, 6 (21) , 4925-4937. https://doi.org/10.1039/D2SE00828A
- Yong Hui, En-Ming You, Qing-Peng Luo, Tan Wang, Zi-Ang Nan, Yu Gu, Wen-Han Zhang, Zhuan-Yun Cai, Liang Chen, Jian-Zhang Zhou, Jia-Wei Yan, Zhao-Xiong Xie, Bing-Wei Mao, Zhong-Qun Tian. Efficient plasmon-enhanced perovskite solar cells by molecularly isolated gold nanorods. Journal of Energy Chemistry 2022, 73 , 60-67. https://doi.org/10.1016/j.jechem.2022.05.015
- Huimin Xiang, Pengyun Liu, Ran Ran, Wei Wang, Wei Zhou, Zongping Shao. Two-dimensional Dion-Jacobson halide perovskites as new-generation light absorbers for perovskite solar cells. Renewable and Sustainable Energy Reviews 2022, 166 , 112614. https://doi.org/10.1016/j.rser.2022.112614
- Hu Zhang, Zhiliang Chen, Yanhui Li, Jianfeng Yao, Duanwangde Liu, Wei Zeng, Pengbin Gui, Zhixiang Huang. A high-performance self-powered photodetector based on a concentric annular α-FAPbI 3 /MAPbI 3 single crystal lateral heterojunction with broadband detectivity. Journal of Materials Chemistry C 2022, 10 (33) , 11903-11913. https://doi.org/10.1039/D2TC02686D
- Jizhong Jiang, Min Xiong, Ke Fan, Chunxiong Bao, Deyu Xin, Zhengwei Pan, Linfeng Fei, Haitao Huang, Lang Zhou, Kai Yao, Xiaojia Zheng, Liang Shen, Feng Gao. Synergistic strain engineering of perovskite single crystals for highly stable and sensitive X-ray detectors with low-bias imaging and monitoring. Nature Photonics 2022, 16 (8) , 575-581. https://doi.org/10.1038/s41566-022-01024-9
- Luisa De Marco, Giuseppe Nasti, Antonio Abate, Aurora Rizzo. Perovskite Single‐Crystal Solar Cells: Advances and Challenges. Solar RRL 2022, 6 (7) https://doi.org/10.1002/solr.202101085
- Xue Dong, Lingfeng Chao, Tingting Niu, Yiyun Li, Peiyao Guo, Wei Hui, Lin Song, Zhongbin Wu, Yonghua Chen. Phase‐Pure Engineering for Efficient and Stable Formamidinium‐Based Perovskite Solar Cells. Solar RRL 2022, 6 (7) https://doi.org/10.1002/solr.202200060
- Muhammed Hamdan, Manasa Manoj, Jigar Shaileshkumar Halpati, Aravind Kumar Chandiran. Acid‐ and Base‐Stable Cs 2 Pt(Cl,Br) 6 Vacancy‐Ordered Double Perovskites and Their Core–Shell Heterostructures for Solar Water Oxidation. Solar RRL 2022, 6 (7) https://doi.org/10.1002/solr.202101092
- Daewon Lee, Ju Ye kim, Lee Seul Oh, Hyun Woo Kim, Youngmin Kim, Wongeun Yoon, Eunho Lim, Won Bae Kim, Jong Hyeok Park, Hyung Ju Kim. Revealing improved electrocatalytic performances of electrochemically synthesized S and Ni doped Fe2O3 nanostructure interfaces. Applied Surface Science 2022, 588 , 152894. https://doi.org/10.1016/j.apsusc.2022.152894
- Feng Li, Tiebin Yang, Rongkun Zheng. Solution-processed perovskite crystals for electronics: Moving forward. Matter 2022, 5 (6) , 1700-1733. https://doi.org/10.1016/j.matt.2022.04.022
- Lili Xu, Gaoyu Liu, Hengyang Xiang, Run Wang, Qingsong Shan, Shichen Yuan, Bo Cai, Zhi Li, Weijin Li, Shengli Zhang, Haibo Zeng. Charge-carrier dynamics and regulation strategies in perovskite light-emitting diodes: From materials to devices. Applied Physics Reviews 2022, 9 (2) https://doi.org/10.1063/5.0080087
- Prerna, Sandeep Arya. Advanced Synthesis Strategies for Single Crystal Perovskite Halides. 2022, 91-121. https://doi.org/10.1002/9781119763376.ch4
