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Thermodynamic Properties of Mixtures Containing Ionic Liquids. 3. Liquid−Liquid Equilibria of Binary Mixtures of 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide with Propan-1-ol, Butan-1-ol, and Pentan-1-ol

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University of Rostock, Department of Physical Chemistry, D-18051 Rostock, Germany
Cite this: J. Chem. Eng. Data 2003, 48, 3, 472–474
Publication Date (Web):March 8, 2003
https://doi.org/10.1021/je0201931
Copyright © 2003 American Chemical Society

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    Abstract

    An apparatus for measuring liquid−liquid equilibria of small samples of liquid mixtures with relatively high differences in density and viscosity was applied for studying mixtures of the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and the three alcohols propan-1-ol, butan-1-ol, and pentan-1-ol. The synthetic method has been applied where cloud points at a given composition were determined by varying the temperature. The point of phase splitting was detected by light scattering. Data in the temperature range 281 K to 340 K have been obtained for the three systems.

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     This contribution will be part of a special print edition containing papers presented at the Workshop on Ionic Liquids at the 17th IUPAC Conference on Chemical Thermodynamics, Rostock, Germany, July 28 to August 2, 2002.

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     Corresponding author. Telephone:  +49-381-498-6500. Fax:  +49-381-498-6502. E-mail:  [email protected].

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