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Post-assembly Modification of Phosphine Cages Controls Host–Guest Behavior

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    Post-assembly Modification of Phosphine Cages Controls Host–Guest Behavior
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2019, 141, 17, 6837–6842
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    https://doi.org/10.1021/jacs.9b02604
    Published April 16, 2019
    Copyright © 2019 American Chemical Society
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    Abstract

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    We report the design, synthesis, and post-assembly modification of a new phosphine-paneled supramolecular cage framework, the anion binding ability of which can be modified rationally through selective post-assembly functionalization. The parent phosphine-paneled cage can be modified in situ through oxidation, methylation, or auration. These covalent and coordinative modifications to the exterior of the cage strongly influence the guest-binding properties of the host.

    Copyright © 2019 American Chemical Society

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.9b02604.

    • Detailed descriptions of synthetic procedures, characterization of new compounds, and spectroscopic data, including Figures S1–S119 and Tables S1 and S2 (PDF)

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    This article is cited by 48 publications.

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    Cite this: J. Am. Chem. Soc. 2019, 141, 17, 6837–6842
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jacs.9b02604
    Published April 16, 2019
    Copyright © 2019 American Chemical Society
    Request reuse permissions

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