- Yipeng Han, Haibing Xie, Eng Liang Lim, Dongqin Bi. Review of Two‐Step Method for Lead Halide Perovskite Solar Cells. Solar RRL 2022, 6 (6) https://doi.org/10.1002/solr.202101007
- Shamim Shahrokhi, Milos Dubajic, Zhi‐Zhan Dai, Saroj Bhattacharyya, Richard A. Mole, Kirrily C. Rule, Mohan Bhadbhade, Ruoming Tian, Nursultan Mussakhanuly, Xinwei Guan, Yuewei Yin, Michael P. Nielsen, Long Hu, Chun‐Ho Lin, Shery L. Y. Chang, Danyang Wang, Irina V. Kabakova, Gavin Conibeer, Stephen Bremner, Xiao‐Guang Li, Claudio Cazorla, Tom Wu. Anomalous Structural Evolution and Glassy Lattice in Mixed‐Halide Hybrid Perovskites. Small 2022, 18 (21) https://doi.org/10.1002/smll.202200847
- Hassan Kassem, Alireza Salehi, Mojtaba Kahrizi, Hamid Mirzanejad, Amin Hedayati, Behnam Khorasani. Poly( N , N ′‐bis‐4‐butylphenyl‐ N , N ′‐biphenyl)benzidine as Interfacial Passivator for Dopant‐Free P3HT Hole Transport Layer‐Based Perovskite Solar Cell in Regular Mesoscopic Architecture. Energy Technology 2022, 10 (5) https://doi.org/10.1002/ente.202100956
- Youbin Song, Ji-Sang Park. Hybrid density functional theory calculation of orthorhombic CsPbI3−3Br3 and CsPbBr3−3Cl3. Current Applied Physics 2022, 36 , 93-96. https://doi.org/10.1016/j.cap.2022.01.010
- Bobo Zhang, Zhuo Xu, Chuang Ma, Haojin Li, Yucheng Liu, Lili Gao, Jing Zhang, Jiaxue You, Shengzhong (Frank) Liu. First‐Principles Calculation Design for 2D Perovskite to Suppress Ion Migration for High‐Performance X‐ray Detection. Advanced Functional Materials 2022, 32 (15) https://doi.org/10.1002/adfm.202110392
- Rasmus Tranås, Ole Martin Løvvik, Kristian Berland. Attaining Low Lattice Thermal Conductivity in Half-Heusler Sublattice Solid Solutions: Which Substitution Site Is Most Effective?. Electronic Materials 2022, 3 (1) , 1-14. https://doi.org/10.3390/electronicmat3010001
- Fan Yu, Jian Liu, Jiahao Huang, Pan Xu, Cheng-Hui Li, You-Xuan Zheng, Hairen Tan, Jing-Lin Zuo. Efficient and Stable Wide‐Bandgap Perovskite Solar Cells Derived from a Thermodynamic Phase‐Pure Intermediate. Solar RRL 2022, 6 (2) https://doi.org/10.1002/solr.202100906
- Ning Li, Anbo Feng, Xinbo Guo, Jinming Wu, Shengdan Xie, Qinglian Lin, Xiaomei Jiang, Yang Liu, Zhaolai Chen, Xutang Tao. Engineering the Hole Extraction Interface Enables Single‐Crystal MAPbI 3 Perovskite Solar Cells with Efficiency Exceeding 22% and Superior Indoor Response. Advanced Energy Materials 2022, 12 (7) https://doi.org/10.1002/aenm.202103241
- Lei Gao, Kezheng Tao, Jia‐Lin Sun, Qingfeng Yan. Gamma‐Ray Radiation Stability of Mixed‐Cation Lead Mixed‐Halide Perovskite Single Crystals. Advanced Optical Materials 2022, 10 (3) https://doi.org/10.1002/adom.202102069
- Jianxiu Hao, Xing Xiao. Recent Development of Optoelectronic Application Based on Metal Halide Perovskite Nanocrystals. Frontiers in Chemistry 2022, 9 https://doi.org/10.3389/fchem.2021.822106
- Daewon Lee, Ju Ye kim, Lee Seul Oh, Hyun Woo Kim, Youngmin Kim, Wongeun Yoon, Eunho Lim, Won Bae Kim, Jong Hyeok Park, Hyung Ju Kim. Revealing improved electrocatalytic performances of electrochemically synthesized S and Ni doped Fe2O3 nanostructure interfaces. Applied Surface Science 2022, 355 , 152401. https://doi.org/10.1016/j.apsusc.2021.152401
