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Densities, Viscosities, and Excess Properties for Binary Mixtures of Some Glycols and Polyglycols in N-Methylacetamide at 308.15 K

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Department of Polymer Science and Technology and Department of Chemistry, Sri Krishnadevaraya University, Anantapur - 515 003, A. P., India
Cite this: J. Chem. Eng. Data 2003, 48, 3, 625–627
Publication Date (Web):March 14, 2003
https://doi.org/10.1021/je020178w
Copyright © 2003 American Chemical Society

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    Abstract

    Densities and viscosities have been measured at 308.15 K over the entire range of composition for N-methylacetamide with ethylene glycol, diethylene glycol, triethylene glycol, poly(ethylene glycol)-200, and poly(ethylene glycol)-300. From the experimental data, excess molar volumes (VE) and deviations in viscosity (Δη) have been calculated, and the deviations are fitted to a Redlich−Kister equation to obtain the binary coefficients and estimate the standard deviations between the experimental and calculated quantities. The values of VE are negative whereas the values of Δη are positive over the entire composition range.

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     Department of Polymer Science and Technology.

    *

     E-mail:  [email protected]. Fax No.:  (08554) 55244 (O).

     Department of Chemistry.

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