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Excess Enthalpies of the Ternary Mixtures Diisopropyl Ether + 3-Methylpentane + (Octane or Decane) at 298.15 K

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Department of Chemical Engineering, University of Ottawa, Ottawa, Ontario, Canada K1N 6N5
Cite this: J. Chem. Eng. Data 2003, 48, 5, 1286–1290
Publication Date (Web):August 26, 2003
https://doi.org/10.1021/je030161t
Copyright © 2003 American Chemical Society
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Abstract

Excess molar enthalpies, measured at 298.15 K in a flow microcalorimeter, are reported for diisopropyl ether + 3-methylpentane + octane and for diisopropyl ether + 3-methylpentane + decane. Smooth representations of the results are described and used to construct constant excess molar enthalpy contours on Roozeboom diagrams. The latter are compared with diagrams obtained when the model of Liebermann and Fried is used to estimate the excess molar enthalpies of the ternary mixtures from the physical properties of the components and the excess molar enthalpies of their constituent binary mixtures.

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Cited By

This article is cited by 2 publications.

  1. Zhaohui Wang, Benjamin C.‐Y. Lu, Ding‐Yu Peng, Christopher Q. Lan. Liebermann‐fried model parameters for calculating vapour‐liquid equlibria of oxygenate and hydrocarbon mixtures. Journal of the Chinese Institute of Engineers 2005, 28 (7) , 1089-1105. https://doi.org/10.1080/02533839.2005.9671086
  2. Zhaohui Wang, George C. Benson, Benjamin C.-Y. Lu. Excess enthalpies of binary mixtures of 1-hexene with some branched alkanes at the temperature 298.15 K. The Journal of Chemical Thermodynamics 2004, 36 (1) , 45-47. https://doi.org/10.1016/j.jct.2003.09.004

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