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Unconventional Method for Fabricating Valence Tautomeric Materials: Integrating Redox Center within a Metal–Organic Framework

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    Unconventional Method for Fabricating Valence Tautomeric Materials: Integrating Redox Center within a Metal–Organic Framework
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    • Bao Li*
      Bao Li
      Key Laboratory of Material Chemistry for Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, People’s Republic of China
      Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, United States
      *[email protected]
      More by Bao Li
      Orcidhttp://orcid.org/0000-0003-1154-6423
    • Yu-Meng Zhao
      Yu-Meng Zhao
      Key Laboratory of Material Chemistry for Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, People’s Republic of China
      More by Yu-Meng Zhao
    • Angelo Kirchon
      Angelo Kirchon
      Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, United States
      More by Angelo Kirchon
    • Jian-Dong Pang
      Jian-Dong Pang
      Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, United States
      More by Jian-Dong Pang
    • Xin-Yu Yang
      Xin-Yu Yang
      Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, United States
      More by Xin-Yu Yang
    • Gui-Lin Zhuang*
      Gui-Lin Zhuang
      Institute of Industrial Catalysis, College of Chemical Engineering, Zhejiang University of Technology, Zhejiang 310023, People’s Republic of China
      *[email protected]
      More by Gui-Lin Zhuang
      Orcidhttp://orcid.org/0000-0002-4763-7397
    • Hong-Cai Zhou*
      Hong-Cai Zhou
      Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, United States
      Department of Materials Science and Engineering, Texas A&M University, College Station, Texas 77842, United States
      *[email protected]
      More by Hong-Cai Zhou
      Orcidhttp://orcid.org/0000-0002-9029-3788
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2019, 141, 17, 6822–6826
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    https://doi.org/10.1021/jacs.9b02375
    Published April 15, 2019
    Copyright © 2019 American Chemical Society
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    Abstract

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    Due to the structural advantages displayed by Metal–Organic Frameworks (MOFs), integrating Valence Tautomerism (VT) systems within MOFs could be an effective strategy in order to break through the constraints of the traditional ones. Herein, we report the first successful integration of a VT system into a MOF termed VT-MOF-1. The structural characteristics of VT-MOF-1, such as dinuclear cobalt-catechol clusters and solvent-accessible pores, are both innovative and novel, potentially yielding new vitality within VT field. In addition, VT-MOF-1 exhibits specific behaviors responsive to temperature and different solvent molecules as n-butanol, tert-butanol, and isopropyl alcohol. The entropy values and configurations of the solvent molecules might be responsible for the tunable sensing behaviors.

    Copyright © 2019 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.9b02375.

    • Detailed experimental methods, crystal data, theoretical calculation methods and results (PDF)

    • Data for C68H77Co2N4O6 (CIF)

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    Cited By

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    Cite this: J. Am. Chem. Soc. 2019, 141, 17, 6822–6826
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jacs.9b02375
    Published April 15, 2019
    Copyright © 2019 American Chemical Society
    Request reuse permissions

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