Reversible Solid-State Isomerism of Azobenzene-Loaded Large-Pore Isoreticular Mg-CUK-1
- Junpeng HeJunpeng HeDepartment of Chemistry, University of Texas at Austin, Austin, Texas 78712, United StatesMore by Junpeng He
- ,
- Kanchan AggarwalKanchan AggarwalDepartment of Chemistry, University of Texas at Austin, Austin, Texas 78712, United StatesMore by Kanchan Aggarwal
- ,
- Naman KatyalNaman KatyalDepartment of Chemistry, University of Texas at Austin, Austin, Texas 78712, United StatesMore by Naman Katyal
- ,
- Shichao HeShichao HeDepartment of Chemistry, University of Texas at Austin, Austin, Texas 78712, United StatesMore by Shichao He
- ,
- Edward ChiangEdward ChiangDepartment of Chemistry, University of Texas at Austin, Austin, Texas 78712, United StatesMore by Edward Chiang
- ,
- Samuel G. DunningSamuel G. DunningDepartment of Chemistry, University of Texas at Austin, Austin, Texas 78712, United StatesMore by Samuel G. Dunning
- ,
- Joseph E. Reynolds IIIJoseph E. Reynolds, IIIDepartment of Chemistry, University of Texas at Austin, Austin, Texas 78712, United StatesMore by Joseph E. Reynolds, III
- ,
- Alexander SteinerAlexander SteinerDepartment of Chemistry, University of Liverpool, Crown Street, Liverpool L69 7ZD, U.K.More by Alexander Steiner
- ,
- Graeme Henkelman*Graeme Henkelman*[email protected]Department of Chemistry, University of Texas at Austin, Austin, Texas 78712, United StatesMore by Graeme Henkelman
- ,
- Emily L. Que*Emily L. Que*[email protected]Department of Chemistry, University of Texas at Austin, Austin, Texas 78712, United StatesMore by Emily L. Que
- , and
- Simon M. Humphrey*Simon M. Humphrey*[email protected]Department of Chemistry, University of Texas at Austin, Austin, Texas 78712, United StatesMore by Simon M. Humphrey
Abstract
A large-pore version of Mg-CUK-1, a water-stable metal–organic framework (MOF) with 1-D channels, was synthesized in basic water. Mg-CUK-1L has a BET surface area of 2896 m2 g–1 and shows stark selectivity for CO2 sorption over N2, O2, H2, and CH4. It displays reversible, multistep gated sorption of CO2 below 0.33 atm. The dehydrated single-crystal structure of Mg-CUK-1L confirms retention of the open-channel structure. The MOF can be loaded with organic molecules by immersion in hot melts, providing single crystals suitable for X-ray diffraction. trans-Azobenzene fills the channels in a 2 × 2 arrangement. Solid-state UV–vis spectroscopy reveals that azobenzene molecules undergo reversible trans–cis isomerization, despite being close-packed; this surprising result is confirmed by DFT-simulated UV–vis spectra.
Cited By
This article is cited by 17 publications.
- Samuel G. Dunning, Nishesh Kumar Gupta, Joseph E. Reynolds, III, Mónica Sagastuy-Breña, J. Gabriel Flores, Eva Martínez-Ahumada, Elí Sánchez-González, Vincent M. Lynch, Aída Gutiérrez-Alejandre, Julia Aguilar-Pliego, Kwang-Soo Kim, Ilich A. Ibarra, Simon M. Humphrey. Mn-CUK-1: A Flexible MOF for SO2, H2O, and H2S Capture. Inorganic Chemistry 2022, 61
(38)
, 15037-15044. https://doi.org/10.1021/acs.inorgchem.2c02012
- Hannah F. Drake, Zhifeng Xiao, Gregory S. Day, Shaik Waseem Vali, Luke L. Daemen, Yongqiang Cheng, Peiyu Cai, Jason E. Kuszynski, Hengyu Lin, Hong-Cai Zhou, Matthew R. Ryder. Influence of Metal Identity on Light-Induced Switchable Adsorption in Azobenzene-Based Metal–Organic Frameworks. ACS Applied Materials & Interfaces 2022, 14
(9)
, 11192-11199. https://doi.org/10.1021/acsami.1c18266
- Shanelle Suepaul, Katherine A. Forrest, Peter A. Georgiev, Paul M. Forster, Wiebke Lohstroh, Veronika Grzimek, Samuel G. Dunning, Joseph E. Reynolds III, Simon M. Humphrey, Juergen Eckert, Brian Space, Tony Pham. Investigating H2 Adsorption in Isostructural Metal–Organic Frameworks M-CUK-1 (M = Co and Mg) through Experimental and Theoretical Studies. ACS Applied Materials & Interfaces 2022, 14
(6)