- Shurong Wang, Aili Wang, Feng Hao. Toward stable lead halide perovskite solar cells: A knob on the A/X sites components. iScience 2022, 25 (1) , 103599. https://doi.org/10.1016/j.isci.2021.103599
- Yanmin Huang, Xiaojuan Lei, Tingwei He, Yuanzhi Jiang, Mingjian Yuan. Recent Progress on Formamidinium‐Dominated Perovskite Photovoltaics. Advanced Energy Materials 2022, 12 (4) https://doi.org/10.1002/aenm.202100690
- Ting-Xiao Qin, En-Ming You, Mao-Xin Zhang, Peng Zheng, Xiao-Feng Huang, Song-Yuan Ding, Bing-Wei Mao, Zhong-Qun Tian. Quantification of electron accumulation at grain boundaries in perovskite polycrystalline films by correlative infrared-spectroscopic nanoimaging and Kelvin probe force microscopy. Light: Science & Applications 2021, 10 (1) https://doi.org/10.1038/s41377-021-00524-7
- Anna Capitaine, Beniamino Sciacca. Monocrystalline Methylammonium Lead Halide Perovskite Materials for Photovoltaics. Advanced Materials 2021, 33 (52) https://doi.org/10.1002/adma.202102588
- Dong-Hyeok Choi, Hae-Jun Seok, Su-Kyung Kim, Do-Hyung Kim, Bo Hou, Han-Ki Kim. The Effect of Cs/FA Ratio on the Long‐Term Stability of Mixed Cation Perovskite Solar Cells. Solar RRL 2021, 5 (12) https://doi.org/10.1002/solr.202100660
- Mi-Hee Jung. Formation of cubic perovskite alloy containing the ammonium cation of 2D perovskite for high performance solar cells with improved stability. RSC Advances 2021, 11 (52) , 32590-32603. https://doi.org/10.1039/D1RA04520B
- Tianju Chen, Peng Zhang, Guoliang Chen, Qi Yang, Feiming Li. Improving Stability and Colloidal Dispersity of CsPbBr3@SiO2 Nanoparticles Based on In-Situ Synthesis in Entropy Ligands Functionalized SiO2 Nanoreactor. Crystals 2021, 11 (10) , 1165. https://doi.org/10.3390/cryst11101165
- Jianjun Zhang, Xiaohe Li, Linxi Wang, Jiaguo Yu, S. Wageh, Ahmed A. Al-Ghamdi. Enhanced performance of CH3NH3PbI3 perovskite solar cells by excess halide modification. Applied Surface Science 2021, 564 , 150464. https://doi.org/10.1016/j.apsusc.2021.150464
- Lukas Schmidt-Mende, Vladimir Dyakonov, Selina Olthof, Feray Ünlü, Khan Moritz Trong Lê, Sanjay Mathur, Andrei D. Karabanov, Doru C. Lupascu, Laura M. Herz, Alexander Hinderhofer, Frank Schreiber, Alexey Chernikov, David A. Egger, Oleksandra Shargaieva, Caterina Cocchi, Eva Unger, Michael Saliba, Mahdi Malekshahi Byranvand, Martin Kroll, Frederik Nehm, Karl Leo, Alex Redinger, Julian Höcker, Thomas Kirchartz, Jonathan Warby, Emilio Gutierrez-Partida, Dieter Neher, Martin Stolterfoht, Uli Würfel, Moritz Unmüssig, Jan Herterich, Clemens Baretzky, John Mohanraj, Mukundan Thelakkat, Clément Maheu, Wolfram Jaegermann, Thomas Mayer, Janek Rieger, Thomas Fauster, Daniel Niesner, Fengjiu Yang, Steve Albrecht, Thomas Riedl, Azhar Fakharuddin, Maria Vasilopoulou, Yana Vaynzof, Davide Moia, Joachim Maier, Marius Franckevičius, Vidmantas Gulbinas, Ross A. Kerner, Lianfeng Zhao, Barry P. Rand, Nadja Glück, Thomas Bein, Fabio Matteocci, Luigi Angelo Castriotta, Aldo Di Carlo, Matthias Scheffler, Claudia Draxl. Roadmap on organic–inorganic hybrid perovskite semiconductors and devices. APL Materials 2021, 9 (10) https://doi.org/10.1063/5.0047616
