Double-Circularly Connected Saloph-Belt Macrocycles Generated from a Bis-Armed Bifunctional Monomer
- Takashi NakamuraTakashi NakamuraGraduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS), University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, JapanMore by Takashi Nakamura,
- Shinnosuke TsukudaShinnosuke TsukudaGraduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS), University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, JapanMore by Shinnosuke Tsukuda, and
- Tatsuya Nabeshima*Tatsuya Nabeshima*[email protected]Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS), University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, JapanMore by Tatsuya Nabeshima
Abstract
Belt-shaped macrocycles possessing saloph units as their walls have been generated by the double-circular connection of a bis-armed bifunctional monomer bearing both o-phenylenediamine and salicylaldehyde functionalities. The saloph-belt macrocycles showed unique properties, such as the selective inclusion of fullerenes (Ka(C70)/Ka(C60) > 100), utilizing their rigid scaffolds.
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