, 8126-8136. https://doi.org/10.1021/acsami.1c20312
- Shi‐Chao Qi, Yong‐Lan Liu, Xiao‐Jie Lu, Yun‐Jie Zhao, Jia‐Xin Li, Xiao‐Qin Liu, Lin‐Bing Sun. Enhanced CO Adsorption by Modulating the Electron Density Distribution of Graphite‐Copper Porphyrin Sorbents with Light. Angewandte Chemie 2023, 135
(27)
https://doi.org/10.1002/ange.202304367
- Shi‐Chao Qi, Yong‐Lan Liu, Xiao‐Jie Lu, Yun‐Jie Zhao, Jia‐Xin Li, Xiao‐Qin Liu, Lin‐Bing Sun. Enhanced CO Adsorption by Modulating the Electron Density Distribution of Graphite‐Copper Porphyrin Sorbents with Light. Angewandte Chemie International Edition 2023, 62
(27)
https://doi.org/10.1002/anie.202304367
- Shi-Chao Qi, Zhen Sun, Zhi-Hui Yang, Yun-Jie Zhao, Jia-Xin Li, Xiao-Qin Liu, Lin-Bing Sun. Photo-Responsive Carbon Capture over Metalloporphyrin-C
60
Metal-Organic Frameworks via Charge-Transfer. Research 2023, 6 https://doi.org/10.34133/research.0261
- Bhart Kumar, Abhik Paul, Dibya Jyoti Mondal, Piyush Paliwal, Sanjit Konar. Spin‐State Modulation in Fe
II
‐Based Hofmann‐Type Coordination Polymers: From Molecules to Materials. The Chemical Record 2022, 22
(11)
https://doi.org/10.1002/tcr.202200135
- Kieran Griffiths, Nathan R. Halcovitch, John M. Griffin. Efficient solid-state photoswitching of methoxyazobenzene in a metal–organic framework for thermal energy storage. Chemical Science 2022, 13
(10)
, 3014-3019. https://doi.org/10.1039/D2SC00632D
- Hannah F. Drake, Gregory S. Day, Zhifeng Xiao, Hong-Cai Zhou, Matthew R. Ryder. Light-induced switchable adsorption in azobenzene- and stilbene-based porous materials. Trends in Chemistry 2022, 4
(1)
, 32-47. https://doi.org/10.1016/j.trechm.2021.11.003
- Kai‐Ping Xie, Ze‐Yu Ruan, Bang‐Heng Lyu, Xiao‐Xian Chen, Xue‐Wen Zhang, Guo‐Zhang Huang, Yan‐Cong Chen, Zhao‐Ping Ni, Ming‐Liang Tong. Guest‐Driven Light‐Induced Spin Change in an Azobenzene Loaded Metal–Organic Framework. Angewandte Chemie 2021, 133
(52)
, 27350-27356. https://doi.org/10.1002/ange.202113294
- Kai‐Ping Xie, Ze‐Yu Ruan, Bang‐Heng Lyu, Xiao‐Xian Chen, Xue‐Wen Zhang, Guo‐Zhang Huang, Yan‐Cong Chen, Zhao‐Ping Ni, Ming‐Liang Tong. Guest‐Driven Light‐Induced Spin Change in an Azobenzene Loaded Metal–Organic Framework. Angewandte Chemie International Edition 2021, 60
(52)
, 27144-27150. https://doi.org/10.1002/anie.202113294
- Gabrielle A. Leith, Corey R. Martin, Jacob M. Mayers, Preecha Kittikhunnatham, Randy W. Larsen, Natalia B. Shustova. Confinement-guided photophysics in MOFs, COFs, and cages. Chemical Society Reviews 2021, 50
(7)
, 4382-4410. https://doi.org/10.1039/D0CS01519A
- Jing Sun, Chao Ma, Sourav Maity, Fan Wang, Yu Zhou, Giuseppe Portale, Robert Göstl, Wouter H. Roos, Hongjie Zhang, Kai Liu, Andreas Herrmann. Reversibly Photo‐Modulating Mechanical Stiffness and Toughness of Bioengineered Protein Fibers. Angewandte Chemie 2021, 133
(6)
, 3259-3265. https://doi.org/10.1002/ange.202012848
- Jing Sun, Chao Ma, Sourav Maity, Fan Wang, Yu Zhou, Giuseppe Portale, Robert Göstl, Wouter H. Roos, Hongjie Zhang, Kai Liu, Andreas Herrmann. Reversibly Photo‐Modulating Mechanical Stiffness and Toughness of Bioengineered Protein Fibers. Angewandte Chemie International Edition 2021, 60
(6)
, 3222-3228. https://doi.org/10.1002/anie.202012848
- Stephanie L. White, Micah W. Heinz, Simon M. Humphrey. Methods and Diversity in the Synthesis of Metal-Organic Frameworks. 2021, 976-1020. https://doi.org/10.1016/B978-0-08-102688-5.00086-6
- Mengyu Deng, Yangdaiyi Zhang, Yufei Wang, Shimei Jiang. Polymeric nanoparticles based on CDs with photoreversible dual-color fluorescence modulation. Journal of Materials Chemistry C 2020, 8
(44)
, 15697-15704. https://doi.org/10.1039/D0TC03993D
- Xiaoxuan Wang, Zhaoxia Li, Haiying Zhao, Shufeng Chen. New azobenzene liquid crystal with dihydropyrazole heterocycle and photoisomerization studies. Royal Society Open Science 2020, 7
(7)
, 200474. https://doi.org/10.1098/rsos.200474