- Kezheng Tao, Lei Gao, Qingfeng Yan. Ternary Hybrid Perovskite Solid Solution Single Crystals: Growth, Composition Determination and Phase Stability in Highly Moist Atmosphere. Chemistry – A European Journal 2021, 27 (55) , 13765-13773. https://doi.org/10.1002/chem.202101655
- Zi-Ang Nan, Liang Chen, Qi Liu, Su-Heng Wang, Zhi-Xin Chen, Shao-Yu Kang, Jia-Bao Ji, Yan-Yan Tan, Yong Hui, Jia-Wei Yan, Zhao-Xiong Xie, Wan-Zhen Liang, Bing-Wei Mao, Zhong-Qun Tian. Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase. Chem 2021, 7 (9) , 2513-2526. https://doi.org/10.1016/j.chempr.2021.07.011
- Eve M. Mozur, James R. Neilson. Cation Dynamics in Hybrid Halide Perovskites. Annual Review of Materials Research 2021, 51 (1) , 269-291. https://doi.org/10.1146/annurev-matsci-080819-012808
- Yusheng Lei, Yimu Chen, Sheng Xu. Single-crystal halide perovskites: Opportunities and challenges. Matter 2021, 4 (7) , 2266-2308. https://doi.org/10.1016/j.matt.2021.05.002
- Lin Ma, Wanpeng Li, Kaixiang Yang, Jianjun Bi, Jicun Feng, Jiabei Zhang, Zhengguang Yan, Xiaoyuan Zhou, Cuixiu Liu, Yuan Ji, Jacob C. Huang, Xiaodong Han. A - or X -site mixture on mechanical properties of A Pb X 3 perovskite single crystals. APL Materials 2021, 9 (4) , 041112. https://doi.org/10.1063/5.0015569
- Yucheng Liu, Yunxia Zhang, Xuejie Zhu, Zhou Yang, Weijun Ke, Jiangshan Feng, Xiaodong Ren, Kui Zhao, Ming Liu, Mercouri G. Kanatzidis, Shengzhong (Frank) Liu. Inch-sized high-quality perovskite single crystals by suppressing phase segregation for light-powered integrated circuits. Science Advances 2021, 7 (7) https://doi.org/10.1126/sciadv.abc8844
- Yucheng Liu, Yunxia Zhang, Xuejie Zhu, Jiangshan Feng, Ioannis Spanopoulos, Weijun Ke, Yihui He, Xiaodong Ren, Zhou Yang, Fengwei Xiao, Kui Zhao, Mercouri Kanatzidis, Shengzhong (Frank) Liu. Triple‐Cation and Mixed‐Halide Perovskite Single Crystal for High‐Performance X‐ray Imaging. Advanced Materials 2021, 33 (8) https://doi.org/10.1002/adma.202006010
- Shuang Chen, Lu Pan, Tao Ye, Nuo Lei, Yijun Yang, Xi Wang. The lattice reconstruction of Cs-introduced FAPbI 1.80 Br 1.20 enables improved stability for perovskite solar cells. RSC Advances 2021, 11 (7) , 3997-4005. https://doi.org/10.1039/D0RA09294K
- 莹 毕. Preparation of CsPbBr3 Perovskite Single Crystal and Research on Its Photodetector. Applied Physics 2021, 11 (12) , 445-452. https://doi.org/10.12677/APP.2021.1112053
- Taiyang Zhang, Yuetian Chen, Miao Kan, Shumao Xu, Yanfeng Miao, Xingtao Wang, Meng Ren, Haoran Chen, Xiaomin Liu, Yixin Zhao. MA Cation-Induced Diffusional Growth of Low-Bandgap FA-Cs Perovskites Driven by Natural Gradient Annealing. Research 2021, 2021 https://doi.org/10.34133/2021/9765106
- Daewon Lee, Ju Ye Kim, Lee Seul Oh, Hyun Woo Kim, Youngmin Kim, Wongeun Yoon, Eunho Lim, Won Bae Kim, Jong Hyeok Park, Hyung Ju Kim. Revealing Improved Electrocatalytic Performances of Electrochemically Synthesized S and Ni Doped Fe 2O 3 Nanostructure Interfaces. SSRN Electronic Journal 2021, 4 https://doi.org/10.2139/ssrn.3985130