High-Pressure Vapor−Liquid Equilibria for CO2 + 2-Butanol, CO2 + Isobutanol, and CO2 + tert-Butanol Systems
View Author Information
Department of Chemical Engineering, National Cheng Kung University, Tainan, 70101, Taiwan
Abstract
In this study, the vapor−liquid equilibrium data of CO2 + isobutanol, CO2 + 2-butanol, and CO2 + tert-butanol systems were measured with an improved static-type phase equilibrium apparatus at temperatures of (331.9, 341.6, and 351.3) K and pressures from (50 to 120) bar. To ensure the accuracy and reliability of these measurements, the experimental data were compared with literature values, and these were found to be in quite good agreement. The mutual solubilities of CO2 + isomeric butanol systems decreased in the following order: CO2 + tert-butanol, CO2 + 2-butanol, and CO2 + isobutanol. The temperature and pressure effects on mutual solubilities between CO2 and isomeric butanols were also demonstrated and discussed.
*
Corresponding author. Fax: +886-6-2344496. E-mail: hueying@ mail.ncku.edu.tw.
Cited By
This article is cited by 16 publications.
- Jean-Noël Jaubert, Yohann Le Guennec, Andrés Piña-Martinez, Nicolas Ramirez-Velez, Silvia Lasala, Bastian Schmid, Ilias K. Nikolaidis, Ioannis G. Economou, Romain Privat. Benchmark Database Containing Binary-System-High-Quality-Certified Data for Cross-Comparing Thermodynamic Models and Assessing Their Accuracy. Industrial & Engineering Chemistry Research 2020, 59
(33)
, 14981-15027. https://doi.org/10.1021/acs.iecr.0c01734
- Mariana González Prieto, Francisco Adrián Sánchez, Selva Pereda. Multiphase Equilibria Modeling with GCA-EoS. Part II: Carbon Dioxide with the Homologous Series of Alcohols. Journal of Chemical & Engineering Data 2018, 63
(4)
, 920-934. https://doi.org/10.1021/acs.jced.7b00663
- M. O. Ferreira, L. Ferreira-Pinto, E. M. B. D. Souza, M. Castier, F. A. P. Voll, V. F. Cabral, and L. Cardozo-Filho . Experimental Vapor–Liquid Equilibria for the Systems {2-Ethyl-1-hexanol + Glycerol + CO2} and {2-Methyl-2-propanol + Glycerol + CO2}. Journal of Chemical & Engineering Data 2013, 58
(9)
, 2506-2512. https://doi.org/10.1021/je400398e
- Catinca Secuianu, Viorel Feroiu and Dan Geană. Phase Behavior for the Carbon Dioxide + 2-Butanol System: Experimental Measurements and Modeling with Cubic Equations of State. Journal of Chemical & Engineering Data 2009, 54
(5)
, 1493-1499. https://doi.org/10.1021/je800799n
- Li-Sheng Hao and, Yan-Qing Nan. Applications of Associating Martin−Hou Equation of State to Vapor−Liquid Equilibria in the Critical Region or the Near-Critical Region. Industrial & Engineering Chemistry Research 2007, 46
(3)
, 990-996. https://doi.org/10.1021/ie060884g
- Qinlan Luo, Yan Ouyang, Shumin Hong, Nan Wang, Yuanyuan Li, Hongxia Gao, Gyeong S. Hwang, Bohak Yoon, Teerawat Sema, Paitoon Tontiwachwuthikul, Peng Luo, Chintana Saiwan, Zhiwu Liang. Combined experimental and computational study on the effect of solvent structure on developing CO2 biphasic absorbents. Separation and Purification Technology 2023, 308 , 122856. https://doi.org/10.1016/j.seppur.2022.122856
- Sutida Meesattham, Pattaraporn Kim-Lohsoontorn. Low-temperature alcohol-assisted methanol synthesis from CO2 and H2: The effect of alcohol type. International Journal of Hydrogen Energy 2022, 47
(54)
, 22691-22703. https://doi.org/10.1016/j.ijhydene.2022.05.083
- Sergiu Sima, Adrian Victor Crişciu, Catinca Secuianu. Phase Behavior of Carbon Dioxide + Isobutanol and Carbon Dioxide + tert-Butanol Binary Systems. Energies 2022, 15
(7)
, 2625. https://doi.org/10.3390/en15072625
- Sona Raeissi, Reza Haghbakhsh, Louw J. Florusse, Cor J. Peters. Solubility of Carbon Dioxide in Secondary Butyl Alcohol at High Pressures: Experimental and Modeling with CPA. Journal of Solution Chemistry 2015, 44
(8)
, 1555-1567. https://doi.org/10.1007/s10953-015-0361-x
- Sergiu Sima, Catinca Secuianu, Viorel Feroiu, Dan Geană. New high-pressures vapor-liquid equilibrium data for the carbon dioxide + 2-methyl-2-propanol binary system. Open Chemistry 2014, 12
(9)
, 893-900. https://doi.org/10.2478/s11532-013-0392-3
- Sergiu Sima, Catinca Secuianu, Viorel Feroiu, Dan Geană. New high-pressures vapor-liquid equilibrium data for the carbon dioxide + 2-methyl-1-propanol (isobutanol) binary system. Open Chemistry 2014, 12
(9)
, 953-961. https://doi.org/10.2478/s11532-013-0394-1
- Lan Zheng, Yu Qi Wang, Kai Xun Chen, Lin Wang. Solubilities Prediction and Partial Molar Volume Calculation for 2-Butanol and CO2 Binary Mixture at High Pressure. Applied Mechanics and Materials 2011, 138-139 , 1032-1039. https://doi.org/10.4028/www.scientific.net/AMM.138-139.1032
- Octavio Elizalde-Solis, Luis A. Galicia-Luna. Vapor–liquid equilibria and phase densities at saturation of carbon dioxide+1-butanol and carbon dioxide+2-butanol from 313 to 363K. Fluid Phase Equilibria 2010, 296
(1)
, 66-71. https://doi.org/10.1016/j.fluid.2010.03.042
- Jorge E. Gutiérrez, Arturo Bejarano, Juan C. de la Fuente. Measurement and modeling of high-pressure (vapour+liquid) equilibria of (CO2+alcohol) binary systems. The Journal of Chemical Thermodynamics 2010, 42
(5)
, 591-596. https://doi.org/10.1016/j.jct.2009.11.015
- Ralf Dohrn, Stephanie Peper, José M.S. Fonseca. High-pressure fluid-phase equilibria: Experimental methods and systems investigated (2000–2004). Fluid Phase Equilibria 2010, 288
(1-2)
, 1-54. https://doi.org/10.1016/j.fluid.2009.08.008
- F.C.v.N. Fourie, C.E. Schwarz, J.H. Knoetze. Phase equilibria of alcohols in supercritical fluids. The Journal of Supercritical Fluids 2008, 47
(2)
, 161-167. https://doi.org/10.1016/j.supflu.2008.07.001