Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers
- Liyuan QuLiyuan QuDepartment of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Sendai 980-8578, JapanMore by Liyuan Qu,
- Hiroaki Iguchi*Hiroaki Iguchi*[email protected] (H.I.)Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Sendai 980-8578, JapanMore by Hiroaki Iguchi,
- Shinya TakaishiShinya TakaishiDepartment of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Sendai 980-8578, JapanMore by Shinya Takaishi,
- Faiza HabibFaiza HabibDepartment of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Sendai 980-8578, JapanMore by Faiza Habib,
- Chanel F. LeongChanel F. LeongSchool of Chemistry, The University of Sydney, Sydney, New South Wales 2006, AustraliaMore by Chanel F. Leong,
- Deanna M. D’AlessandroDeanna M. D’AlessandroSchool of Chemistry, The University of Sydney, Sydney, New South Wales 2006, AustraliaMore by Deanna M. D’Alessandro,
- Takefumi YoshidaTakefumi YoshidaElectronic Functional Macromolecules Group, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, JapanMore by Takefumi Yoshida,
- Hitoshi AbeHitoshi AbeInstitute of Materials Structure Science High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki 305-0801, JapanDepartment of Materials Structure Science, School of High Energy Accelerator Science, SOKENDAI (the Graduate University for Advanced Studies), 1-1 Oho, Tsukuba, Ibaraki 305-0801, JapanMore by Hitoshi Abe,
- Eiji NishiboriEiji NishiboriDivision of Physics, Faculty of Pure and Applied Sciences & Tsukuba Research Center for Energy Materials Science (TREMS), University of Tsukuba, Tsukuba, Ibaraki 305-8571, JapanMore by Eiji Nishibori, and
- Masahiro Yamashita*Masahiro Yamashita*[email protected] (M.Y.)Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Sendai 980-8578, JapanAdvanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, JapanSchool of Materials Science and Engineering, Nankai University, Tianjin 300350, ChinaMore by Masahiro Yamashita
Abstract
The first porous molecular conductor (PMC), which exhibits porosity, a through-space conduction pathway and rich charge carriers (electrons), was prepared through electrocrystallization from Cd2+ and N,N′-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxdiimide (NDI-py). [Cd(NDI-py)(OH2)4](NO3)1.3±0.1·nDMA (PMC-1) was assembled by π–π stacking among one-dimensional (1D) linear coordination polymers. The NDI cores were partially reduced into radical anions to form conductive π-stacked columns, yielding (1.0–3.3) × 10–3 S cm–1 at room temperature. Moreover, the electrical conductivity was significantly enhanced by removing the solvent molecules from PMC-1, indicating that PMCs are promising as molecule-responsive conductive materials.
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